CA1236818A - Immobilisation des depots du vanadium sur un materiau de sorption au cours de la viscoreduction des petroles carbometalliques - Google Patents

Immobilisation des depots du vanadium sur un materiau de sorption au cours de la viscoreduction des petroles carbometalliques

Info

Publication number: CA1236818A
Authority: CA; Canada
Prior art keywords: sorbent; clay; pore volume; slurry; feed
Prior art date: 1984-10-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000464443A

Other languages

English (en)

Inventor

H. Wayne Beck

William P. Hettinger, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ashland LLC

Original Assignee

Ashland Oil Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-10-01

Filing date

1984-10-01

Publication date

1988-05-17

1984-10-01 Application filed by Ashland Oil Inc filed Critical Ashland Oil Inc

1984-10-01 Priority to CA000464443A priority Critical patent/CA1236818A/fr

1988-05-17 Application granted granted Critical

1988-05-17 Publication of CA1236818A publication Critical patent/CA1236818A/fr

Status Expired legal-status Critical Current

Links

239000002594 sorbent Substances 0.000 title claims abstract description 226
239000000463 material Substances 0.000 title claims description 87
239000003921 oil Substances 0.000 title claims description 75
238000011282 treatment Methods 0.000 title description 17
229910052751 metal Inorganic materials 0.000 claims abstract description 165
239000002184 metal Substances 0.000 claims abstract description 164
239000011148 porous material Substances 0.000 claims abstract description 90
239000007787 solid Substances 0.000 claims abstract description 69
238000000034 method Methods 0.000 claims abstract description 66
229910052720 vanadium Inorganic materials 0.000 claims abstract description 65
238000009835 boiling Methods 0.000 claims abstract description 40
238000002360 preparation method Methods 0.000 claims abstract description 14
239000002245 particle Substances 0.000 claims description 87
150000002739 metals Chemical class 0.000 claims description 60
239000004927 clay Substances 0.000 claims description 50
239000000203 mixture Substances 0.000 claims description 29
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 22
150000001875 compounds Chemical class 0.000 claims description 21
239000002002 slurry Substances 0.000 claims description 21
239000007921 spray Substances 0.000 claims description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
239000011236 particulate material Substances 0.000 claims description 15
239000006229 carbon black Substances 0.000 claims description 14
238000002156 mixing Methods 0.000 claims description 9
229910052719 titanium Inorganic materials 0.000 claims description 9
239000010936 titanium Substances 0.000 claims description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
238000010438 heat treatment Methods 0.000 claims description 8
230000003100 immobilizing effect Effects 0.000 claims description 8
239000000377 silicon dioxide Substances 0.000 claims description 8
238000001694 spray drying Methods 0.000 claims description 8
238000000354 decomposition reaction Methods 0.000 claims description 6
239000002270 dispersing agent Substances 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 6
239000003463 adsorbent Substances 0.000 claims description 5
239000011230 binding agent Substances 0.000 claims description 5
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
229910052791 calcium Inorganic materials 0.000 claims description 4
239000011575 calcium Substances 0.000 claims description 4
239000011368 organic material Substances 0.000 claims description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
239000004115 Sodium Silicate Substances 0.000 claims description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
238000013019 agitation Methods 0.000 claims description 3
229910010272 inorganic material Inorganic materials 0.000 claims description 3
239000011777 magnesium Substances 0.000 claims description 3
229910052749 magnesium Inorganic materials 0.000 claims description 3
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 3
229940048086 sodium pyrophosphate Drugs 0.000 claims description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
229910052911 sodium silicate Inorganic materials 0.000 claims description 3
238000003756 stirring Methods 0.000 claims description 3
235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 3
239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
229910052726 zirconium Inorganic materials 0.000 claims description 3
229910052788 barium Inorganic materials 0.000 claims description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
229920005610 lignin Polymers 0.000 claims description 2
235000019795 sodium metasilicate Nutrition 0.000 claims description 2
235000011149 sulphuric acid Nutrition 0.000 claims description 2
229910052622 kaolinite Inorganic materials 0.000 claims 4
238000001816 cooling Methods 0.000 claims 3
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 2
239000011147 inorganic material Substances 0.000 claims 1
239000012265 solid product Substances 0.000 claims 1
239000001117 sulphuric acid Substances 0.000 claims 1
239000000654 additive Substances 0.000 abstract description 92
230000000996 additive effect Effects 0.000 abstract description 71
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 46
229910052799 carbon Inorganic materials 0.000 abstract description 45
229930195733 hydrocarbon Natural products 0.000 abstract description 36
150000002430 hydrocarbons Chemical class 0.000 abstract description 35
239000004215 Carbon black (E152) Substances 0.000 abstract description 22
230000008018 melting Effects 0.000 abstract description 18
238000002844 melting Methods 0.000 abstract description 18
239000000356 contaminant Substances 0.000 abstract description 17
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 12
-1 carbon metals Chemical class 0.000 abstract description 10
239000003575 carbonaceous material Substances 0.000 abstract description 7
229910052759 nickel Inorganic materials 0.000 abstract description 7
229910052742 iron Inorganic materials 0.000 abstract description 5
229910052802 copper Inorganic materials 0.000 abstract description 4
150000003682 vanadium compounds Chemical class 0.000 abstract description 3
239000000470 constituent Substances 0.000 abstract 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 62
239000003054 catalyst Substances 0.000 description 43
230000008569 process Effects 0.000 description 43
230000002829 reductive effect Effects 0.000 description 32
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 28
238000007792 addition Methods 0.000 description 27
239000007789 gas Substances 0.000 description 26
238000004581 coalescence Methods 0.000 description 25
238000012545 processing Methods 0.000 description 24
238000006243 chemical reaction Methods 0.000 description 23
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230000008929 regeneration Effects 0.000 description 23
238000011069 regeneration method Methods 0.000 description 23
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239000010779 crude oil Substances 0.000 description 20
238000005336 cracking Methods 0.000 description 16
239000000047 product Substances 0.000 description 15
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229910001385 heavy metal Inorganic materials 0.000 description 13
239000007788 liquid Substances 0.000 description 13
238000004519 manufacturing process Methods 0.000 description 13
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
239000001257 hydrogen Substances 0.000 description 11
229910052739 hydrogen Inorganic materials 0.000 description 11
239000000243 solution Substances 0.000 description 10
230000002411 adverse Effects 0.000 description 9
239000005995 Aluminium silicate Substances 0.000 description 8
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
235000012211 aluminium silicate Nutrition 0.000 description 8
230000008901 benefit Effects 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
238000001354 calcination Methods 0.000 description 8
239000011734 sodium Substances 0.000 description 8
229910052708 sodium Inorganic materials 0.000 description 8
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
241000282320 Panthera leo Species 0.000 description 7
239000002826 coolant Substances 0.000 description 7
238000011161 development Methods 0.000 description 7
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239000012530 fluid Substances 0.000 description 7
238000005243 fluidization Methods 0.000 description 7
239000004005 microsphere Substances 0.000 description 7
239000000725 suspension Substances 0.000 description 7
238000012360 testing method Methods 0.000 description 7
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
238000004523 catalytic cracking Methods 0.000 description 6
238000002485 combustion reaction Methods 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
230000036961 partial effect Effects 0.000 description 6
229910052717 sulfur Inorganic materials 0.000 description 6
239000011593 sulfur Substances 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
239000002253 acid Substances 0.000 description 5
229910002092 carbon dioxide Inorganic materials 0.000 description 5
239000000295 fuel oil Substances 0.000 description 5
239000003502 gasoline Substances 0.000 description 5
239000012798 spherical particle Substances 0.000 description 5
239000001569 carbon dioxide Substances 0.000 description 4
238000004939 coking Methods 0.000 description 4
230000008021 deposition Effects 0.000 description 4
238000009792 diffusion process Methods 0.000 description 4
238000004821 distillation Methods 0.000 description 4
239000003546 flue gas Substances 0.000 description 4
239000000395 magnesium oxide Substances 0.000 description 4
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150000002902 organometallic compounds Chemical class 0.000 description 4
150000004032 porphyrins Chemical class 0.000 description 4
239000002904 solvent Substances 0.000 description 4
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
206010039509 Scab Diseases 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
238000002441 X-ray diffraction Methods 0.000 description 3
229910045601 alloy Inorganic materials 0.000 description 3
239000000956 alloy Substances 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
239000000292 calcium oxide Substances 0.000 description 3
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
239000010949 copper Substances 0.000 description 3
238000004455 differential thermal analysis Methods 0.000 description 3
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
229940071125 manganese acetate Drugs 0.000 description 3
UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 3
239000011159 matrix material Substances 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 3
230000009467 reduction Effects 0.000 description 3
238000001179 sorption measurement Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000008399 tap water Substances 0.000 description 3
235000020679 tap water Nutrition 0.000 description 3
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
238000012546 transfer Methods 0.000 description 3
ANHQLUBMNSSPBV-UHFFFAOYSA-N 4h-pyrido[3,2-b][1,4]oxazin-3-one Chemical group C1=CN=C2NC(=O)COC2=C1 ANHQLUBMNSSPBV-UHFFFAOYSA-N 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
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229910002651 NO3 Inorganic materials 0.000 description 2
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235000018936 Vitellaria paradoxa Nutrition 0.000 description 2
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150000002602 lanthanoids Chemical class 0.000 description 2
238000011068 loading method Methods 0.000 description 2
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JCVGSKJSMKEPAM-UHFFFAOYSA-J tetrasodium;phosphonato phosphate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O JCVGSKJSMKEPAM-UHFFFAOYSA-J 0.000 description 2
VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 2
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NGCRLFIYVFOUMZ-UHFFFAOYSA-N 2,3-dichloroquinoxaline-6-carbonyl chloride Chemical compound N1=C(Cl)C(Cl)=NC2=CC(C(=O)Cl)=CC=C21 NGCRLFIYVFOUMZ-UHFFFAOYSA-N 0.000 description 1
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GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
230000008034 disappearance Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000004134 energy conservation Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
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239000011440 grout Substances 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910003437 indium oxide Inorganic materials 0.000 description 1
PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910017053 inorganic salt Inorganic materials 0.000 description 1
239000011872 intimate mixture Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
230000005722 itchiness Effects 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
229910000464 lead oxide Inorganic materials 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
239000007769 metal material Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
239000002923 metal particle Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
125000005609 naphthenate group Chemical group 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
ZGSOBQAJAUGRBK-UHFFFAOYSA-N propan-2-olate;zirconium(4+) Chemical compound [Zr+4].CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-] ZGSOBQAJAUGRBK-UHFFFAOYSA-N 0.000 description 1
239000008262 pumice Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000001172 regenerating effect Effects 0.000 description 1
230000008439 repair process Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000010454 slate Substances 0.000 description 1
229910021647 smectite Inorganic materials 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000004227 thermal cracking Methods 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
150000003608 titanium Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
210000003371 toe Anatomy 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
229910001935 vanadium oxide Inorganic materials 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
239000011800 void material Substances 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
229910052845 zircon Inorganic materials 0.000 description 1
GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1

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Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

CA000464443A 1984-10-01 1984-10-01 Immobilisation des depots du vanadium sur un materiau de sorption au cours de la viscoreduction des petroles carbometalliques Expired CA1236818A (fr)

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CA000464443A CA1236818A (fr)	1984-10-01	1984-10-01	Immobilisation des depots du vanadium sur un materiau de sorption au cours de la viscoreduction des petroles carbometalliques

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CA000464443A CA1236818A (fr)	1984-10-01	1984-10-01	Immobilisation des depots du vanadium sur un materiau de sorption au cours de la viscoreduction des petroles carbometalliques

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN117140687A (zh) *	2023-09-19	2023-12-01	宜宾红星电子有限公司	一种陶瓷热压铸成型的排蜡方法

1984
- 1984-10-01 CA CA000464443A patent/CA1236818A/fr not_active Expired

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN117140687A (zh) *	2023-09-19	2023-12-01	宜宾红星电子有限公司	一种陶瓷热压铸成型的排蜡方法

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Date	Code	Title	Description
2005-05-17	MKEX	Expiry

Publication	Publication Date	Title
US4469588A (en)	1984-09-04	Immobilization of vanadia deposited on sorbent materials during visbreaking treatment of carbo-metallic oils
US4549958A (en)	1985-10-29	Immobilization of vanadia deposited on sorbent materials during treatment of carbo-metallic oils
US4412914A (en)	1983-11-01	Endothermic removal of coke deposited on sorbent materials during carbo-metallic oil conversion
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US4432890A (en)	1984-02-21	Immobilization of vanadia deposited on catalytic materials during carbo-metallic oil conversion
JP4864261B2 (ja)	2012-02-01	流体接触分解法におけるガソリンの脱硫
US4414098A (en)	1983-11-08	Upgrading carbo-metallic oils with used catalyst
KR100863822B1 (ko)	2008-10-15	유체 촉매에 의한 분해 방법용 가솔린 황 감소 촉매
CN101027128A (zh)	2007-08-29	去除金属污染物用的添加剂
WO1982003225A1 (fr)	1982-09-30	Immobilisation de composes de vanadium deposes sur des materiaux catalytiques pendant la conversion d'une huile carbometallique
US5174890A (en)	1992-12-29	Catalytic cracking using a metals scavenging composition
CA1190879A (fr)	1985-07-23	Immobilisation du vanadium depose sur les lits de catalyse au cours de la conversion des petroles carbometalliques
US4515900A (en)	1985-05-07	Sorbent useful in a visbreaking treatment of carbo-metallic oils
WO1982003226A1 (fr)	1982-09-30	Immobilisation de composes de vanadium deposes sur des materiaux sorbants pendant le traitement d'huiles carbo-metalliques
EP0175799A1 (fr)	1986-04-02	Immobilisation de vanadium déposé sur des adsorbants pendant la viscoréduction d'huiles contenant des métaux et des précurseurs de carbone
CA1236818A (fr)	1988-05-17	Immobilisation des depots du vanadium sur un materiau de sorption au cours de la viscoreduction des petroles carbometalliques
US4920087A (en)	1990-04-24	Vanadium scavenging compositions
JPH0210694B2 (fr)	1990-03-09
US4750987A (en)	1988-06-14	Immobilization of vanadia deposited on catalytic materials during carbo-metallic oil conversion
EP0073874A1 (fr)	1983-03-16	Immobilisation d'oxyde de vanadium déposé sur des catalyseurs pendant la conversion d'huiles contenant des précurseurs de coke et des métaux lourds
CA2560482A1 (fr)	2005-10-06	Catalyseur de craquage catalytique fluide contenant du zinc et utilisation de celui-ci pour reduire la teneur en soufre de l'essence
JP2020142229A (ja)	2020-09-10	炭化水素油用流動接触分解触媒
CA1183792A (fr)	1985-03-12	Immobilisation du vanadium depose sur un catalyseur durant la transformation des petroles carbo- metalliques
EP0063683A2 (fr)	1982-11-03	Immobilisation de vanadium déposé sur des adsorbants pendant le traitement d'huiles contenant des métaux lourds et des précurseurs de coke
JPS5946994B2 (ja)	1984-11-16	バナジウム含有炭化水素油を軽質生成物に転化する方法

CA1236818A - Immobilisation des depots du vanadium sur un materiau de sorption au cours de la viscoreduction des petroles carbometalliques - Google Patents

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ID=4128816

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