CA1242054A - Process and compositions for sizing paper - Google Patents

Process and compositions for sizing paper

Info

Publication number: CA1242054A
Authority: CA; Canada
Prior art keywords: weight; water; reactive size; polyelectrolyte; composition
Prior art date: 1983-11-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000467105A

Other languages

English (en)

French (fr)

Inventor

Peter Flesher

John G. Langley

Norma D. Rosier

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ciba Specialty Chemicals Water Treatments Ltd

Original Assignee

Allied Colloids Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-11-07

Filing date

1984-11-06

Publication date

1988-09-20

1984-11-06 Application filed by Allied Colloids Ltd filed Critical Allied Colloids Ltd

1988-09-20 Application granted granted Critical

1988-09-20 Publication of CA1242054A publication Critical patent/CA1242054A/en

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 54
238000004513 sizing Methods 0.000 title claims abstract description 19
238000000034 method Methods 0.000 title claims abstract description 12
239000006185 dispersion Substances 0.000 claims abstract description 43
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
229920000867 polyelectrolyte Polymers 0.000 claims abstract description 33
239000012141 concentrate Substances 0.000 claims abstract description 30
239000007788 liquid Substances 0.000 claims abstract description 21
239000002904 solvent Substances 0.000 claims abstract description 17
230000002209 hydrophobic effect Effects 0.000 claims abstract description 15
229920000642 polymer Polymers 0.000 claims description 20
239000000243 solution Substances 0.000 claims description 17
125000002091 cationic group Chemical group 0.000 claims description 14
-1 dialkylaminoalkyl acrylates Chemical class 0.000 claims description 14
WASQWSOJHCZDFK-UHFFFAOYSA-N diketene Chemical group C=C1CC(=O)O1 WASQWSOJHCZDFK-UHFFFAOYSA-N 0.000 claims description 13
239000003995 emulsifying agent Substances 0.000 claims description 10
239000000178 monomer Substances 0.000 claims description 8
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 5
150000008064 anhydrides Chemical class 0.000 claims description 5
229920006318 anionic polymer Polymers 0.000 claims description 5
239000003960 organic solvent Substances 0.000 claims description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
229920006317 cationic polymer Polymers 0.000 claims description 4
239000000463 material Substances 0.000 claims description 3
150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 3
229920000768 polyamine Polymers 0.000 claims description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
235000019270 ammonium chloride Nutrition 0.000 claims description 2
238000010790 dilution Methods 0.000 claims description 2
239000012895 dilution Substances 0.000 claims description 2
150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
238000002156 mixing Methods 0.000 abstract description 5
239000000839 emulsion Substances 0.000 description 52
235000008504 concentrate Nutrition 0.000 description 22
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 18
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 10
239000003921 oil Substances 0.000 description 8
229940014800 succinic anhydride Drugs 0.000 description 8
239000000539 dimer Substances 0.000 description 7
235000019198 oils Nutrition 0.000 description 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 6
239000000123 paper Substances 0.000 description 6
239000007787 solid Substances 0.000 description 6
229910021653 sulphate ion Inorganic materials 0.000 description 6
229920002472 Starch Polymers 0.000 description 5
229910000019 calcium carbonate Inorganic materials 0.000 description 5
239000011436 cob Substances 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
239000008107 starch Substances 0.000 description 5
235000019698 starch Nutrition 0.000 description 5
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 4
NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
238000004945 emulsification Methods 0.000 description 4
230000001804 emulsifying effect Effects 0.000 description 4
239000002480 mineral oil Substances 0.000 description 4
239000012071 phase Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 3
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
235000018185 Betula X alpestris Nutrition 0.000 description 3
235000018212 Betula X uliginosa Nutrition 0.000 description 3
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
229940037003 alum Drugs 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
239000004815 dispersion polymer Substances 0.000 description 3
229920001519 homopolymer Polymers 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
235000010446 mineral oil Nutrition 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000000725 suspension Substances 0.000 description 3
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000003792 electrolyte Substances 0.000 description 2
150000002561 ketenes Chemical class 0.000 description 2
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
229940050176 methyl chloride Drugs 0.000 description 2
239000007764 o/w emulsion Substances 0.000 description 2
229920002401 polyacrylamide Polymers 0.000 description 2
239000013055 pulp slurry Substances 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical class CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
235000021360 Myristic acid Nutrition 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
150000003926 acrylamides Chemical class 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
239000002655 kraft paper Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
239000004533 oil dispersion Substances 0.000 description 1
235000021313 oleic acid Nutrition 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
230000035515 penetration Effects 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000008149 soap solution Substances 0.000 description 1
150000003385 sodium Chemical class 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
235000020354 squash Nutrition 0.000 description 1
238000003860 storage Methods 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Paper (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Adhesives Or Adhesive Processes (AREA)
Diaphragms For Electromechanical Transducers (AREA)
Credit Cards Or The Like (AREA)
Making Paper Articles (AREA)

CA000467105A 1983-11-07 1984-11-06 Process and compositions for sizing paper Expired CA1242054A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB838329655A GB8329655D0 (en)	1983-11-07	1983-11-07	Sizing paper
GB8329655		1983-11-07

Publications (1)

Publication Number	Publication Date
CA1242054A true CA1242054A (en)	1988-09-20

Family

ID=10551354

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000467105A Expired CA1242054A (en)	1983-11-07	1984-11-06	Process and compositions for sizing paper

Country Status (10)

Country	Link
EP (1)	EP0141641B1 (de)
JP (1)	JPS60119298A (de)
AT (1)	ATE29540T1 (de)
AU (1)	AU580014B2 (de)
CA (1)	CA1242054A (de)
DE (1)	DE3466025D1 (de)
FI (1)	FI81636C (de)
GB (1)	GB8329655D0 (de)
NO (1)	NO170769C (de)
ZA (1)	ZA848625B (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB8511379D0 (en) *	1985-05-03	1985-06-12	Allied Colloids Ltd	Compositions for sizing paper
JPH0678462B2 (ja) *	1984-06-04	1994-10-05	日本ピー・エム・シー株式会社	ケテンダイマー系水性分散液
GB8602121D0 (en) *	1986-01-29	1986-03-05	Allied Colloids Ltd	Paper & paper board
US4913775A (en) *	1986-01-29	1990-04-03	Allied Colloids Ltd.	Production of paper and paper board
US5176748A (en) *	1988-07-05	1993-01-05	Bercen, Inc.	Alkenyl succinic anhydride emulsion
US5725731A (en) †	1995-05-08	1998-03-10	Hercules Incorporated	2-oxetanone sizing agents comprising saturated and unsaturated tails, paper made with the 2-oxetanone sizing agents, and use of the paper in high speed converting and reprographic operations
US6162328A (en) *	1997-09-30	2000-12-19	Hercules Incorporated	Method for surface sizing paper with cellulose reactive and cellulose non-reactive sizes, and paper prepared thereby
US7892398B2 (en) *	2005-12-21	2011-02-22	Akzo Nobel N.V.	Sizing of paper

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US1370650A (en) *	1920-04-09	1921-03-08	Hoskins William	Art of making water-resistant paper
US1958202A (en) *	1931-12-19	1934-05-08	Raybestos Manhattan Inc	Method of making sizing material
US3046186A (en) *	1957-06-12	1962-07-24	American Cyanamid Co	Cationic sizing emulsions and paper sized therewith
GB1397933A (en) *	1971-12-21	1975-06-18	Allied Colloids Ltd	Vinyl addition polymers
GB1397333A (en) *	1972-04-18	1975-06-11	Stag Plastics Ltd	Box dividers
GB1482515A (en) *	1974-07-24	1977-08-10	Allied Colloids Ltd	Polymers
US4214948A (en) *	1974-07-31	1980-07-29	National Starch And Chemical Corporation	Method of sizing paper
US4021399A (en) *	1976-03-12	1977-05-03	Nalco Chemical Company	Method for the concentration of water-in-oil emulsions of water soluble vinyl addition polymers
GB1569591A (en) *	1977-04-06	1980-06-18	Tenneco Chem	Paper sizing agents
FR2486950B1 (fr) *	1980-07-15	1985-09-13	Inst Francais Du Petrole	Suspensions stables de polymeres hydrosolubles et leur preparation

1983
- 1983-11-07 GB GB838329655A patent/GB8329655D0/en active Pending
1984
- 1984-10-30 AT AT84307468T patent/ATE29540T1/de not_active IP Right Cessation
- 1984-10-30 DE DE8484307468T patent/DE3466025D1/de not_active Expired
- 1984-10-30 EP EP84307468A patent/EP0141641B1/de not_active Expired
- 1984-11-05 ZA ZA848625A patent/ZA848625B/xx unknown
- 1984-11-05 AU AU34996/84A patent/AU580014B2/en not_active Ceased
- 1984-11-06 NO NO844415A patent/NO170769C/no unknown
- 1984-11-06 CA CA000467105A patent/CA1242054A/en not_active Expired
- 1984-11-07 FI FI844373A patent/FI81636C/fi not_active IP Right Cessation
- 1984-11-07 JP JP59235936A patent/JPS60119298A/ja active Pending

Also Published As

Publication number	Publication date
EP0141641B1 (de)	1987-09-09
DE3466025D1 (en)	1987-10-15
NO170769C (no)	1992-12-02
AU3499684A (en)	1985-05-16
NO844415L (no)	1985-05-08
NO170769B (no)	1992-08-24
FI81636C (fi)	1990-11-12
FI844373A0 (fi)	1984-11-07
EP0141641A3 (en)	1985-06-12
ZA848625B (en)	1985-12-24
JPS60119298A (ja)	1985-06-26
FI81636B (fi)	1990-07-31
EP0141641A2 (de)	1985-05-15
FI844373L (fi)	1985-05-08
ATE29540T1 (de)	1987-09-15
AU580014B2 (en)	1988-12-22
GB8329655D0 (en)	1983-12-07

Legal Events

Date	Code	Title	Description
2005-09-20	MKEX	Expiry

Publication	Publication Date	Title
US4657946A (en)	1987-04-14	Paper sizing method and emulsion
JP2948358B2 (ja)	1999-09-13	製紙工程に添加される有機重合体微小球
KR100473003B1 (ko)	2005-05-16	로진사이징제용유화시스템
DE69410361T2 (de)	1998-10-01	Zusammensetzungen und Verfahren zur Verbesserung zur Trennung von Feststoffen aus Dispersionen von Teilchen in Flüssigkeit
EP0151994B1 (de)	1991-08-07	Verfahren zur Herstellung eines Leimungsmittels und Papierleimungsverfahren
US3902958A (en)	1975-09-02	Method of making improved paper and paper products
CA1242054A (en)	1988-09-20	Process and compositions for sizing paper
EP0499448A1 (de)	1992-08-19	Papierherstellung
US4859720A (en)	1989-08-22	Process and compositions for sizing paper
DE69205956T2 (de)	1996-04-25	Emulgierte Alkenylbernsteinsäure als Leimungmittel.
EP0200504B1 (de)	1989-08-09	Zusammensetzungen für die Papierleimung
GB2159183A (en)	1985-11-27	Paper sizing composition
DE69125241T2 (de)	1997-07-17	Verwendung von dispergierungsmitteln in der herstellung wässriger emulsionen von kolophoniumverbindungen, sowie diese wässrige emulsionen der kolophoniumverbindungen
EP0177260B1 (de)	1989-06-07	Dispergierte, wässrige Lösung eines substituierten Bernsteinsäureanhydrids und Verfahren zur Herstellung derselben
EP0228801B1 (de)	1991-01-02	Dispergierte wässrige Lösung eines substituierten Bernsteinsäureanhydrids
JPS60246893A (ja)	1985-12-06	サイズ剤の調製方法
JP3477932B2 (ja)	2003-12-10	製紙用ロジン系エマルジョンサイズ剤および紙サイジング方法
JP2799505B2 (ja)	1998-09-17	エマルジョンサイズ剤
JP3221189B2 (ja)	2001-10-22	ロジン系エマルション組成物、その製造方法、サイズ剤、サイジング方法及びサイズされた紙
CA2245507C (en)	2006-05-23	Emulsifier system for rosin sizing agents
RU2172799C2 (ru)	2001-08-27	Проклеивающая композиция, композиция коацерватной дисперсии, способ ее приготовления, способ изготовления проклеенной бумаги, проклеенная бумага с использованием композиций
JP3221188B2 (ja)	2001-10-22	ロジン系エマルション組成物、その製造方法、サイズ剤、サイジング方法及びサイズされた紙
JP3221062B2 (ja)	2001-10-22	ロジン系エマルション組成物、その製造方法、サイジング方法、サイズ剤及びサイズ紙
Shiraishi et al.	0	SPMC Technical Review EN