CA1250539A - Cotraitement de suspensions epaisses de bitume et de charbon a l'aide d'hydrogene sulfure comme activateur - Google Patents

Cotraitement de suspensions epaisses de bitume et de charbon a l'aide d'hydrogene sulfure comme activateur

Info

Publication number: CA1250539A
Authority: CA; Canada
Prior art keywords: coal; slurry; hydrogen; heavy; bitumen
Prior art date: 1986-04-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000507816A

Other languages

English (en)

Inventor

James F. Kelly

Parviz M. Rahimi

Safaa A. Fouda

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Canada Minister of Energy Mines and Resources

Original Assignee

Canada Minister of Energy Mines and Resources

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-04-29

Filing date

1986-04-29

Publication date

1989-02-28

1986-04-29 Application filed by Canada Minister of Energy Mines and Resources filed Critical Canada Minister of Energy Mines and Resources

1986-04-29 Priority to CA000507816A priority Critical patent/CA1250539A/fr

1989-02-28 Application granted granted Critical

1989-02-28 Publication of CA1250539A publication Critical patent/CA1250539A/fr

Status Expired legal-status Critical Current

Links

RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims abstract description 31
239000010426 asphalt Substances 0.000 title abstract description 21
239000003250 coal slurry Substances 0.000 title description 3
239000003245 coal Substances 0.000 claims abstract description 83
239000002002 slurry Substances 0.000 claims abstract description 36
238000000034 method Methods 0.000 claims abstract description 27
229930195733 hydrocarbon Natural products 0.000 claims abstract description 26
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 26
230000008569 process Effects 0.000 claims abstract description 25
239000003054 catalyst Substances 0.000 claims abstract description 23
238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 23
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 16
239000000295 fuel oil Substances 0.000 claims abstract description 10
238000005984 hydrogenation reaction Methods 0.000 claims abstract description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 32
239000001257 hydrogen Substances 0.000 claims description 31
229910052739 hydrogen Inorganic materials 0.000 claims description 31
239000003921 oil Substances 0.000 claims description 26
239000007792 gaseous phase Substances 0.000 claims description 2
239000003077 lignite Substances 0.000 claims description 2
239000012071 phase Substances 0.000 claims description 2
239000000463 material Substances 0.000 abstract description 12
239000000571 coke Substances 0.000 abstract description 6
238000009835 boiling Methods 0.000 abstract description 4
230000015572 biosynthetic process Effects 0.000 abstract description 3
238000005755 formation reaction Methods 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 10
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
239000000047 product Substances 0.000 description 9
239000007789 gas Substances 0.000 description 8
239000005864 Sulphur Substances 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 5
239000010779 crude oil Substances 0.000 description 5
229910052742 iron Inorganic materials 0.000 description 5
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 4
229910052500 inorganic mineral Inorganic materials 0.000 description 4
239000011707 mineral Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
238000005201 scrubbing Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
238000004939 coking Methods 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000000356 contaminant Substances 0.000 description 3
229910000359 iron(II) sulfate Inorganic materials 0.000 description 3
239000007788 liquid Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000000852 hydrogen donor Substances 0.000 description 2
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
125000002524 organometallic group Chemical group 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000003476 subbituminous coal Substances 0.000 description 2
WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical class N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
229910005390 FeSO4-7H2O Inorganic materials 0.000 description 1
229910005444 FeSO4—7H2O Inorganic materials 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
239000003830 anthracite Substances 0.000 description 1
239000002802 bituminous coal Substances 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000003575 carbonaceous material Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
230000001066 destructive effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000002737 fuel gas Substances 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
239000002815 homogeneous catalyst Substances 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000003415 peat Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
238000002407 reforming Methods 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000004227 thermal cracking Methods 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
229940045605 vanadium Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
- C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Wood Science & Technology (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000507816A 1986-04-29 1986-04-29 Cotraitement de suspensions epaisses de bitume et de charbon a l'aide d'hydrogene sulfure comme activateur Expired CA1250539A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000507816A CA1250539A (fr)	1986-04-29	1986-04-29	Cotraitement de suspensions epaisses de bitume et de charbon a l'aide d'hydrogene sulfure comme activateur

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000507816A CA1250539A (fr)	1986-04-29	1986-04-29	Cotraitement de suspensions epaisses de bitume et de charbon a l'aide d'hydrogene sulfure comme activateur

Publications (1)

Publication Number	Publication Date
CA1250539A true CA1250539A (fr)	1989-02-28

Family

ID=4132994

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000507816A Expired CA1250539A (fr)	1986-04-29	1986-04-29	Cotraitement de suspensions epaisses de bitume et de charbon a l'aide d'hydrogene sulfure comme activateur

Country Status (1)

Country	Link
CA (1)	CA1250539A (fr)

1986
- 1986-04-29 CA CA000507816A patent/CA1250539A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2006-04-29	MKEX	Expiry

Publication	Publication Date	Title
CA1094492A (fr)	1981-01-27	Hydrocraquage d'huiles lourdes avec un catalyseur fer- charbon
US4067799A (en)	1978-01-10	Hydroconversion process
US4252634A (en)	1981-02-24	Thermal hydrocracking of heavy hydrocarbon oils with heavy oil recycle
US4376695A (en)	1983-03-15	Simultaneous demetalization and hydrocracking of heavy hydrocarbon oils
US4298454A (en)	1981-11-03	Hydroconversion of an oil-coal mixture
US4695369A (en)	1987-09-22	Catalytic hydroconversion of heavy oil using two metal catalyst
US4370221A (en)	1983-01-25	Catalytic hydrocracking of heavy oils
US4299685A (en)	1981-11-10	Hydrocracking of heavy oils/fly ash slurries
US4075079A (en)	1978-02-21	Process for the production of hydrocarbons from coal
US4077867A (en)	1978-03-07	Hydroconversion of coal in a hydrogen donor solvent with an oil-soluble catalyst
CA1079665A (fr)	1980-06-17	Hydroconversion d'un melange petrole-charbon
US4251346A (en)	1981-02-17	Process for coal liquefaction
US4435280A (en)	1984-03-06	Hydrocracking of heavy hydrocarbon oils with high pitch conversion
US4092236A (en)	1978-05-30	Molten salt hydroconversion process
US4411767A (en)	1983-10-25	Integrated process for the solvent refining of coal
US3862899A (en)	1975-01-28	Process for the production of synthesis gas and clean fuels
US3155608A (en)	1964-11-03	Process for reducing metals content of catalytic cracking feedstock
US4369106A (en)	1983-01-18	Coal liquefaction process
US4051015A (en)	1977-09-27	Hydroconversion of heavy hydrocarbons using copper chloride catalyst
CA1202588A (fr)	1986-04-01	Hydrofractionnement des petroles lourds par intervention d'additifs secs
CA1124195A (fr)	1982-05-25	Hydrofractionnement des hydrocarbures lourds au gaz de synthese
CA1322746C (fr)	1993-10-05	Hydrocraquage de petrole lourd en presence de coke de petrole sous-produit de la cokefaction de petrole lourd
US4824558A (en)	1989-04-25	Coal liquefaction process with metal/iodine cocatalyst
US4534847A (en)	1985-08-13	Process for producing low-sulfur boiler fuel by hydrotreatment of solvent deashed SRC
US4617106A (en)	1986-10-14	Catalysts for coal liquefaction processes