CA1256821A - Fibres optiques avec revetement de diorganopolysiloxane et photo-initiateur catalytique - Google Patents

Fibres optiques avec revetement de diorganopolysiloxane et photo-initiateur catalytique

Info

Publication number: CA1256821A
Authority: CA; Canada
Prior art keywords: epoxy; coating; optical fiber; diorganopolysiloxane; photoinitiator
Prior art date: 1984-11-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000469072A

Other languages

English (en)

Inventor

Richard P. Eckberg

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-11-30

Filing date

1984-11-30

Publication date

1989-07-04

1984-11-30 Application filed by General Electric Co filed Critical General Electric Co

1984-11-30 Priority to CA000469072A priority Critical patent/CA1256821A/fr

1989-07-04 Application granted granted Critical

1989-07-04 Publication of CA1256821A publication Critical patent/CA1256821A/fr

Status Expired legal-status Critical Current

Links

238000000576 coating method Methods 0.000 title claims abstract description 53
239000011248 coating agent Substances 0.000 title claims abstract description 47
229920005645 diorganopolysiloxane polymer Polymers 0.000 title claims abstract description 18
230000003197 catalytic effect Effects 0.000 title claims abstract description 7
230000003287 optical effect Effects 0.000 title description 6
239000013307 optical fiber Substances 0.000 claims abstract description 43
239000000835 fiber Substances 0.000 claims abstract description 28
239000008199 coating composition Substances 0.000 claims abstract description 19
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
238000004519 manufacturing process Methods 0.000 claims abstract description 9
230000001464 adherent effect Effects 0.000 claims abstract description 6
-1 hydrocarbon radical Chemical class 0.000 claims description 75
239000000203 mixture Substances 0.000 claims description 57
125000004432 carbon atom Chemical group C* 0.000 claims description 25
239000004593 Epoxy Substances 0.000 claims description 23
238000000034 method Methods 0.000 claims description 21
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 18
229920002554 vinyl polymer Polymers 0.000 claims description 16
229920005989 resin Polymers 0.000 claims description 15
239000011347 resin Substances 0.000 claims description 15
229910052739 hydrogen Inorganic materials 0.000 claims description 14
239000001257 hydrogen Substances 0.000 claims description 14
239000004215 Carbon black (E152) Substances 0.000 claims description 13
229930195733 hydrocarbon Natural products 0.000 claims description 13
150000003254 radicals Chemical class 0.000 claims description 13
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
230000005855 radiation Effects 0.000 claims description 12
238000004132 cross linking Methods 0.000 claims description 9
239000003085 diluting agent Substances 0.000 claims description 9
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 8
125000005520 diaryliodonium group Chemical group 0.000 claims description 7
239000004447 silicone coating Substances 0.000 claims description 7
PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 6
AENNXXRRACDJAY-UHFFFAOYSA-N bis(2-dodecylphenyl)iodanium Chemical group CCCCCCCCCCCCC1=CC=CC=C1[I+]C1=CC=CC=C1CCCCCCCCCCCC AENNXXRRACDJAY-UHFFFAOYSA-N 0.000 claims description 6
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical class I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 6
229920001897 terpolymer Polymers 0.000 claims description 6
125000000549 (4R)-limonene 1,2-epoxide group Chemical group 0.000 claims description 5
239000000178 monomer Substances 0.000 claims description 5
229910017048 AsF6 Inorganic materials 0.000 claims description 4
150000002148 esters Chemical class 0.000 claims description 4
239000003504 photosensitizing agent Substances 0.000 claims description 4
RBHIUNHSNSQJNG-UHFFFAOYSA-N 6-methyl-3-(2-methyloxiran-2-yl)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CC2(C)OC2CC1C1(C)CO1 RBHIUNHSNSQJNG-UHFFFAOYSA-N 0.000 claims description 3
239000012949 free radical photoinitiator Substances 0.000 claims description 3
150000002430 hydrocarbons Chemical class 0.000 claims description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
229920000647 polyepoxide Polymers 0.000 claims description 3
239000004655 radiation curable silicone release coating Substances 0.000 claims description 3
150000001282 organosilanes Chemical class 0.000 claims 1
125000005375 organosiloxane group Chemical group 0.000 claims 1
229920001296 polysiloxane Polymers 0.000 description 51
239000012530 fluid Substances 0.000 description 30
239000000463 material Substances 0.000 description 18
239000003054 catalyst Substances 0.000 description 17
238000001723 curing Methods 0.000 description 17
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
150000002118 epoxides Chemical group 0.000 description 13
229920000642 polymer Polymers 0.000 description 12
CCEFMUBVSUDRLG-KXUCPTDWSA-N (4R)-limonene 1,2-epoxide Natural products C1[C@H](C(=C)C)CC[C@@]2(C)O[C@H]21 CCEFMUBVSUDRLG-KXUCPTDWSA-N 0.000 description 11
WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 11
CCEFMUBVSUDRLG-XNWIYYODSA-N Limonene-1,2-epoxide Chemical compound C1[C@H](C(=C)C)CCC2(C)OC21 CCEFMUBVSUDRLG-XNWIYYODSA-N 0.000 description 11
239000000047 product Substances 0.000 description 10
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical class [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 9
239000002243 precursor Substances 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
239000004205 dimethyl polysiloxane Substances 0.000 description 6
238000006459 hydrosilylation reaction Methods 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 6
229920001843 polymethylhydrosiloxane Polymers 0.000 description 6
239000011541 reaction mixture Substances 0.000 description 6
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
125000003118 aryl group Chemical group 0.000 description 5
239000003365 glass fiber Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
239000004698 Polyethylene Substances 0.000 description 4
239000002253 acid Substances 0.000 description 4
229920005601 base polymer Polymers 0.000 description 4
KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 4
239000002655 kraft paper Substances 0.000 description 4
229910052697 platinum Inorganic materials 0.000 description 4
229920000573 polyethylene Polymers 0.000 description 4
125000001424 substituent group Chemical group 0.000 description 4
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 3
239000011247 coating layer Substances 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
239000010410 layer Substances 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
239000010970 precious metal Substances 0.000 description 3
125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 3
239000000758 substrate Substances 0.000 description 3
VMAWODUEPLAHOE-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 VMAWODUEPLAHOE-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
238000007259 addition reaction Methods 0.000 description 2
150000001491 aromatic compounds Chemical class 0.000 description 2
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
239000012965 benzophenone Substances 0.000 description 2
230000005540 biological transmission Effects 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000005253 cladding Methods 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
238000011161 development Methods 0.000 description 2
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
238000011067 equilibration Methods 0.000 description 2
239000012467 final product Substances 0.000 description 2
238000009472 formulation Methods 0.000 description 2
229920001002 functional polymer Polymers 0.000 description 2
230000004927 fusion Effects 0.000 description 2
150000004678 hydrides Chemical class 0.000 description 2
239000003999 initiator Substances 0.000 description 2
239000000543 intermediate Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000005304 joining Methods 0.000 description 2
230000000670 limiting effect Effects 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
230000001737 promoting effect Effects 0.000 description 2
229920002050 silicone resin Polymers 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 2
MCVUKOYZUCWLQQ-UHFFFAOYSA-N tridecylbenzene Chemical class CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 2
238000009736 wetting Methods 0.000 description 2
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
CUFXMPWHOWYNSO-UHFFFAOYSA-N 2-[(4-methylphenoxy)methyl]oxirane Chemical compound C1=CC(C)=CC=C1OCC1OC1 CUFXMPWHOWYNSO-UHFFFAOYSA-N 0.000 description 1
MPGABYXKKCLIRW-UHFFFAOYSA-N 2-decyloxirane Chemical compound CCCCCCCCCCC1CO1 MPGABYXKKCLIRW-UHFFFAOYSA-N 0.000 description 1
OFEUQEUSBJIWCY-UHFFFAOYSA-N 2-pent-4-enyl-3-propan-2-yloxirane Chemical compound CC(C)C1OC1CCCC=C OFEUQEUSBJIWCY-UHFFFAOYSA-N 0.000 description 1
OTLNPYWUJOZPPA-UHFFFAOYSA-M 4-nitrobenzoate Chemical compound [O-]C(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-M 0.000 description 1
101150034533 ATIC gene Proteins 0.000 description 1
LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
HIBWGGKDGCBPTA-UHFFFAOYSA-N C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 HIBWGGKDGCBPTA-UHFFFAOYSA-N 0.000 description 1
239000005046 Chlorosilane Substances 0.000 description 1
241001050985 Disco Species 0.000 description 1
241000490229 Eucephalus Species 0.000 description 1
238000005727 Friedel-Crafts reaction Methods 0.000 description 1
241000282337 Nasua nasua Species 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
229910020485 SiO4/2 Inorganic materials 0.000 description 1
241000950638 Symphysodon discus Species 0.000 description 1
150000008062 acetophenones Chemical class 0.000 description 1
238000013006 addition curing Methods 0.000 description 1
230000002730 additional effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
125000003368 amide group Chemical group 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
208000027697 autoimmune lymphoproliferative syndrome due to CTLA4 haploinsuffiency Diseases 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
125000006267 biphenyl group Chemical group 0.000 description 1
YSXJIDHYEFYSON-UHFFFAOYSA-N bis(4-dodecylphenyl)iodanium Chemical compound C1=CC(CCCCCCCCCCCC)=CC=C1[I+]C1=CC=C(CCCCCCCCCCCC)C=C1 YSXJIDHYEFYSON-UHFFFAOYSA-N 0.000 description 1
OMCZICOPCUYJDB-UHFFFAOYSA-N bis(4-tridecylphenyl)iodanium Chemical compound C1=CC(CCCCCCCCCCCCC)=CC=C1[I+]C1=CC=C(CCCCCCCCCCCCC)C=C1 OMCZICOPCUYJDB-UHFFFAOYSA-N 0.000 description 1
FSIJKGMIQTVTNP-UHFFFAOYSA-N bis(ethenyl)-methyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C=C)C=C FSIJKGMIQTVTNP-UHFFFAOYSA-N 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
238000004891 communication Methods 0.000 description 1
FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 description 1
LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
229920006240 drawn fiber Polymers 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000002657 fibrous material Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
230000006870 function Effects 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
101150085091 lat-2 gene Proteins 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
238000013508 migration Methods 0.000 description 1
230000005012 migration Effects 0.000 description 1
238000002156 mixing Methods 0.000 description 1
YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
229920003986 novolac Polymers 0.000 description 1
HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
125000000466 oxiranyl group Chemical group 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000000123 paper Substances 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000003847 radiation curing Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
238000007142 ring opening reaction Methods 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229920005573 silicon-containing polymer Polymers 0.000 description 1
230000000391 smoking effect Effects 0.000 description 1
241000894007 species Species 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
238000012360 testing method Methods 0.000 description 1
XBEADGFTLHRJRB-UHFFFAOYSA-N undecylbenzene Chemical class CCCCCCCCCCCC1=CC=CC=C1 XBEADGFTLHRJRB-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/106—Single coatings

Landscapes

Life Sciences & Earth Sciences (AREA)
Chemical & Material Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Geochemistry & Mineralogy (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Paints Or Removers (AREA)
Epoxy Resins (AREA)
Surface Treatment Of Glass Fibres Or Filaments (AREA)

CA000469072A 1984-11-30 1984-11-30 Fibres optiques avec revetement de diorganopolysiloxane et photo-initiateur catalytique Expired CA1256821A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000469072A CA1256821A (fr)	1984-11-30	1984-11-30	Fibres optiques avec revetement de diorganopolysiloxane et photo-initiateur catalytique

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000469072A CA1256821A (fr)	1984-11-30	1984-11-30	Fibres optiques avec revetement de diorganopolysiloxane et photo-initiateur catalytique

Publications (1)

Publication Number	Publication Date
CA1256821A true CA1256821A (fr)	1989-07-04

Family

ID=4129263

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000469072A Expired CA1256821A (fr)	1984-11-30	1984-11-30	Fibres optiques avec revetement de diorganopolysiloxane et photo-initiateur catalytique

Country Status (1)

Country	Link
CA (1)	CA1256821A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5381504A (en) *	1993-11-15	1995-01-10	Minnesota Mining And Manufacturing Company	Optical fiber element having a permanent protective coating with a Shore D hardness value of 65 or more
US5523374A (en) *	1992-12-03	1996-06-04	Hercules Incorporated	Curable and cured organosilicon compositions

1984
- 1984-11-30 CA CA000469072A patent/CA1256821A/fr not_active Expired

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5523374A (en) *	1992-12-03	1996-06-04	Hercules Incorporated	Curable and cured organosilicon compositions
US5381504A (en) *	1993-11-15	1995-01-10	Minnesota Mining And Manufacturing Company	Optical fiber element having a permanent protective coating with a Shore D hardness value of 65 or more
USRE36146E (en) *	1993-11-15	1999-03-16	Minnesota Mining And Manufacturing Company	Optical fiber element having a permanent protective coating with a shore D hardness value of 65 or more

Legal Events

Date	Code	Title	Description
2006-07-04	MKEX	Expiry

Publication	Publication Date	Title
US4689248A (en)	1987-08-25	Silicone coated optical fibers
CA1212796A (fr)	1986-10-14	Fibres optiques de verre, revetues de melanges a base de polyepoxyde, reticulables a l'aide de cations
EP0464706B1 (fr)	1995-08-30	Composition de silicone durcissable par rayonnement ultraviolet
CA1218494A (fr)	1987-02-24	Compositions de silicium a dispersion temporisee durcies aux ultraviolets
US5240971A (en)	1993-08-31	UV-curable epoxysilicone-polyether block copolymers
US4640967A (en)	1987-02-03	Ultraviolet radiation-curable silicone release compositions with epoxy and/or acrylic functionality
US5227410A (en)	1993-07-13	Uv-curable epoxysilicone-polyether block copolymers
US5310601A (en)	1994-05-10	Epoxy-functionalized siloxane resin copolymers as controlled release additives
US4317616A (en)	1982-03-02	Fluorosiloxane optical cladding
JP5324213B2 (ja)	2013-10-23	エポキシ官能性ポリシロキサン、シリコーン組成物、および被覆された光ファイバ
DE19615489A1 (de)	1996-10-31	UV-härtbare Epoxysilicon-Mischungszusammensetzungen
US5512605A (en)	1996-04-30	One-part UV-curable epoxy silicone compositions
US4835057A (en)	1989-05-30	Glass fibers having organosilsesquioxane coatings and claddings
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