CA1256903A - Methode de preparation d'alcools aliphatiques de 2 a 6 carbones - Google Patents

Methode de preparation d'alcools aliphatiques de 2 a 6 carbones

Info

Publication number: CA1256903A
Authority: CA; Canada
Prior art keywords: catalyst; weight percent; surface area; aliphatic alcohols; micromoles
Prior art date: 1986-08-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000516720A

Other languages

English (en)

Inventor

Edwin R. Kerr, (Deceased)

Michael V. Grazioso

Richard F. Love

David A. Storm

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Texaco Development Corp

Original Assignee

Texaco Development Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-08-25

Filing date

1986-08-25

Publication date

1989-07-04

1986-08-25 Application filed by Texaco Development Corp filed Critical Texaco Development Corp

1986-08-25 Priority to CA000516720A priority Critical patent/CA1256903A/fr

1989-07-04 Application granted granted Critical

1989-07-04 Publication of CA1256903A publication Critical patent/CA1256903A/fr

Status Expired legal-status Critical Current

Links

-1 aliphatic alcohols Chemical class 0.000 title claims abstract description 28
238000004519 manufacturing process Methods 0.000 title description 16
239000003054 catalyst Substances 0.000 claims abstract description 107
238000000034 method Methods 0.000 claims abstract description 55
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 28
239000000203 mixture Substances 0.000 claims abstract description 28
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 26
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 26
239000001257 hydrogen Substances 0.000 claims abstract description 25
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 25
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 24
229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 24
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 20
229910052802 copper Inorganic materials 0.000 claims abstract description 20
239000010949 copper Substances 0.000 claims abstract description 20
229910052751 metal Inorganic materials 0.000 claims abstract description 18
239000002184 metal Substances 0.000 claims abstract description 18
239000011733 molybdenum Substances 0.000 claims abstract description 17
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 16
229910052750 molybdenum Inorganic materials 0.000 claims abstract description 16
229910052742 iron Inorganic materials 0.000 claims abstract description 13
229910052759 nickel Inorganic materials 0.000 claims abstract description 12
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 11
239000010941 cobalt Substances 0.000 claims abstract description 11
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 11
229910052700 potassium Inorganic materials 0.000 claims abstract description 11
239000011591 potassium Substances 0.000 claims abstract description 11
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 10
229910017052 cobalt Inorganic materials 0.000 claims abstract description 10
229910052792 caesium Inorganic materials 0.000 claims abstract description 9
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 9
229910052701 rubidium Inorganic materials 0.000 claims abstract description 6
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims abstract description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 36
239000007789 gas Substances 0.000 claims description 17
150000001298 alcohols Chemical class 0.000 claims description 14
229910052783 alkali metal Inorganic materials 0.000 claims description 14
150000001340 alkali metals Chemical class 0.000 claims description 14
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 12
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 10
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
150000002739 metals Chemical class 0.000 claims description 4
YZYDPPZYDIRSJT-UHFFFAOYSA-K boron phosphate Chemical class [B+3].[O-]P([O-])([O-])=O YZYDPPZYDIRSJT-UHFFFAOYSA-K 0.000 claims description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
125000001931 aliphatic group Chemical group 0.000 claims 1
239000000395 magnesium oxide Substances 0.000 claims 1
239000000377 silicon dioxide Substances 0.000 claims 1
239000003513 alkali Substances 0.000 abstract description 10
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
239000012153 distilled water Substances 0.000 description 8
238000003786 synthesis reaction Methods 0.000 description 8
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 7
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 7
229930195733 hydrocarbon Natural products 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
239000000463 material Substances 0.000 description 6
229910000027 potassium carbonate Inorganic materials 0.000 description 6
238000004458 analytical method Methods 0.000 description 5
238000001354 calcination Methods 0.000 description 5
239000000126 substance Substances 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000000446 fuel Substances 0.000 description 3
238000002309 gasification Methods 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
229910052702 rhenium Inorganic materials 0.000 description 3
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000003245 coal Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000004817 gas chromatography Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910000480 nickel oxide Inorganic materials 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
229910000619 316 stainless steel Inorganic materials 0.000 description 1
239000002028 Biomass Substances 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
230000000274 adsorptive effect Effects 0.000 description 1
229910000272 alkali metal oxide Inorganic materials 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
150000007514 bases Chemical class 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
239000004568 cement Substances 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
229910000428 cobalt oxide Inorganic materials 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000012050 conventional carrier Substances 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
229910000476 molybdenum oxide Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000003134 recirculating effect Effects 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1

Landscapes

Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA000516720A 1986-08-25 1986-08-25 Methode de preparation d'alcools aliphatiques de 2 a 6 carbones Expired CA1256903A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000516720A CA1256903A (fr)	1986-08-25	1986-08-25	Methode de preparation d'alcools aliphatiques de 2 a 6 carbones

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000516720A CA1256903A (fr)	1986-08-25	1986-08-25	Methode de preparation d'alcools aliphatiques de 2 a 6 carbones

Publications (1)

Publication Number	Publication Date
CA1256903A true CA1256903A (fr)	1989-07-04

Family

ID=4133791

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000516720A Expired CA1256903A (fr)	1986-08-25	1986-08-25	Methode de preparation d'alcools aliphatiques de 2 a 6 carbones

Country Status (1)

Country	Link
CA (1)	CA1256903A (fr)

1986
- 1986-08-25 CA CA000516720A patent/CA1256903A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2006-08-25	MKEX	Expiry

Publication	Publication Date	Title
CA1261883A (fr)	1989-09-26	Methode de preparation d'alcools aliphatiques inferieurs
EP0110449B1 (fr)	1986-08-13	Procédé de fabrication d'un catalyseur Fischer-Tropsch, le catalyseur ainsi préparé et l'application de ce catalyseur pour la préparation d'hydrocarbures
EP0216967B1 (fr)	1990-01-03	Catalyseurs au cobalt utilisables pour la préparation d'hydrocarbures à partir de gaz de synthèse ou de méthanol et procédé utilisant ces catalyseurs
US4607056A (en)	1986-08-19	Mixed aliphatic alcohol production
US4616040A (en)	1986-10-07	Production of C2 -C6 aliphatic alcohols
Inoue et al.	1989	Hydrogenation of carbon dioxide and carbon monoxide over supported rhodium catalysts under 10 bar pressure
US4607055A (en)	1986-08-19	Aliphatic alcohol production
US5140049A (en)	1992-08-18	Method for producing olefins from H2 and CO2 using an iron carbide based catalyst
US4774220A (en)	1988-09-27	Lithium-doped gamma-alumina supported cobalt-molybdenum catalyst
US4579995A (en)	1986-04-01	Process for the conversion of methanol to hydrocarbons
US4980380A (en)	1990-12-25	Catalyst and method for producing lower aliphatic alcohols
CA1150321A (fr)	1983-07-19	Methode de preparation d'hydrocarbures insatures
Hoflund et al.	1997	Higher alcohol synthesis reaction study using K-promoted ZnO catalysts. III
US4605639A (en)	1986-08-12	Methods for making a supported iron-copper catalyst
US4436834A (en)	1984-03-13	Iron-thallium catalysts for use in CO hydrogenation and process of preparing the catalysts
US5070058A (en)	1991-12-03	Method for making a catalyst composition used in the production of lower aliphatic alcohols
US4657885A (en)	1987-04-14	Cerium promoted Fischer-Tropsch catalysts
US4565831A (en)	1986-01-21	Process for producing aromatic hydrocarbons from carbon monoxide and water
KR101653429B1 (ko)	2016-09-01	파라핀계 저급 탄화수소의 산화적 탈수소반응 방법
US4518714A (en)	1985-05-21	Process for the selective production of olefins from synthesis gas
CA1220776A (fr)	1987-04-21	Catalyseur au fer sur titane, et son emploi en synthese des hydrocarbures
US4168276A (en)	1979-09-18	Methanation
US4639431A (en)	1987-01-27	Catalysts in Fischer-Tropsch process for producing olefins
US5013764A (en)	1991-05-07	Catalyst and method for producing lower aliphatic alcohols
US4719240A (en)	1988-01-12	Cerium promoted fischer-tropsch catalysts