CA1263363A - Catalyseurs a base de fer et carbone, et production d'hydrocarbures a l'aide desdits catalyseurs - Google Patents

Catalyseurs a base de fer et carbone, et production d'hydrocarbures a l'aide desdits catalyseurs

Info

Publication number
CA1263363A
CA1263363A CA000503153A CA503153A CA1263363A CA 1263363 A CA1263363 A CA 1263363A CA 000503153 A CA000503153 A CA 000503153A CA 503153 A CA503153 A CA 503153A CA 1263363 A CA1263363 A CA 1263363A
Authority
CA
Canada
Prior art keywords
catalyst
iron
promoter
carbon
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000503153A
Other languages
English (en)
Inventor
Gary W. Rice
Stuart L. Soled
Rocco A. Fiato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/735,768 external-priority patent/US4659681A/en
Priority claimed from US06/735,769 external-priority patent/US4668647A/en
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of CA1263363A publication Critical patent/CA1263363A/fr
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/16—Making metallic powder or suspensions thereof using chemical processes
    • B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/121—Coherent waves, e.g. laser beams
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/349—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00139—Controlling the temperature using electromagnetic heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00186—Controlling or regulating processes controlling the composition of the reactive mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00189—Controlling or regulating processes controlling the stirring velocity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Electromagnetism (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA000503153A 1985-05-20 1986-03-03 Catalyseurs a base de fer et carbone, et production d'hydrocarbures a l'aide desdits catalyseurs Expired CA1263363A (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US06/735,768 US4659681A (en) 1985-05-20 1985-05-20 Promoted iron-carbon-based catalysts produced in the presence laser radiation
US06/735,769 US4668647A (en) 1985-05-20 1985-05-20 Iron carbide-based catalyst produced in the presence of laser radiation
US735,768 1985-05-20
US735,769 1985-05-20

Publications (1)

Publication Number Publication Date
CA1263363A true CA1263363A (fr) 1989-11-28

Family

ID=27112940

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000503153A Expired CA1263363A (fr) 1985-05-20 1986-03-03 Catalyseurs a base de fer et carbone, et production d'hydrocarbures a l'aide desdits catalyseurs

Country Status (5)

Country Link
EP (1) EP0202911B1 (fr)
AU (1) AU588035B2 (fr)
CA (1) CA1263363A (fr)
DE (1) DE3669445D1 (fr)
NO (1) NO167960C (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3739002A1 (de) * 1987-11-17 1989-05-24 Veba Oel Ag Metallmischoxidpulver, deren mischungen, metalloxidpulver und deren verwendung bei der katalytischen dehydrierung von kohlenwasserstoffen
US5037785A (en) * 1989-11-17 1991-08-06 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Energy, Mines And Resources Catalyst regeneration process using laser radiation
CA2042801C (fr) * 1991-05-16 1996-12-03 Michael F. Wilson Reacteur de traitement de catalyseur
US7384680B2 (en) 1997-07-21 2008-06-10 Nanogram Corporation Nanoparticle-based power coatings and corresponding structures
US6387531B1 (en) 1998-07-27 2002-05-14 Nanogram Corporation Metal (silicon) oxide/carbon composite particles
US6045769A (en) * 1997-12-08 2000-04-04 Nanogram Corporation Process for carbon production

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2608535A (en) * 1947-05-09 1952-08-26 Standard Oil Dev Co Carbon-containing fischer-tropsch catalyst and its preparation
US4134907A (en) * 1977-07-21 1979-01-16 Hazen Research, Inc. Process for enhancing the fuel value of low BTU gas
US4472513A (en) * 1980-12-29 1984-09-18 Allied Corporation Laser-synthesized catalysts
US4468474A (en) * 1983-05-16 1984-08-28 Allied Corporation Iron/silicon-based catalyst exhibiting high selectivity to C2 -C62 Fischer-Tropsch reactions
CA1220776A (fr) * 1983-07-07 1987-04-21 Rocco A. Fiato Catalyseur au fer sur titane, et son emploi en synthese des hydrocarbures

Also Published As

Publication number Publication date
NO167960B (no) 1991-09-23
NO167960C (no) 1992-01-02
DE3669445D1 (de) 1990-04-19
AU588035B2 (en) 1989-09-07
NO860860L (no) 1986-11-21
AU5754286A (en) 1986-11-27
EP0202911B1 (fr) 1990-03-14
EP0202911A1 (fr) 1986-11-26

Similar Documents

Publication Publication Date Title
US4788222A (en) Method for the production of hydrocarbons using iron-carbon-based catalysts
US4668647A (en) Iron carbide-based catalyst produced in the presence of laser radiation
US4687753A (en) Laser produced iron carbide-based catalysts
US4659681A (en) Promoted iron-carbon-based catalysts produced in the presence laser radiation
Dry Catalytic aspects of industrial Fischer-Tropsch synthesis
EP2569266B1 (fr) Procédé de production d'oléfines légères à partir d'un gaz de synthèse
RU2597084C2 (ru) Способ модифицирования диоксида углерода с использованием технического углерода в качестве катализатора (варианты)
Deckwer et al. Fischer-Tropsch synthesis in the slurry phase on manganese/iron catalysts
JPH0581635B2 (fr)
EP0128302A1 (fr) Catalyseur à base de fer et de silicium ayant une haute sélectivité pour des alcènes en C2-C6 dans des réactions Fischer-Tropsch entre CO et H2
Storch The Fischer-Tropsch and related processes for synthesis of hydrocarbons by hydrogenation of carbon monoxide
WO2003087265A1 (fr) Procede de synthese d'hydrocarbures au moyen d'un catalyseur de fer ameliore aux alcalis
Das et al. Conversion of syngas to light olefins over silicalite-1 supported iron and cobalt catalysts: Effect of manganese addition
EP0202911B1 (fr) Catalyseurs à base de fer-carbone et une méthode de production d'hydrocarbures utilisant ces catalyseurs
US2735862A (en) Synthesis of hydrocarbons with iron-cobalt catalyst
CN108970637B (zh) 一种催化剂及合成气直接转化制液体燃料联产低碳烯烃的方法
US4532229A (en) Process for preparing a Fe-Co catalyst slurry system for alpha olefin production
WO2000050366A1 (fr) Procede relatif a l'elaboration d'hydrocarbures aromatiques a partir d'hydrocarbures c¿1-4?
Bi et al. Selective Production of C4 Hydrocarbons from Syngas Using Fe‐Co/ZrO2 and SO42—/ZrO2 Catalysts
AU2022300502A1 (en) Hydrogen producing device and hydrogen producing method
Bacaud et al. Development of a new iron catalyst for the direct liquefaction of coal
Davis Technology development for iron Fischer-Tropsch catalysts
Jackson et al. Supported nickel catalysts: Hydrogenolysis of ethane, propane, n-butane and iso-butane over alumina-, molybdena-, and silica-supported nickel catalysts
US4624967A (en) Fe-Co catalyst slurry system for use in alpha olefin production
Hager et al. Relative activity of nanoscale iron oxide, iron carbide, and iron sulfide catalyst precursors for the liquefaction of a subbituminous coal

Legal Events

Date Code Title Description
MKLA Lapsed