CA1264051A - Catalyseurs et leurs supports - Google Patents

Catalyseurs et leurs supports

Info

Publication number: CA1264051A
Authority: CA; Canada
Prior art keywords: composition; catalyst; particles; weight percent; alumina
Prior art date: 1984-10-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000491963A

Other languages

English (en)

Inventor

Roger J. Lussier

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co

Original Assignee

WR Grace and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-10-05

Filing date

1985-10-01

Publication date

1989-12-27

1985-10-01 Application filed by WR Grace and Co filed Critical WR Grace and Co

1989-12-27 Application granted granted Critical

1989-12-27 Publication of CA1264051A publication Critical patent/CA1264051A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 53
239000000203 mixture Substances 0.000 claims abstract description 32
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 19
238000005336 cracking Methods 0.000 claims abstract description 11
238000004523 catalytic cracking Methods 0.000 claims abstract description 9
229930195733 hydrocarbon Natural products 0.000 claims abstract description 9
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 9
229910052596 spinel Inorganic materials 0.000 claims abstract description 8
239000011029 spinel Substances 0.000 claims abstract description 8
229910052720 vanadium Inorganic materials 0.000 claims abstract description 7
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 6
230000003197 catalytic effect Effects 0.000 claims abstract description 5
229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims abstract description 4
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 4
238000001354 calcination Methods 0.000 claims abstract description 3
239000011238 particulate composite Substances 0.000 claims abstract 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
239000010457 zeolite Substances 0.000 claims description 17
239000005995 Aluminium silicate Substances 0.000 claims description 16
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
235000012211 aluminium silicate Nutrition 0.000 claims description 16
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 16
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 15
229910021536 Zeolite Inorganic materials 0.000 claims description 13
238000000034 method Methods 0.000 claims description 13
239000002245 particle Substances 0.000 claims description 11
239000011230 binding agent Substances 0.000 claims description 10
239000002131 composite material Substances 0.000 claims description 9
239000000377 silicon dioxide Substances 0.000 claims description 7
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
229910052921 ammonium sulfate Inorganic materials 0.000 claims description 6
235000011130 ammonium sulphate Nutrition 0.000 claims description 6
239000012530 fluid Substances 0.000 claims description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
229910052782 aluminium Inorganic materials 0.000 claims description 3
238000001694 spray drying Methods 0.000 claims description 3
238000002156 mixing Methods 0.000 claims description 2
238000005406 washing Methods 0.000 claims description 2
239000000243 solution Substances 0.000 claims 4
229910000272 alkali metal oxide Inorganic materials 0.000 claims 2
150000001342 alkaline earth metals Chemical class 0.000 claims 2
239000007864 aqueous solution Substances 0.000 claims 1
238000005342 ion exchange Methods 0.000 claims 1
239000004927 clay Substances 0.000 abstract description 18
239000003518 caustics Substances 0.000 abstract description 10
229910052783 alkali metal Inorganic materials 0.000 abstract description 2
150000001340 alkali metals Chemical class 0.000 abstract description 2
238000002386 leaching Methods 0.000 abstract 1
239000004005 microsphere Substances 0.000 description 18
238000006243 chemical reaction Methods 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
229910001868 water Inorganic materials 0.000 description 11
239000011148 porous material Substances 0.000 description 10
230000000694 effects Effects 0.000 description 9
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
239000000571 coke Substances 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
150000002739 metals Chemical class 0.000 description 5
229910052761 rare earth metal Inorganic materials 0.000 description 5
150000002910 rare earth metals Chemical group 0.000 description 5
230000009849 deactivation Effects 0.000 description 4
230000014759 maintenance of location Effects 0.000 description 4
239000000463 material Substances 0.000 description 4
239000002002 slurry Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000007921 spray Substances 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
239000002585 base Substances 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
238000009826 distribution Methods 0.000 description 2
150000002500 ions Chemical group 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
229910001415 sodium ion Inorganic materials 0.000 description 2
-1 sodium silicate Chemical class 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910017974 NH40H Inorganic materials 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
230000032683 aging Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000012013 faujasite Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000004231 fluid catalytic cracking Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000006187 pill Substances 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000007669 thermal treatment Methods 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1

Landscapes

Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000491963A 1984-10-05 1985-10-01 Catalyseurs et leurs supports Expired CA1264051A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US65785984A	1984-10-05	1984-10-05
US657,859		1984-10-05

Publications (1)

Publication Number	Publication Date
CA1264051A true CA1264051A (fr)	1989-12-27

Family

ID=24638954

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000491963A Expired CA1264051A (fr)	1984-10-05	1985-10-01	Catalyseurs et leurs supports

Country Status (3)

Country	Link
JP (1)	JPS6190736A (fr)
AU (1)	AU584361B2 (fr)
CA (1)	CA1264051A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7307038B2 (en) *	2002-10-21	2007-12-11	W.R. Grace & Co. -Conn.	NOx reduction compositions for use in FCC processes

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS52148028A (en) *	1976-06-04	1977-12-08	Toa Nenryo Kogyo Kk	Conversion of c8 aromatic hydrocarbon
US4458023A (en) *	1981-08-10	1984-07-03	W. R. Grace & Co.	Catalyst manufacture
NL8301731A (nl) *	1982-05-21	1983-12-16	Grace W R & Co	Katalysator en katalysatordrager, werkwijze voor de bereiding daarvan, alsmede werkwijze voor het kraken van koolwaterstoffen onder toepassing van deze katalysator.

1985
- 1985-10-01 CA CA000491963A patent/CA1264051A/fr not_active Expired
- 1985-10-02 JP JP21815885A patent/JPS6190736A/ja active Pending
- 1985-10-03 AU AU48236/85A patent/AU584361B2/en not_active Ceased

Also Published As

Publication number	Publication date
JPS6190736A (ja)	1986-05-08
AU584361B2 (en)	1989-05-25
AU4823685A (en)	1986-04-10

Legal Events

Date	Code	Title	Description
1994-06-27	MKLA	Lapsed

Publication	Publication Date	Title
US4458023A (en)	1984-07-03	Catalyst manufacture
CA1140102A (fr)	1983-01-25	Catalyseur a base d'hydrogel de silice-alumine
CA1160200A (fr)	1984-01-10	Preparation d'un agent de catalyse
US5304299A (en)	1994-04-19	Catalytic cracking catalysts and additives
US5168086A (en)	1992-12-01	Catalytic cracking catalysis
CA2080773C (fr)	2003-07-01	Catalyseurs pour craquage catalytique de bayerite et/ou d'eta alumine
EP1244520B1 (fr)	2005-06-15	Procede de preparation d'un aluminophosphate mesoporeux thermiquement stable et de grande surface specifique
US4843052A (en)	1989-06-27	Acid-reacted metakaolin catalyst and catalyst support compositions
US4247420A (en)	1981-01-27	Hydrocarbon conversion catalyst preparation
US4847225A (en)	1989-07-11	Catalysts and catalyst supports
US4339354A (en)	1982-07-13	Hydrocarbon conversion catalysts
US5306417A (en)	1994-04-26	Catalytic cracking process utilizing a silica modified bayerite and/or eta alumina-containing catalyst
US3867310A (en)	1975-02-18	Catalyst compositions
US4376039A (en)	1983-03-08	Hydrocarbon conversion catalysts and processes utilizing the same
US4929338A (en)	1990-05-29	Catalytic cracking catalyst and process
CA1226269A (fr)	1987-09-01	Catalyseur et procede de craquage
GB2085861A (en)	1982-05-06	Thermally-stabilised/aluminium- exchanged type Y zeolite
US4940531A (en)	1990-07-10	Catalytic cracking process employing an acid-reacted metakaolin catalyst
GB2109696A (en)	1983-06-08	Method for preparing a zeolite- containing fluid cracking catalyst
CA1131193A (fr)	1982-09-07	Catalyseur pour le cracking ameliorant l'indice d'octane
US4894143A (en)	1990-01-16	Catalytic cracking process employing an aluminum silicon spinel-mullite-gamma alumia containing catalyst
CA1264051A (fr)	1989-12-27	Catalyseurs et leurs supports
US4920087A (en)	1990-04-24	Vanadium scavenging compositions
EP0208868B1 (fr)	1990-02-07	Procédé et catalyseur de craquage
GB2084892A (en)	1982-04-21	Hydrocarbon conversion zeolite- containing catalysts and processes utilizing the same