CA1267347A - Particules de blanchiment enrobees de savon - Google Patents

Particules de blanchiment enrobees de savon

Info

Publication number: CA1267347A
Authority: CA; Canada
Prior art keywords: particles; soap; coating; fatty acid; binder
Prior art date: 1986-12-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000526143A

Other languages

English (en)

Inventor

Kil W. Chun

David J. Lang

Edward Santos

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-12-23

Filing date

1986-12-23

Publication date

1990-04-03

1986-12-23 Application filed by Unilever PLC filed Critical Unilever PLC

1986-12-23 Priority to CA000526143A priority Critical patent/CA1267347A/fr

1990-04-03 Application granted granted Critical

1990-04-03 Publication of CA1267347A publication Critical patent/CA1267347A/fr

2007-04-03 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

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239000002245 particle Substances 0.000 title claims abstract description 48
239000007844 bleaching agent Substances 0.000 title abstract description 19
239000000203 mixture Substances 0.000 claims abstract description 50
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 33
239000000194 fatty acid Substances 0.000 claims abstract description 33
229930195729 fatty acid Natural products 0.000 claims abstract description 33
150000004665 fatty acids Chemical class 0.000 claims abstract description 28
239000000463 material Substances 0.000 claims abstract description 23
230000001590 oxidative effect Effects 0.000 claims abstract description 22
239000011230 binding agent Substances 0.000 claims abstract description 19
238000004061 bleaching Methods 0.000 claims abstract description 19
238000000034 method Methods 0.000 claims abstract description 19
150000003839 salts Chemical class 0.000 claims abstract description 15
239000003085 diluting agent Substances 0.000 claims abstract description 12
239000000758 substrate Substances 0.000 claims abstract description 5
238000004519 manufacturing process Methods 0.000 claims abstract 2
238000000576 coating method Methods 0.000 claims description 44
239000011248 coating agent Substances 0.000 claims description 42
239000000460 chlorine Substances 0.000 claims description 34
229910052801 chlorine Inorganic materials 0.000 claims description 33
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 32
-1 alkali metal fatty acid Chemical class 0.000 claims description 21
239000004744 fabric Substances 0.000 claims description 15
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid ester group Chemical group C(CCCCCCCCCCC)(=O)O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 13
238000002844 melting Methods 0.000 claims description 11
230000008569 process Effects 0.000 claims description 11
229910052783 alkali metal Inorganic materials 0.000 claims description 10
230000008018 melting Effects 0.000 claims description 10
239000007771 core particle Substances 0.000 claims description 9
239000003599 detergent Substances 0.000 claims description 8
235000019832 sodium triphosphate Nutrition 0.000 claims description 8
239000002904 solvent Substances 0.000 claims description 7
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
150000001340 alkali metals Chemical class 0.000 claims description 6
239000012530 fluid Substances 0.000 claims description 6
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 5
239000005639 Lauric acid Substances 0.000 claims description 5
238000013019 agitation Methods 0.000 claims description 4
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
229910052794 bromium Inorganic materials 0.000 claims description 4
239000004094 surface-active agent Substances 0.000 claims description 4
125000000129 anionic group Chemical group 0.000 claims description 3
238000002156 mixing Methods 0.000 claims description 3
239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
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235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
150000001298 alcohols Chemical class 0.000 claims description 2
239000003093 cationic surfactant Substances 0.000 claims description 2
150000002170 ethers Chemical class 0.000 claims description 2
238000005507 spraying Methods 0.000 claims description 2
238000009835 boiling Methods 0.000 claims 5
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
239000012736 aqueous medium Substances 0.000 claims 1
239000000919 ceramic Substances 0.000 claims 1
150000002148 esters Chemical class 0.000 claims 1
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150000002367 halogens Chemical class 0.000 abstract description 10
239000011162 core material Substances 0.000 description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
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238000003853 Pinholing Methods 0.000 description 9
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229910052708 sodium Inorganic materials 0.000 description 8
239000011734 sodium Substances 0.000 description 8
238000005406 washing Methods 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 7
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MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 4
238000005054 agglomeration Methods 0.000 description 3
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238000004090 dissolution Methods 0.000 description 3
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235000019488 nut oil Nutrition 0.000 description 3
238000011084 recovery Methods 0.000 description 3
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QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
230000009471 action Effects 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000004140 cleaning Methods 0.000 description 2
230000001427 coherent effect Effects 0.000 description 2
239000008358 core component Substances 0.000 description 2
239000000975 dye Substances 0.000 description 2
238000009472 formulation Methods 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
238000012545 processing Methods 0.000 description 2
239000008149 soap solution Substances 0.000 description 2
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239000007921 spray Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
SFRLSTJPMFGBDP-UHFFFAOYSA-N 1,2-diphosphonoethylphosphonic acid Chemical compound OP(O)(=O)CC(P(O)(O)=O)P(O)(O)=O SFRLSTJPMFGBDP-UHFFFAOYSA-N 0.000 description 1
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
UETRXHVBFZAHHT-UHFFFAOYSA-N 1,3-dichloro-5-(2-methylpropyl)imidazolidine-2,4-dione Chemical compound CC(C)CC1N(Cl)C(=O)N(Cl)C1=O UETRXHVBFZAHHT-UHFFFAOYSA-N 0.000 description 1
OFTZZDZZNXTWFO-UHFFFAOYSA-N 1,3-dichloro-5-ethyl-5-methylimidazolidine-2,4-dione Chemical compound CCC1(C)N(Cl)C(=O)N(Cl)C1=O OFTZZDZZNXTWFO-UHFFFAOYSA-N 0.000 description 1
KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
WCVOGSZTONGSQY-UHFFFAOYSA-N 2,4,6-trichloroanisole Chemical compound COC1=C(Cl)C=C(Cl)C=C1Cl WCVOGSZTONGSQY-UHFFFAOYSA-N 0.000 description 1
PJVDOKCFHXPXFM-UHFFFAOYSA-N 2-N,4-N,6-N-tribromo-1,3,5-triazine-2,4,6-triamine Chemical compound BrNC1=NC(=NC(=N1)NBr)NBr PJVDOKCFHXPXFM-UHFFFAOYSA-N 0.000 description 1
TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
KEPNSIARSTUPGS-UHFFFAOYSA-N 2-n,4-n,6-n-trichloro-1,3,5-triazine-2,4,6-triamine Chemical compound ClNC1=NC(NCl)=NC(NCl)=N1 KEPNSIARSTUPGS-UHFFFAOYSA-N 0.000 description 1
SPUFTPUOEHLZRQ-UHFFFAOYSA-N 3,7,9-tribromo-2,6,8-trioxopurine-1-carbonitrile Chemical compound BrN1C(N(C=2N(C(N(C(C1=2)=O)C#N)=O)Br)Br)=O SPUFTPUOEHLZRQ-UHFFFAOYSA-N 0.000 description 1
HUFNOZMYOQJBKF-UHFFFAOYSA-N 4,5-dibromo-2,6,8-trioxo-7,9-dihydro-3H-purine-1-carbonitrile Chemical compound BrC12NC(NC1(NC(N(C2=O)C#N)=O)Br)=O HUFNOZMYOQJBKF-UHFFFAOYSA-N 0.000 description 1
WLRZLHCGXUHRIG-UHFFFAOYSA-N 5-(2-methylpropyl)imidazolidine-2,4-dione Chemical compound CC(C)CC1NC(=O)NC1=O WLRZLHCGXUHRIG-UHFFFAOYSA-N 0.000 description 1
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229940068041 phytic acid Drugs 0.000 description 1
235000002949 phytic acid Nutrition 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920000193 polymethacrylate Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
IFIDXBCRSWOUSB-UHFFFAOYSA-N potassium;1,3-dichloro-1,3,5-triazinane-2,4,6-trione Chemical compound [K+].ClN1C(=O)NC(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-N 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
BALXUFOVQVENIU-KXNXZCPBSA-N pseudoephedrine hydrochloride Chemical compound [H+].[Cl-].CN[C@@H](C)[C@@H](O)C1=CC=CC=C1 BALXUFOVQVENIU-KXNXZCPBSA-N 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000011160 research Methods 0.000 description 1
239000011369 resultant mixture Substances 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
CMXPERZAMAQXSF-UHFFFAOYSA-M sodium;1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;1,8-dihydroxyanthracene-9,10-dione Chemical compound [Na+].O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O.CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC CMXPERZAMAQXSF-UHFFFAOYSA-M 0.000 description 1
KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
NSUYGRHTCQVYET-UHFFFAOYSA-J tetrapotassium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate;1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound [K+].[K+].[K+].[K+].[O-]C1=NC(=O)N(Cl)C(=O)N1Cl.[O-]C1=NC(=O)N(Cl)C(=O)N1Cl.[O-]C1=NC(=O)N(Cl)C(=O)N1Cl.[O-]C1=NC(=O)N(Cl)C(=O)N1Cl.ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O NSUYGRHTCQVYET-UHFFFAOYSA-J 0.000 description 1
238000004448 titration Methods 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
229910000406 trisodium phosphate Inorganic materials 0.000 description 1
235000019801 trisodium phosphate Nutrition 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Landscapes

Detergent Compositions (AREA)

CA000526143A 1986-12-23 1986-12-23 Particules de blanchiment enrobees de savon Expired - Fee Related CA1267347A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000526143A CA1267347A (fr)	1986-12-23	1986-12-23	Particules de blanchiment enrobees de savon

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000526143A CA1267347A (fr)	1986-12-23	1986-12-23	Particules de blanchiment enrobees de savon

Publications (1)

Publication Number	Publication Date
CA1267347A true CA1267347A (fr)	1990-04-03

Family

ID=4134620

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000526143A Expired - Fee Related CA1267347A (fr)	1986-12-23	1986-12-23	Particules de blanchiment enrobees de savon

Country Status (1)

Country	Link
CA (1)	CA1267347A (fr)

1986
- 1986-12-23 CA CA000526143A patent/CA1267347A/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1992-10-05	MKLA	Lapsed

Publication	Publication Date	Title
US4655780A (en)	1987-04-07	Encapsulated bleach particles coated with a mixture of C16 -C18 and C12 -C14 fatty acid soaps
US4713079A (en)	1987-12-15	Particles containing dihalohydantoin bleach in a diluted core
CA1095662A (fr)	1981-02-17	Traduction non-disponible
US3042621A (en)	1962-07-03	Detergent composition
US4279764A (en)	1981-07-21	Encapsulated bleaches and methods of preparing them
US4327151A (en)	1982-04-27	Encapsulated bleaches and methods for their preparation
US5407598A (en)	1995-04-18	Shaped solid bleach with encapsulate source of bleach
US4532063A (en)	1985-07-30	Dissolvable bleach sheet
AU605682B2 (en)	1991-01-17	Encapsulated photoactivator dyes for detergent use
EP0070067B2 (fr)	1990-02-07	Produit de blanchiment pour le linge avec libération contrôlée de produit de blanchiment
CA1259543A (fr)	1989-09-19	Methode de preparation de detergents solides
CA1232413A (fr)	1988-02-09	Agents de lessive assouplisseur de tissus
JPS5842240B2 (ja)	1983-09-17	ユウキエンソヒヨウハクザイリユウシ
CA1269014A (fr)	1990-05-15	Pastilles contenant un agent de blanchiment halogene actif dans un centre dilue
JPH037720B2 (fr)	1991-02-04
US4526699A (en)	1985-07-02	Encapsulated bleach composition and method of preparation
US3265624A (en)	1966-08-09	Detergent composition
CA1267347A (fr)	1990-04-03	Particules de blanchiment enrobees de savon
EP0328190B1 (fr)	1994-05-04	Composition détergente de forme particulaire
JPH0354158B2 (fr)	1991-08-19
CA1054311A (fr)	1979-05-15	Procede d'enrobage
CA2151475C (fr)	2005-11-22	Compose solide moule contenant un agent de blanchiment oxydant en poudre et un agent de blanchiment encapsule
NO170946B (no)	1992-09-21	Blekemiddel som er saerlig effektivt for lavtemperaturbleking av toey, samt bleke- og vaskemiddelblanding