CA1267743A - Melanges transparents de polymethylmethacrylate et de certains copolymeres de styrene - Google Patents

Melanges transparents de polymethylmethacrylate et de certains copolymeres de styrene

Info

Publication number: CA1267743A
Authority: CA; Canada
Prior art keywords: component; composition; styrene; weight percent; monomer
Prior art date: 1984-11-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000468002A

Other languages

English (en)

Inventor

Henno Keskkula

Donald A. Maass

Kathleen M. Mccreedy

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-11-16

Filing date

1984-11-16

Publication date

1990-04-10

1984-11-16 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1984-11-16 Priority to CA000468002A priority Critical patent/CA1267743A/fr

1990-04-10 Application granted granted Critical

1990-04-10 Publication of CA1267743A publication Critical patent/CA1267743A/fr

2007-04-10 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 111
239000004926 polymethyl methacrylate Substances 0.000 title claims abstract description 57
229920003229 poly(methyl methacrylate) Polymers 0.000 title claims abstract description 48
229920001577 copolymer Polymers 0.000 title claims abstract description 39
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract description 29
239000000178 monomer Substances 0.000 claims abstract description 24
239000002253 acid Substances 0.000 claims abstract description 14
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 14
229920002554 vinyl polymer Polymers 0.000 claims abstract description 12
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 27
229920000642 polymer Polymers 0.000 claims description 27
229920001971 elastomer Polymers 0.000 claims description 24
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 23
239000005060 rubber Substances 0.000 claims description 21
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 19
238000002835 absorbance Methods 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000002245 particle Substances 0.000 claims description 8
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 8
229920000638 styrene acrylonitrile Polymers 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 7
239000004615 ingredient Substances 0.000 claims description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
239000005062 Polybutadiene Substances 0.000 claims description 4
125000003118 aryl group Chemical group 0.000 claims description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
229920002857 polybutadiene Polymers 0.000 claims description 4
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 3
239000007787 solid Substances 0.000 claims description 3
229920003051 synthetic elastomer Polymers 0.000 claims description 3
239000005061 synthetic rubber Substances 0.000 claims description 3
230000000295 complement effect Effects 0.000 claims description 2
229920003052 natural elastomer Polymers 0.000 claims description 2
229920001194 natural rubber Polymers 0.000 claims description 2
238000012360 testing method Methods 0.000 claims description 2
229920001169 thermoplastic Polymers 0.000 claims description 2
230000016776 visual perception Effects 0.000 claims description 2
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 2
238000009472 formulation Methods 0.000 claims 1
229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 27
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract description 19
239000004676 acrylonitrile butadiene styrene Substances 0.000 abstract description 19
239000011347 resin Substances 0.000 abstract description 18
229920005989 resin Polymers 0.000 abstract description 18
FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 18
229940114077 acrylic acid Drugs 0.000 description 14
238000002156 mixing Methods 0.000 description 14
239000000463 material Substances 0.000 description 7
-1 aromatic radical Chemical class 0.000 description 6
238000000034 method Methods 0.000 description 6
229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
229920005479 Lucite® Polymers 0.000 description 4
150000001993 dienes Chemical class 0.000 description 4
229920002959 polymer blend Polymers 0.000 description 4
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000000155 melt Substances 0.000 description 3
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 3
239000000126 substance Substances 0.000 description 3
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical class C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 2
ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
239000004793 Polystyrene Substances 0.000 description 2
229920006383 Tyril Polymers 0.000 description 2
239000000654 additive Substances 0.000 description 2
FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
238000013329 compounding Methods 0.000 description 2
230000006835 compression Effects 0.000 description 2
238000007906 compression Methods 0.000 description 2
239000000806 elastomer Substances 0.000 description 2
239000008187 granular material Substances 0.000 description 2
229920000126 latex Polymers 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
238000010587 phase diagram Methods 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000758 substrate Substances 0.000 description 2
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
LLVWLCAZSOLOTF-UHFFFAOYSA-N 1-methyl-4-[1,4,4-tris(4-methylphenyl)buta-1,3-dienyl]benzene Chemical compound C1=CC(C)=CC=C1C(C=1C=CC(C)=CC=1)=CC=C(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 LLVWLCAZSOLOTF-UHFFFAOYSA-N 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
YMOONIIMQBGTDU-UHFFFAOYSA-N 2-bromoethenylbenzene Chemical class BrC=CC1=CC=CC=C1 YMOONIIMQBGTDU-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 description 1
VJOWMORERYNYON-UHFFFAOYSA-N 5-ethenyl-2-methylpyridine Chemical compound CC1=CC=C(C=C)C=N1 VJOWMORERYNYON-UHFFFAOYSA-N 0.000 description 1
WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
101100459319 Arabidopsis thaliana VIII-2 gene Proteins 0.000 description 1
239000004604 Blowing Agent Substances 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical group ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
101001055222 Homo sapiens Interleukin-8 Proteins 0.000 description 1
102100026236 Interleukin-8 Human genes 0.000 description 1
229920000459 Nitrile rubber Polymers 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
238000000149 argon plasma sintering Methods 0.000 description 1
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000000460 chlorine Chemical group 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
229920001198 elastomeric copolymer Polymers 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012765 fibrous filler Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000004816 latex Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical group [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
238000003801 milling Methods 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000006069 physical mixture Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920005553 polystyrene-acrylate Polymers 0.000 description 1
239000005077 polysulfide Substances 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
150000008117 polysulfides Polymers 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
239000012260 resinous material Substances 0.000 description 1
241000894007 species Species 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
230000000707 stereoselective effect Effects 0.000 description 1
239000011145 styrene acrylonitrile resin Substances 0.000 description 1
229920001909 styrene-acrylic polymer Polymers 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000012780 transparent material Substances 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA000468002A 1984-11-16 1984-11-16 Melanges transparents de polymethylmethacrylate et de certains copolymeres de styrene Expired - Fee Related CA1267743A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000468002A CA1267743A (fr)	1984-11-16	1984-11-16	Melanges transparents de polymethylmethacrylate et de certains copolymeres de styrene

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000468002A CA1267743A (fr)	1984-11-16	1984-11-16	Melanges transparents de polymethylmethacrylate et de certains copolymeres de styrene

Publications (1)

Publication Number	Publication Date
CA1267743A true CA1267743A (fr)	1990-04-10

Family

ID=4129164

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000468002A Expired - Fee Related CA1267743A (fr)	1984-11-16	1984-11-16	Melanges transparents de polymethylmethacrylate et de certains copolymeres de styrene

Country Status (1)

Country	Link
CA (1)	CA1267743A (fr)

1984
- 1984-11-16 CA CA000468002A patent/CA1267743A/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1993-10-11	MKLA	Lapsed

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