CA1268440A - Methode pour ameliorer l'indice d'octane des essences de fractionnement - Google Patents

Methode pour ameliorer l'indice d'octane des essences de fractionnement

Info

Publication number: CA1268440A
Authority: CA; Canada
Prior art keywords: zsm; gasoline; octane; zeolite; octane number
Prior art date: 1986-02-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000502641A

Other languages

English (en)

Inventor

Roger Allan Morrison

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-02-25

Filing date

1986-02-25

Publication date

1990-05-01

1986-02-25 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1986-02-25 Priority to CA000502641A priority Critical patent/CA1268440A/fr

1990-05-01 Application granted granted Critical

1990-05-01 Publication of CA1268440A publication Critical patent/CA1268440A/fr

Status Expired legal-status Critical Current

Links

TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 title claims abstract description 59
238000000034 method Methods 0.000 title claims abstract description 37
230000008569 process Effects 0.000 title claims abstract description 35
239000010457 zeolite Substances 0.000 claims abstract description 49
239000003054 catalyst Substances 0.000 claims abstract description 45
150000001336 alkenes Chemical class 0.000 claims abstract description 26
230000002378 acidificating effect Effects 0.000 claims abstract description 8
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 37
229910021536 Zeolite Inorganic materials 0.000 claims description 31
238000009835 boiling Methods 0.000 claims description 13
239000000463 material Substances 0.000 claims description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 36
238000004231 fluid catalytic cracking Methods 0.000 description 32
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
239000000047 product Substances 0.000 description 19
238000006243 chemical reaction Methods 0.000 description 17
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
239000007789 gas Substances 0.000 description 15
230000000694 effects Effects 0.000 description 14
230000006872 improvement Effects 0.000 description 14
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 12
238000005336 cracking Methods 0.000 description 10
125000003118 aryl group Chemical group 0.000 description 9
239000000203 mixture Substances 0.000 description 8
239000011148 porous material Substances 0.000 description 8
239000000377 silicon dioxide Substances 0.000 description 8
238000005804 alkylation reaction Methods 0.000 description 7
229930195733 hydrocarbon Natural products 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
239000004215 Carbon black (E152) Substances 0.000 description 6
229910000323 aluminium silicate Inorganic materials 0.000 description 6
229910052681 coesite Inorganic materials 0.000 description 6
229910052906 cristobalite Inorganic materials 0.000 description 6
239000007788 liquid Substances 0.000 description 6
235000012239 silicon dioxide Nutrition 0.000 description 6
229910052682 stishovite Inorganic materials 0.000 description 6
229910052905 tridymite Inorganic materials 0.000 description 6
230000029936 alkylation Effects 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
238000005899 aromatization reaction Methods 0.000 description 4
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
238000010025 steaming Methods 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
230000032683 aging Effects 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
-1 aliphatic olefins Chemical class 0.000 description 3
238000004939 coking Methods 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
238000002407 reforming Methods 0.000 description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
229910052793 cadmium Inorganic materials 0.000 description 2
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
238000012937 correction Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000004821 distillation Methods 0.000 description 2
239000012634 fragment Substances 0.000 description 2
239000001282 iso-butane Substances 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
238000006384 oligomerization reaction Methods 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
239000002574 poison Substances 0.000 description 2
231100000614 poison Toxicity 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
102220482905 Myotubularin-related protein 1_C71S_mutation Human genes 0.000 description 1
102220482909 Myotubularin-related protein 1_C81S_mutation Human genes 0.000 description 1
CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000008901 benefit Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
229910052676 chabazite Inorganic materials 0.000 description 1
230000008859 change Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000012013 faujasite Substances 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
238000004868 gas analysis Methods 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
238000002429 nitrogen sorption measurement Methods 0.000 description 1
239000003921 oil Substances 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
238000007363 ring formation reaction Methods 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000007740 vapor deposition Methods 0.000 description 1

Landscapes

Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000502641A 1986-02-25 1986-02-25 Methode pour ameliorer l'indice d'octane des essences de fractionnement Expired CA1268440A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000502641A CA1268440A (fr)	1986-02-25	1986-02-25	Methode pour ameliorer l'indice d'octane des essences de fractionnement

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000502641A CA1268440A (fr)	1986-02-25	1986-02-25	Methode pour ameliorer l'indice d'octane des essences de fractionnement

Publications (1)

Publication Number	Publication Date
CA1268440A true CA1268440A (fr)	1990-05-01

Family

ID=4132549

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000502641A Expired CA1268440A (fr)	1986-02-25	1986-02-25	Methode pour ameliorer l'indice d'octane des essences de fractionnement

Country Status (1)

Country	Link
CA (1)	CA1268440A (fr)

1986
- 1986-02-25 CA CA000502641A patent/CA1268440A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2000-05-01	MKLA	Lapsed

Publication	Publication Date	Title
EP0235416B1 (fr)	1991-02-06	Procédé pour améliorer l'indice d'octane d'essences craquées
US4822477A (en)	1989-04-18	Integrated process for gasoline production
Giannetto et al.	1994	Transformation of LPG into aromatic hydrocarbons and hydrogen over zeolite catalysts
US3894934A (en)	1975-07-15	Conversion of hydrocarbons with mixture of small and large pore crystalline zeolite catalyst compositions to accomplish cracking cyclization, and alkylation reactions
US3890218A (en)	1975-06-17	Upgrading aliphatic naphthas to higher octane gasoline
US6652737B2 (en)	2003-11-25	Production of naphtha and light olefins
CA2290960C (fr)	2005-03-15	Production d'olefines accrue dans un procede catalytique a l'aide de diolefines
US5000837A (en)	1991-03-19	Multistage integrated process for upgrading olefins
AU2001276996A1 (en)	2002-05-02	Production of naphtha and light olefins
US20040014593A1 (en)	2004-01-22	Hybrid catalyst for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks
CA1119547A (fr)	1982-03-09	Procede par combinaison, pour l'amelioration de l'indice d'octane de constituants c.sub.5-c.sub.6 a faible indice d'un gisement d'essence
CA2219137A1 (fr)	1996-10-03	Procede d'amelioration du naphta
EP3237581B1 (fr)	2021-05-12	Procédé de production d'hydrocarbures c2 et c3
US4871444A (en)	1989-10-03	Distillate fuel quality of FCC cycle oils
AU661863B2 (en)	1995-08-10	Hydrocarbon upgrading process
WO1998056740A1 (fr)	1998-12-17	Systeme multireacteur de production amelioree d'olefines legeres
CN1259983A (zh)	2000-07-12	反应器正向温度梯度法的烃裂解
CA1300541C (fr)	1992-05-12	Procede integre de production d'essence
RU2208624C2 (ru)	2003-07-20	Способ получения высокооктановых бензиновых фракций и ароматических углеводородов (варианты)
EP3237583A1 (fr)	2017-11-01	Procédé de production de gpl et de btx
CA1268440A (fr)	1990-05-01	Methode pour ameliorer l'indice d'octane des essences de fractionnement
US5171912A (en)	1992-12-15	Production of C5 + gasoline from butane and propane
US11591527B2 (en)	2023-02-28	Processes for producing high octane reformate having high C5+ yield
US20090182184A1 (en)	2009-07-16	Method for producing ethylene and propylene
US20040182748A1 (en)	2004-09-23	Process for production of high octane gasoline from straight run light naphtha on Pt containing HZSM - 5 molecular sieve catalyst