CA1269630A - METHODE DE FRACTIONNEMENT CATALYTIQUE A LA ZEOLITE .beta. POUR CHARGES A TENEUR DE PARAFFINE - Google Patents

METHODE DE FRACTIONNEMENT CATALYTIQUE A LA ZEOLITE .beta. POUR CHARGES A TENEUR DE PARAFFINE

Info

Publication number: CA1269630A
Authority: CA; Canada
Prior art keywords: cracking; catalyst; process according; zeolite; zeolite beta
Prior art date: 1984-12-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000497263A

Other languages

English (en)

Inventor

Clinton Robert Kennedy

Robert Adams Ware

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-12-27

Filing date

1985-12-10

Publication date

1990-05-29

1985-12-10 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1990-05-29 Application granted granted Critical

1990-05-29 Publication of CA1269630A publication Critical patent/CA1269630A/fr

2007-05-29 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000010457 zeolite Substances 0.000 title claims abstract description 109
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 101
229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 99
238000004523 catalytic cracking Methods 0.000 title claims description 32
238000005336 cracking Methods 0.000 claims abstract description 83
238000009835 boiling Methods 0.000 claims abstract description 23
239000003502 gasoline Substances 0.000 claims abstract description 21
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims abstract description 21
230000000694 effects Effects 0.000 claims abstract description 10
229930195733 hydrocarbon Natural products 0.000 claims abstract description 7
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 7
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 6
239000003054 catalyst Substances 0.000 claims description 118
238000000034 method Methods 0.000 claims description 81
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 19
238000006243 chemical reaction Methods 0.000 claims description 19
239000000377 silicon dioxide Substances 0.000 claims description 16
230000003647 oxidation Effects 0.000 claims description 11
238000007254 oxidation reaction Methods 0.000 claims description 11
229910052799 carbon Inorganic materials 0.000 claims description 9
239000001257 hydrogen Substances 0.000 claims description 9
229910052739 hydrogen Inorganic materials 0.000 claims description 9
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
229910052751 metal Inorganic materials 0.000 claims description 7
239000002184 metal Substances 0.000 claims description 7
230000001590 oxidative effect Effects 0.000 claims description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
229910052697 platinum Inorganic materials 0.000 claims description 5
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 4
229910002091 carbon monoxide Inorganic materials 0.000 claims description 4
125000004122 cyclic group Chemical group 0.000 claims description 4
230000001172 regenerating effect Effects 0.000 claims 3
239000003921 oil Substances 0.000 abstract description 43
239000012188 paraffin wax Substances 0.000 abstract description 6
230000003247 decreasing effect Effects 0.000 abstract description 2
239000007789 gas Substances 0.000 description 29
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
239000011148 porous material Substances 0.000 description 10
230000008929 regeneration Effects 0.000 description 10
238000011069 regeneration method Methods 0.000 description 10
239000000463 material Substances 0.000 description 9
230000002378 acidificating effect Effects 0.000 description 8
239000011230 binding agent Substances 0.000 description 7
239000000571 coke Substances 0.000 description 7
239000000203 mixture Substances 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
239000002245 particle Substances 0.000 description 7
239000008186 active pharmaceutical agent Substances 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 6
238000004821 distillation Methods 0.000 description 6
230000005484 gravity Effects 0.000 description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
239000003208 petroleum Substances 0.000 description 5
239000001993 wax Substances 0.000 description 5
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
229910052784 alkaline earth metal Inorganic materials 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
238000009826 distribution Methods 0.000 description 4
239000010453 quartz Substances 0.000 description 4
238000010025 steaming Methods 0.000 description 4
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000010763 heavy fuel oil Substances 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
-1 alkaline earth metal cations Chemical class 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000011324 bead Substances 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
238000000605 extraction Methods 0.000 description 2
239000012013 faujasite Substances 0.000 description 2
239000000295 fuel oil Substances 0.000 description 2
239000001307 helium Substances 0.000 description 2
229910052734 helium Inorganic materials 0.000 description 2
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
125000005842 heteroatom Chemical group 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
125000003367 polycyclic group Chemical group 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000010926 purge Methods 0.000 description 2
230000009467 reduction Effects 0.000 description 2
238000012360 testing method Methods 0.000 description 2
238000004227 thermal cracking Methods 0.000 description 2
238000011282 treatment Methods 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
LLQHSBBZNDXTIV-UHFFFAOYSA-N 6-[5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-4,5-dihydro-1,2-oxazol-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC1CC(=NO1)C1=CC2=C(NC(O2)=O)C=C1 LLQHSBBZNDXTIV-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
238000013459 approach Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
239000010771 distillate fuel oil Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000004231 fluid catalytic cracking Methods 0.000 description 1
238000005243 fluidization Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
150000002892 organic cations Chemical class 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000006187 pill Substances 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical group 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
238000005245 sintering Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000007669 thermal treatment Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA000497263A 1984-12-27 1985-12-10 METHODE DE FRACTIONNEMENT CATALYTIQUE A LA ZEOLITE .beta. POUR CHARGES A TENEUR DE PARAFFINE Expired - Lifetime CA1269630A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US68677284A	1984-12-27	1984-12-27
US686,772		1991-04-17

Publications (1)

Publication Number	Publication Date
CA1269630A true CA1269630A (fr)	1990-05-29

Family

ID=24757682

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000497263A Expired - Lifetime CA1269630A (fr)	1984-12-27	1985-12-10	METHODE DE FRACTIONNEMENT CATALYTIQUE A LA ZEOLITE .beta. POUR CHARGES A TENEUR DE PARAFFINE

Country Status (7)

Country	Link
EP (1)	EP0186447B1 (fr)
JP (1)	JPH0649869B2 (fr)
AR (1)	AR246757A1 (fr)
AU (1)	AU575451B2 (fr)
CA (1)	CA1269630A (fr)
DE (1)	DE3581517D1 (fr)
ZA (1)	ZA859839B (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5102530A (en) *	1986-03-21	1992-04-07	W. R. Grace & Co.-Conn.	Cracking catalysts with octane enhancement
US4898846A (en) *	1986-03-21	1990-02-06	W. R. Grace & Co.-Conn.	Cracking catalysts with octane enhancement
US5116794A (en) *	1988-03-30	1992-05-26	Uop	Method for enhancing the activity of zeolite beta
US5256392A (en) *	1989-06-23	1993-10-26	Fina Technology, Inc.	Modified zeolite beta method of preparation
FR2678180B1 (fr) *	1991-06-27	1995-01-27	Inst Francais Du Petrole	Catalyseur de craquage de charges hydrocarbonees riches en composes naphteniques et/ou en paraffines comprenant une zeolithe d'indice de contrainte inferieure a 1 et une matrice.
US5907073A (en) *	1998-02-24	1999-05-25	Fina Technology, Inc.	Aromatic alkylation process
US6878327B2 (en)	2002-04-19	2005-04-12	Fina Technology, Inc.	Process of making polypropylene fibers
US7268264B2 (en)	2002-10-04	2007-09-11	Fina Technology, Inc.	Critical phase alkylation process
US6987078B2 (en)	2003-10-03	2006-01-17	Fina Technology, Inc.	Alkylation and catalyst regenerative process
US11225416B2 (en)	2019-11-26	2022-01-18	Saudi Arabian Oil Company	Dry gel synthesis of nano-sized ZSM-5
US11247196B2 (en)	2019-12-04	2022-02-15	Saudi Arabian Oil Company	Zeolite with encapsulated platinum
US11148124B2 (en)	2019-12-04	2021-10-19	Saudi Arabian Oil Company	Hierarchical zeolite Y and nano-sized zeolite beta composite
US20210171687A1 (en)	2019-12-09	2021-06-10	Saudi Arabian Oil Company	Acryloyl based polymers with active end cap as corrosion inhibitors

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
USRE28341E (en) *	1964-05-01	1975-02-18		Marshall dann
NZ204093A (en) *	1982-05-18	1985-01-31	Mobil Oil Corp	Simultaneous catalytic hydrocracking and hydrodewaxing of hydrocarbon oils using zeolite beta

1985
- 1985-12-06 AU AU50866/85A patent/AU575451B2/en not_active Ceased
- 1985-12-10 CA CA000497263A patent/CA1269630A/fr not_active Expired - Lifetime
- 1985-12-19 EP EP85309274A patent/EP0186447B1/fr not_active Expired - Lifetime
- 1985-12-19 DE DE8585309274T patent/DE3581517D1/de not_active Expired - Lifetime
- 1985-12-23 ZA ZA859839A patent/ZA859839B/xx unknown
- 1985-12-27 AR AR85302744A patent/AR246757A1/es active
- 1985-12-27 JP JP60293354A patent/JPH0649869B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JPS61157581A (ja)	1986-07-17
AR246757A1 (es)	1994-09-30
JPH0649869B2 (ja)	1994-06-29
AU575451B2 (en)	1988-07-28
EP0186447B1 (fr)	1991-01-23
EP0186447A2 (fr)	1986-07-02
EP0186447A3 (en)	1987-11-11
AU5086685A (en)	1986-07-03
ZA859839B (en)	1987-08-26
DE3581517D1 (de)	1991-02-28

Legal Events

Date	Code	Title	Description
1999-05-31	MKLA	Lapsed

Publication	Publication Date	Title
US4911823A (en)	1990-03-27	Catalytic cracking of paraffinic feedstocks with zeolite beta
CA1165263A (fr)	1984-04-10	Amelioration du rendement d'indice d'octane grace a un catalyseur de craquage
US4740292A (en)	1988-04-26	Catalytic cracking with a mixture of faujasite-type zeolite and zeolite beta
CA1153973A (fr)	1983-09-20	Amelioration du taux d'octane dans le craquage catalytique
US5389232A (en)	1995-02-14	Riser cracking for maximum C3 and C4 olefin yields
US4179358A (en)	1979-12-18	Fluid cracking catalyst process using a zeolite dispersed in a magnesia-alumina-aluminum phosphate matrix
CA1218618A (fr)	1987-03-03	Fractionnement catalytique
US4137152A (en)	1979-01-30	Selective high conversion cracking process
DE69418282T2 (de)	1999-11-04	Integriertes katalytisches Krack- und Olefinen Herstellungsverfahren
CA1269630A (fr)	1990-05-29	METHODE DE FRACTIONNEMENT CATALYTIQUE A LA ZEOLITE .beta. POUR CHARGES A TENEUR DE PARAFFINE
US4994173A (en)	1991-02-19	Method of adding zsm-5 containing catalyst to fluid bed catalytic cracking units
US4927526A (en)	1990-05-22	Octane improvement of gasoline in catalytic cracking without decreasing total liquid yield
DE69419873T2 (de)	2000-04-20	Integriertes katalytisches Krack- und Olefinen Herstellungsverfahren
GB2048299A (en)	1980-12-10	Catalytic cracking process
CA2319263A1 (fr)	2000-06-02	Craquage catalytique destine a la production d'olefines
US4450241A (en)	1984-05-22	Endothermic removal of coke deposited on catalytic materials during carbo-metallic oil conversion
US7678952B2 (en)	2010-03-16	Process to prepare a gasoline
US5318692A (en)	1994-06-07	FCC for producing low emission fuels from high hydrogen and low nitrogen and aromatic feeds
GB1570682A (en)	1980-07-09	Hydrocarbon catalytic cracking process
US4521298A (en)	1985-06-04	Promotion of cracking catalyst octane yield performance
US5008000A (en)	1991-04-16	Cracking catalyst for hydrocarbon charges comprising an offretite, a zeolite and a matrix
EP0320179A2 (fr)	1989-06-14	L'utilisation d'un catalyseur additif à activité hautement équilibrée pour le craquage catalytique
WO1995002653A1 (fr)	1995-01-26	Systeme catalyseur et procede de craquage catalytique
US5173174A (en)	1992-12-22	Metal-tolerant FCC catalyst and process
EP0186446B1 (fr)	1991-05-15	Craquage catalytique avec un mélange de zéolithes de type faujasite et de type bêta