CA1270809A - Silicate de magnesium modifie au phosphore - Google Patents

Silicate de magnesium modifie au phosphore

Info

Publication number: CA1270809A
Authority: CA; Canada
Prior art keywords: phosphorus; magnesium silicate; percent; modified; magnesium
Prior art date: 1986-03-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000504846A

Other languages

English (en)

Inventor

William P. Dianis

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-03-24

Filing date

1986-03-24

Publication date

1990-06-26

1986-03-24 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1986-03-24 Priority to CA000504846A priority Critical patent/CA1270809A/fr

1990-06-26 Application granted granted Critical

1990-06-26 Publication of CA1270809A publication Critical patent/CA1270809A/fr

2007-06-26 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 40
239000011574 phosphorus Substances 0.000 title claims abstract description 40
-1 Phosphorus modified magnesium silicate Chemical class 0.000 title description 14
239000000391 magnesium silicate Substances 0.000 claims abstract description 56
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 31
150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract 3
230000002152 alkylating effect Effects 0.000 claims abstract 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 40
238000000034 method Methods 0.000 claims description 25
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 24
239000000203 mixture Substances 0.000 claims description 24
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 23
235000019792 magnesium silicate Nutrition 0.000 claims description 22
229910052919 magnesium silicate Inorganic materials 0.000 claims description 22
239000000377 silicon dioxide Substances 0.000 claims description 15
235000012239 silicon dioxide Nutrition 0.000 claims description 13
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 10
238000002441 X-ray diffraction Methods 0.000 claims description 8
229910052681 coesite Inorganic materials 0.000 claims description 8
229910052906 cristobalite Inorganic materials 0.000 claims description 8
229910052682 stishovite Inorganic materials 0.000 claims description 8
229910052905 tridymite Inorganic materials 0.000 claims description 8
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
239000005977 Ethylene Substances 0.000 claims description 7
230000029936 alkylation Effects 0.000 claims description 7
238000005804 alkylation reaction Methods 0.000 claims description 7
150000001768 cations Chemical class 0.000 claims description 7
239000011541 reaction mixture Substances 0.000 claims description 7
229910052783 alkali metal Inorganic materials 0.000 claims description 4
229910052760 oxygen Inorganic materials 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 3
239000002168 alkylating agent Substances 0.000 claims description 3
229940100198 alkylating agent Drugs 0.000 claims description 3
230000004048 modification Effects 0.000 claims description 3
238000012986 modification Methods 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims 1
235000012243 magnesium silicates Nutrition 0.000 abstract description 34
150000004760 silicates Chemical class 0.000 abstract description 11
235000014786 phosphorus Nutrition 0.000 description 28
239000010457 zeolite Substances 0.000 description 27
239000011777 magnesium Substances 0.000 description 17
238000002425 crystallisation Methods 0.000 description 16
230000008025 crystallization Effects 0.000 description 16
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 14
229910021536 Zeolite Inorganic materials 0.000 description 11
239000003054 catalyst Substances 0.000 description 11
239000000463 material Substances 0.000 description 11
230000015572 biosynthetic process Effects 0.000 description 10
238000005342 ion exchange Methods 0.000 description 10
150000003839 salts Chemical class 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 9
150000001875 compounds Chemical class 0.000 description 9
229910052749 magnesium Inorganic materials 0.000 description 9
235000001055 magnesium Nutrition 0.000 description 9
229940091250 magnesium supplement Drugs 0.000 description 9
229910001868 water Inorganic materials 0.000 description 9
235000013350 formula milk Nutrition 0.000 description 8
238000004458 analytical method Methods 0.000 description 7
238000001354 calcination Methods 0.000 description 7
239000013078 crystal Substances 0.000 description 7
238000005755 formation reaction Methods 0.000 description 7
239000000843 powder Substances 0.000 description 7
239000002904 solvent Substances 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
239000002253 acid Substances 0.000 description 5
229910000323 aluminium silicate Inorganic materials 0.000 description 5
239000000499 gel Substances 0.000 description 5
239000010453 quartz Substances 0.000 description 5
239000011734 sodium Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
JRLPEMVDPFPYPJ-UHFFFAOYSA-N 1-ethyl-4-methylbenzene Chemical compound CCC1=CC=C(C)C=C1 JRLPEMVDPFPYPJ-UHFFFAOYSA-N 0.000 description 4
GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
230000001419 dependent effect Effects 0.000 description 4
239000002808 molecular sieve Substances 0.000 description 4
238000000634 powder X-ray diffraction Methods 0.000 description 4
239000000047 product Substances 0.000 description 4
239000000376 reactant Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 4
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 3
239000004115 Sodium Silicate Substances 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
238000012512 characterization method Methods 0.000 description 3
238000004455 differential thermal analysis Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
239000011148 porous material Substances 0.000 description 3
125000001453 quaternary ammonium group Chemical group 0.000 description 3
229940032158 sodium silicate Drugs 0.000 description 3
229910052911 sodium silicate Inorganic materials 0.000 description 3
235000019794 sodium silicate Nutrition 0.000 description 3
238000006467 substitution reaction Methods 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
ZLCSFXXPPANWQY-UHFFFAOYSA-N 3-ethyltoluene Chemical compound CCC1=CC=CC(C)=C1 ZLCSFXXPPANWQY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
229910004476 SiIV Inorganic materials 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
238000004279 X-ray Guinier Methods 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910001413 alkali metal ion Inorganic materials 0.000 description 2
150000001491 aromatic compounds Chemical class 0.000 description 2
229910052796 boron Inorganic materials 0.000 description 2
230000010261 cell growth Effects 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Substances 0.000 description 2
239000004927 clay Substances 0.000 description 2
239000008119 colloidal silica Substances 0.000 description 2
229910052593 corundum Inorganic materials 0.000 description 2
229910052733 gallium Inorganic materials 0.000 description 2
229910052732 germanium Inorganic materials 0.000 description 2
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
238000001027 hydrothermal synthesis Methods 0.000 description 2
239000012535 impurity Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
238000002156 mixing Methods 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
HYFLWBNQFMXCPA-UHFFFAOYSA-N o-toluene acid methyl ester Natural products CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 2
150000003018 phosphorus compounds Chemical class 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
229910052761 rare earth metal Inorganic materials 0.000 description 2
125000005372 silanol group Chemical group 0.000 description 2
239000002002 slurry Substances 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
235000011149 sulphuric acid Nutrition 0.000 description 2
229910001845 yogo sapphire Inorganic materials 0.000 description 2
101150091111 ACAN gene Proteins 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical group CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
229910007157 Si(OH)3 Inorganic materials 0.000 description 1
229910020175 SiOH Inorganic materials 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
238000002835 absorbance Methods 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
229910000148 ammonium phosphate Inorganic materials 0.000 description 1
235000019289 ammonium phosphates Nutrition 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
230000008602 contraction Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910021485 fumed silica Inorganic materials 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
230000012010 growth Effects 0.000 description 1
125000001475 halogen functional group Chemical group 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052909 inorganic silicate Inorganic materials 0.000 description 1
229910001867 inorganic solvent Inorganic materials 0.000 description 1
239000003049 inorganic solvent Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
230000002045 lasting effect Effects 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
229910001635 magnesium fluoride Inorganic materials 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
235000012254 magnesium hydroxide Nutrition 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
239000003607 modifier Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000011368 organic material Substances 0.000 description 1
150000002897 organic nitrogen compounds Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000002903 organophosphorus compounds Chemical class 0.000 description 1
239000008188 pellet Substances 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
150000003017 phosphorus Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229910001414 potassium ion Inorganic materials 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
230000005855 radiation Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
239000012925 reference material Substances 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000012265 solid product Substances 0.000 description 1
241000894007 species Species 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229910052717 sulfur Chemical group 0.000 description 1
239000011593 sulfur Chemical group 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 1
LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
238000002076 thermal analysis method Methods 0.000 description 1
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1

Landscapes

Silicates, Zeolites, And Molecular Sieves (AREA)
Catalysts (AREA)

CA000504846A 1986-03-24 1986-03-24 Silicate de magnesium modifie au phosphore Expired - Fee Related CA1270809A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000504846A CA1270809A (fr)	1986-03-24	1986-03-24	Silicate de magnesium modifie au phosphore

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000504846A CA1270809A (fr)	1986-03-24	1986-03-24	Silicate de magnesium modifie au phosphore

Publications (1)

Publication Number	Publication Date
CA1270809A true CA1270809A (fr)	1990-06-26

Family

ID=4132724

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000504846A Expired - Fee Related CA1270809A (fr)	1986-03-24	1986-03-24	Silicate de magnesium modifie au phosphore

Country Status (1)

Country	Link
CA (1)	CA1270809A (fr)

1986
- 1986-03-24 CA CA000504846A patent/CA1270809A/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1993-12-27	MKLA	Lapsed

Publication	Publication Date	Title
US5013537A (en)	1991-05-07	Process for the synthesis of zeolites of the ferrisilicate type, products so obtained
US4346021A (en)	1982-08-24	Method for producing aluminosilicates, their use as catalysts and supports and method for producing catalysts therefrom
US3966883A (en)	1976-06-29	Synthetic ferrierite synthesis
US5910299A (en)	1999-06-08	ERS-10 zeolite and process for its preparation
EP0002079A1 (fr)	1979-05-30	Silicates crystallins et leurs méthodes de préparation
CA1269088A (fr)	1990-05-15	Zeolite ayant une structure de type paulingite (ecr-18) et methode de preparation
JPH0521843B2 (fr)	1993-03-25
JPH0228521B2 (fr)	1990-06-25
EP0104107A1 (fr)	1984-03-28	Titanoborosilicates cristallins et leur procédé de préparation
EP0040104B1 (fr)	1985-10-16	Aluminosilicate synthétique cristallin, composition et procédé pour sa production
JPS58145616A (ja)	1983-08-30	新規結晶性アルミノシリケ−トゼオライト及びその製造法
US4857288A (en)	1989-08-15	Zeolite LZ-135 and process for preparing same
US4977120A (en)	1990-12-11	Binderless zeolite catalysts, production thereof and catalytic reaction therewith
US4732747A (en)	1988-03-22	Magnesium silicate compositions and process for making
US5098894A (en)	1992-03-24	Binderless zeolite catalysts, production thereof and catalytic reaction therewith
JPH0228523B2 (fr)	1990-06-25
CA1270809A (fr)	1990-06-26	Silicate de magnesium modifie au phosphore
US4668837A (en)	1987-05-26	Phosphorus modified magnesium silicate
EP0108271B1 (fr)	1986-02-19	Compositions de tamis moléculaires ferrosilicates
EP0091049A1 (fr)	1983-10-12	Zéolithe LZ-133
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