CA1272031A - Methode d'oxydation partielle - Google Patents

Methode d'oxydation partielle

Info

Publication number: CA1272031A
Authority: CA; Canada
Prior art keywords: iron; nickel; sulfur; feedstock; range
Prior art date: 1987-04-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000535064A

Other languages

English (en)

Inventor

Mitri S. Najjar

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Texaco Development Corp

Original Assignee

Texaco Development Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-04-21

Filing date

1987-04-21

Publication date

1990-07-31

1987-04-21 Application filed by Texaco Development Corp filed Critical Texaco Development Corp

1987-04-21 Priority to CA000535064A priority Critical patent/CA1272031A/fr

1990-07-31 Application granted granted Critical

1990-07-31 Publication of CA1272031A publication Critical patent/CA1272031A/fr

2007-07-31 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 57
230000008569 process Effects 0.000 title claims abstract description 55
238000007254 oxidation reaction Methods 0.000 title claims abstract description 45
230000003647 oxidation Effects 0.000 title claims abstract description 31
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 330
229910052742 iron Inorganic materials 0.000 claims abstract description 167
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 165
229910052759 nickel Inorganic materials 0.000 claims abstract description 83
239000000654 additive Substances 0.000 claims abstract description 74
229910052717 sulfur Inorganic materials 0.000 claims abstract description 74
230000000996 additive effect Effects 0.000 claims abstract description 73
239000011593 sulfur Substances 0.000 claims abstract description 73
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 72
239000000446 fuel Substances 0.000 claims abstract description 66
239000002893 slag Substances 0.000 claims abstract description 50
239000000203 mixture Substances 0.000 claims abstract description 46
239000002006 petroleum coke Substances 0.000 claims abstract description 46
239000007788 liquid Substances 0.000 claims abstract description 42
238000006243 chemical reaction Methods 0.000 claims abstract description 26
239000003795 chemical substances by application Substances 0.000 claims abstract description 26
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 18
229940043430 calcium compound Drugs 0.000 claims abstract description 17
150000001674 calcium compounds Chemical class 0.000 claims abstract description 17
YGHCWPXPAHSSNA-UHFFFAOYSA-N nickel subsulfide Chemical compound [Ni].[Ni]=S.[Ni]=S YGHCWPXPAHSSNA-UHFFFAOYSA-N 0.000 claims abstract description 14
239000012530 fluid Substances 0.000 claims abstract description 11
229910000990 Ni alloy Inorganic materials 0.000 claims abstract description 9
239000000470 constituent Substances 0.000 claims abstract description 9
238000004519 manufacturing process Methods 0.000 claims abstract description 8
230000009467 reduction Effects 0.000 claims abstract description 7
239000002956 ash Substances 0.000 claims description 69
239000007789 gas Substances 0.000 claims description 53
239000000463 material Substances 0.000 claims description 20
229910052710 silicon Inorganic materials 0.000 claims description 17
239000010703 silicon Substances 0.000 claims description 17
238000004939 coking Methods 0.000 claims description 16
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical group [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
150000004763 sulfides Chemical class 0.000 claims description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
239000003208 petroleum Substances 0.000 claims description 9
239000002002 slurry Substances 0.000 claims description 9
239000003245 coal Substances 0.000 claims description 8
230000003111 delayed effect Effects 0.000 claims description 8
150000002506 iron compounds Chemical class 0.000 claims description 8
238000002156 mixing Methods 0.000 claims description 8
229910052760 oxygen Inorganic materials 0.000 claims description 7
239000001301 oxygen Substances 0.000 claims description 7
239000004215 Carbon black (E152) Substances 0.000 claims description 5
229930195733 hydrocarbon Natural products 0.000 claims description 5
150000002430 hydrocarbons Chemical class 0.000 claims description 5
239000003921 oil Substances 0.000 claims description 5
238000005292 vacuum distillation Methods 0.000 claims description 5
235000002918 Fraxinus excelsior Nutrition 0.000 claims description 4
229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 4
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
239000008246 gaseous mixture Substances 0.000 claims description 4
239000002609 medium Substances 0.000 claims description 4
239000002245 particle Substances 0.000 claims description 4
238000005201 scrubbing Methods 0.000 claims description 4
239000000292 calcium oxide Substances 0.000 claims description 3
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
150000003841 chloride salts Chemical class 0.000 claims description 3
150000002823 nitrates Chemical class 0.000 claims description 3
150000002825 nitriles Chemical class 0.000 claims description 3
150000002894 organic compounds Chemical class 0.000 claims description 3
239000003209 petroleum derivative Substances 0.000 claims description 3
150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
239000006163 transport media Substances 0.000 claims description 3
150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
239000010426 asphalt Substances 0.000 claims description 2
150000001558 benzoic acid derivatives Chemical class 0.000 claims description 2
238000009835 boiling Methods 0.000 claims description 2
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
150000001860 citric acid derivatives Chemical class 0.000 claims description 2
239000011280 coal tar Substances 0.000 claims description 2
150000002505 iron Chemical class 0.000 claims description 2
-1 oleates Chemical class 0.000 claims description 2
150000003891 oxalate salts Chemical class 0.000 claims description 2
238000004525 petroleum distillation Methods 0.000 claims description 2
239000003079 shale oil Substances 0.000 claims description 2
239000011275 tar sand Substances 0.000 claims description 2
150000003892 tartrate salts Chemical class 0.000 claims description 2
229910000905 alloy phase Inorganic materials 0.000 claims 1
238000005336 cracking Methods 0.000 claims 1
150000002484 inorganic compounds Chemical class 0.000 claims 1
125000005609 naphthenate group Chemical group 0.000 claims 1
238000011112 process operation Methods 0.000 claims 1
231100000331 toxic Toxicity 0.000 abstract description 13
230000002588 toxic effect Effects 0.000 abstract description 13
230000015572 biosynthetic process Effects 0.000 abstract description 11
238000003786 synthesis reaction Methods 0.000 abstract description 6
CXHOBALGAWRZEJ-UHFFFAOYSA-N nickel nickel(2+) disulfide Chemical compound [S--].[S--].[Ni].[Ni++].[Ni++] CXHOBALGAWRZEJ-UHFFFAOYSA-N 0.000 abstract description 4
239000000571 coke Substances 0.000 description 13
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 11
238000002309 gasification Methods 0.000 description 10
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 8
239000011575 calcium Substances 0.000 description 8
229910052791 calcium Inorganic materials 0.000 description 8
229910052720 vanadium Inorganic materials 0.000 description 8
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
229910052799 carbon Inorganic materials 0.000 description 6
239000007787 solid Substances 0.000 description 6
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
239000000356 contaminant Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
238000005406 washing Methods 0.000 description 4
JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000002737 fuel gas Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
238000000746 purification Methods 0.000 description 3
238000010791 quenching Methods 0.000 description 3
239000011343 solid material Substances 0.000 description 3
229910052566 spinel group Inorganic materials 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000004821 distillation Methods 0.000 description 2
230000004927 fusion Effects 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
238000012545 processing Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000008033 biological extinction Effects 0.000 description 1
230000000903 blocking effect Effects 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
238000013329 compounding Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001687 destabilization Effects 0.000 description 1
230000005484 gravity Effects 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000009434 installation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000013384 organic framework Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
238000005120 petroleum cracking Methods 0.000 description 1
150000004032 porphyrins Chemical class 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000004071 soot Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
150000003463 sulfur Chemical class 0.000 description 1
238000012546 transfer Methods 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
238000010977 unit operation Methods 0.000 description 1
229910001935 vanadium oxide Inorganic materials 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage

Landscapes

Coke Industry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000535064A 1987-04-21 1987-04-21 Methode d'oxydation partielle Expired - Fee Related CA1272031A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000535064A CA1272031A (fr)	1987-04-21	1987-04-21	Methode d'oxydation partielle

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000535064A CA1272031A (fr)	1987-04-21	1987-04-21	Methode d'oxydation partielle

Publications (1)

Publication Number	Publication Date
CA1272031A true CA1272031A (fr)	1990-07-31

Family

ID=4135462

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000535064A Expired - Fee Related CA1272031A (fr)	1987-04-21	1987-04-21	Methode d'oxydation partielle

Country Status (1)

Country	Link
CA (1)	CA1272031A (fr)

1987
- 1987-04-21 CA CA000535064A patent/CA1272031A/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1996-01-31	MKLA	Lapsed

Publication	Publication Date	Title
US4668428A (en)	1987-05-26	Partial oxidation process
US4668429A (en)	1987-05-26	Partial oxidation process
US4671804A (en)	1987-06-09	Partial oxidation process
EP0290689B1 (fr)	1992-04-15	Procédé d'oxydation partielle
US5250083A (en)	1993-10-05	Process for production desulfurized of synthesis gas
US5401282A (en)	1995-03-28	Partial oxidation process for producing a stream of hot purified gas
US5403366A (en)	1995-04-04	Partial oxidation process for producing a stream of hot purified gas
US5441990A (en)	1995-08-15	Cleaned, H2 -enriched syngas made using water-gas shift reaction
US4784670A (en)	1988-11-15	Partial oxidation process
US4654164A (en)	1987-03-31	Partial oxidation process
US4705539A (en)	1987-11-10	Partial oxidation process
EP0386352B1 (fr)	1994-03-09	Procédé d'oxydation partielle
US4851152A (en)	1989-07-25	Prevention of formation of nickel subsulfide in partial oxidation of heavy liquid and/or solid fuels
US4952380A (en)	1990-08-28	Partial oxidation process
US4692172A (en)	1987-09-08	Coal gasification process
US4826627A (en)	1989-05-02	Partial oxidation process
US4657698A (en)	1987-04-14	Partial oxidation process
US4971601A (en)	1990-11-20	Partial oxidation of ash-containing solid carbonaceous and/or liquid hydrocarbonaceous fuel
KR940005198B1 (ko)	1994-06-13	부분산화에 의한 기체 혼합물 생산방법
US4778484A (en)	1988-10-18	Partial oxidation process with second stage addition of iron containing additive
US4957544A (en)	1990-09-18	Partial oxidation process including the concentration of vanadium and nickel in separate slag phases
US4857229A (en)	1989-08-15	Partial oxidation process of sulfur, nickel, and vanadium-containing fuels
EP0209261B1 (fr)	1989-11-29	Procédé d'oxydation partielle
US4801402A (en)	1989-01-31	Partial oxidation process
CA1272031A (fr)	1990-07-31	Methode d'oxydation partielle