CA1279896C - Microcapteur electrochimique - Google Patents

Microcapteur electrochimique

Info

Publication number: CA1279896C
Authority: CA; Canada
Prior art keywords: accordance; substrate; electrode means; layer; medium
Prior art date: 1987-05-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000567772A

Other languages

English (en)

Inventor

Joseph R. Stetter

G. Jordan Maclay

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Transducer Research Inc

Original Assignee

Transducer Research Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-05-26

Filing date

1988-05-26

Publication date

1991-02-05

1988-05-26 Application filed by Transducer Research Inc filed Critical Transducer Research Inc

1991-02-05 Application granted granted Critical

1991-02-05 Publication of CA1279896C publication Critical patent/CA1279896C/fr

2008-05-26 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000758 substrate Substances 0.000 claims abstract description 49
239000000463 material Substances 0.000 claims abstract description 25
238000000576 coating method Methods 0.000 claims abstract description 24
239000012530 fluid Substances 0.000 claims abstract description 21
239000011248 coating agent Substances 0.000 claims abstract description 17
239000007787 solid Substances 0.000 claims abstract description 13
230000004044 response Effects 0.000 claims description 13
239000012528 membrane Substances 0.000 claims description 11
238000003487 electrochemical reaction Methods 0.000 claims description 8
239000002318 adhesion promoter Substances 0.000 claims description 5
239000007784 solid electrolyte Substances 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 4
239000002184 metal Substances 0.000 claims description 4
239000011810 insulating material Substances 0.000 claims 2
230000008859 change Effects 0.000 abstract description 5
238000006056 electrooxidation reaction Methods 0.000 abstract 1
241000894007 species Species 0.000 description 40
239000003792 electrolyte Substances 0.000 description 27
238000006243 chemical reaction Methods 0.000 description 10
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
230000008020 evaporation Effects 0.000 description 8
238000001704 evaporation Methods 0.000 description 8
238000009792 diffusion process Methods 0.000 description 7
229920000557 Nafion® Polymers 0.000 description 6
230000008901 benefit Effects 0.000 description 5
238000000034 method Methods 0.000 description 5
230000003647 oxidation Effects 0.000 description 5
238000007254 oxidation reaction Methods 0.000 description 5
239000011253 protective coating Substances 0.000 description 5
239000011521 glass Substances 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
238000001514 detection method Methods 0.000 description 3
230000001788 irregular Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
238000012544 monitoring process Methods 0.000 description 3
229910052710 silicon Inorganic materials 0.000 description 3
239000010703 silicon Substances 0.000 description 3
235000012239 silicon dioxide Nutrition 0.000 description 3
239000010409 thin film Substances 0.000 description 3
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
238000000151 deposition Methods 0.000 description 2
230000008021 deposition Effects 0.000 description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
230000008569 process Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
208000006379 syphilis Diseases 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 1
241001527902 Aratus Species 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
238000006873 Coates reaction Methods 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
101100346656 Drosophila melanogaster strat gene Proteins 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
239000006087 Silane Coupling Agent Substances 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
238000007792 addition Methods 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
230000004075 alteration Effects 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
238000010276 construction Methods 0.000 description 1
239000011889 copper foil Substances 0.000 description 1
238000012937 correction Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
239000007772 electrode material Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
238000005530 etching Methods 0.000 description 1
239000010408 film Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
239000011133 lead Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
GLVAUDGFNGKCSF-UHFFFAOYSA-N mercaptopurine Chemical compound S=C1NC=NC2=C1NC=N2 GLVAUDGFNGKCSF-UHFFFAOYSA-N 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
238000010606 normalization Methods 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
-1 perfluoro Chemical group 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
230000010287 polarization Effects 0.000 description 1
229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
239000005518 polymer electrolyte Substances 0.000 description 1
229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
235000019422 polyvinyl alcohol Nutrition 0.000 description 1
KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000006722 reduction reaction Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
229910052594 sapphire Inorganic materials 0.000 description 1
239000010980 sapphire Substances 0.000 description 1
239000004065 semiconductor Substances 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000011343 solid material Substances 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
238000004528 spin coating Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
PYJJCSYBSYXGQQ-UHFFFAOYSA-N trichloro(octadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](Cl)(Cl)Cl PYJJCSYBSYXGQQ-UHFFFAOYSA-N 0.000 description 1

Classifications

- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/404—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors
- G01N27/4045—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors for gases other than oxygen

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
Biochemistry (AREA)
General Physics & Mathematics (AREA)
Electrochemistry (AREA)
Physics & Mathematics (AREA)
Analytical Chemistry (AREA)
Molecular Biology (AREA)
General Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Immunology (AREA)
Pathology (AREA)
Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Measurement Of The Respiration, Hearing Ability, Form, And Blood Characteristics Of Living Organisms (AREA)
Primary Cells (AREA)
Electric Double-Layer Capacitors Or The Like (AREA)

CA000567772A 1987-05-26 1988-05-26 Microcapteur electrochimique Expired - Fee Related CA1279896C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US5370587A	1987-05-26	1987-05-26
US07/053,705		1987-05-26

Publications (1)

Publication Number	Publication Date
CA1279896C true CA1279896C (fr)	1991-02-05

Family

ID=21985990

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000567772A Expired - Fee Related CA1279896C (fr)	1987-05-26	1988-05-26	Microcapteur electrochimique

Country Status (4)

Country	Link
EP (1)	EP0363427A4 (fr)
AU (1)	AU604142B2 (fr)
CA (1)	CA1279896C (fr)
WO (1)	WO1988009500A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4795543A (en) *	1987-05-26	1989-01-03	Transducer Research, Inc.	Spin coating of electrolytes
FR2695481B1 (fr) *	1992-09-07	1994-12-02	Cylergie Gie	Dispositif de mesure ampérométrique comportant un capteur électrochimique.
GB2290382A (en) *	1994-03-25	1995-12-20	Univ Cranfield	Electrochemical measurement and reactions in highly-resistive solvents
US5841021A (en) *	1995-09-05	1998-11-24	De Castro; Emory S.	Solid state gas sensor and filter assembly
GB9625464D0 (en) *	1996-12-07	1997-01-22	Central Research Lab Ltd	Gas sensor
DE102004037312B4 (de)	2004-07-31	2015-02-05	Dräger Safety AG & Co. KGaA	Elektrochemischer Gassensor und Verfahren zu seiner Herstellung

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US751897A (en) *		1904-02-09		Gitido bodlander
US2913386A (en) *	1956-03-21	1959-11-17	Jr Leland C Clark	Electrochemical device for chemical analysis
US3260656A (en) *	1962-09-27	1966-07-12	Corning Glass Works	Method and apparatus for electrolytically determining a species in a fluid
US3305457A (en) *	1965-08-09	1967-02-21	Hyman Edward Sidney	Hydrocarbon detection
US3701632A (en) *	1970-03-05	1972-10-31	California Inst Of Techn	Vapor phase detectors
US3836449A (en) *	1970-06-01	1974-09-17	California Inst Of Techn	Electrolytic cell for use with vapor phase detectors
US3824168A (en) *	1970-11-10	1974-07-16	Energetics Science	Gas detecting and quantitative measuring device
US3776832A (en) *	1970-11-10	1973-12-04	Energetics Science	Electrochemical detection cell
US3909386A (en) *	1970-11-10	1975-09-30	Energetics Science	Gas detector unit
US3764269A (en) *	1971-12-28	1973-10-09	North American Rockwell	Sensor for fluid components
US4076596A (en) *	1976-10-07	1978-02-28	Leeds & Northrup Company	Apparatus for electrolytically determining a species in a fluid and method of use
US4267023A (en) *	1977-10-17	1981-05-12	Orion Research Incorporated	Chemically integrating dosimeter and gas analysis methods
JPS5467497A (en) *	1977-11-09	1979-05-30	Nippon Soken	Gas detector
EP0004184A1 (fr) *	1978-03-08	1979-09-19	British Gas Corporation	Détecteur de gaz et son procédé de réalisation
US4228400A (en) *	1978-03-28	1980-10-14	Research Corporation	Conductometric gas analysis cell
US4184937A (en) *	1978-12-26	1980-01-22	Catalyst Research Corporation	Electrochemical cell for the detection of chlorine
US4169779A (en) *	1978-12-26	1979-10-02	Catalyst Research Corporation	Electrochemical cell for the detection of hydrogen sulfide
US4227984A (en) *	1979-03-01	1980-10-14	General Electric Company	Potentiostated, three-electrode, solid polymer electrolyte (SPE) gas sensor having highly invariant background current characteristics with temperature during zero-air operation
JPS55154450A (en) *	1979-05-19	1980-12-02	Nissan Motor Co Ltd	Air-fuel-ratio detector
JPS55166039A (en) *	1979-06-12	1980-12-24	Nissan Motor Co Ltd	Air fuel ratio detector
US4329214A (en) *	1980-07-21	1982-05-11	Becton, Dickinson And Company	Gas detection unit
US4347732A (en) *	1980-08-18	1982-09-07	Leary David J	Gas monitoring apparatus
GB2094005B (en) *	1981-02-03	1985-05-30	Coal Industry Patents Ltd	Electrochemical gas sensor
JPS57137850A (en) *	1981-02-20	1982-08-25	Nissan Motor Co Ltd	Oxygen concentration measuring element
US4423407A (en) *	1981-02-27	1983-12-27	Dart Industries Inc.	Apparatus and method for measuring the concentration of gases
US4387165A (en) *	1982-04-22	1983-06-07	Youngblood James L	H2 S Detector having semiconductor and noncontinuous inert film deposited thereon
US4571292A (en) *	1982-08-12	1986-02-18	Case Western Reserve University	Apparatus for electrochemical measurements
US4477541A (en) *	1982-12-22	1984-10-16	The United States Of America As Represented By The United States Department Of Energy	Solid electrolyte structure
US4521290A (en) *	1984-03-16	1985-06-04	Honeywell Inc.	Thin layer electrochemical cell for rapid detection of toxic chemicals
US4587105A (en) *	1984-05-17	1986-05-06	Honeywell Inc.	Integratable oxygen sensor
US4795543A (en) *	1987-05-26	1989-01-03	Transducer Research, Inc.	Spin coating of electrolytes

1988
- 1988-05-26 CA CA000567772A patent/CA1279896C/fr not_active Expired - Fee Related
- 1988-05-26 AU AU19580/88A patent/AU604142B2/en not_active Ceased
- 1988-05-26 WO PCT/US1988/001772 patent/WO1988009500A1/fr not_active Ceased
- 1988-05-26 EP EP19880906286 patent/EP0363427A4/en not_active Withdrawn

Also Published As

Publication number	Publication date
AU1958088A (en)	1988-12-21
EP0363427A1 (fr)	1990-04-18
WO1988009500A1 (fr)	1988-12-01
AU604142B2 (en)	1990-12-06
EP0363427A4 (en)	1991-01-16

Legal Events

Date	Code	Title	Description
1998-02-05	MKLA	Lapsed

Publication	Publication Date	Title
US4865717A (en)	1989-09-12	Electrochemical micro sensor
CA1074867A (fr)	1980-04-01	Appareil pour la determination electrolytique d'une espece portee dans un fluide
US4874500A (en)	1989-10-17	Microelectrochemical sensor and sensor array
Bartlett et al.	1989	Conducting polymer gas sensors part I: fabrication and characterization
US5338432A (en)	1994-08-16	Corrosivity sensor
Nishikata et al.	1997	Influence of electrolyte layer thickness and pH on the initial stage of the atmospheric corrosion of iron
US4534356A (en)	1985-08-13	Solid state transcutaneous blood gas sensors
US5252292A (en)	1993-10-12	Ammonia sensor
EP0299780A2 (fr)	1989-01-18	Microcapteur électronique pour gaz et vapeur en saillie
US4326927A (en)	1982-04-27	Method and device for the detection and measurement of electrochemically active compounds
US4662996A (en)	1987-05-05	Method and electrochemical sensor for sensing chemical agents using a sensing elctrode coated with electrically conductive polymers
US4324760A (en)	1982-04-13	Hydrogen detector
TWI625522B (zh)	2018-06-01	平面型氨選擇性感測電極及其製法
Uhlig et al.	1997	Highly sensitive heavy metal analysis on platinum‐and gold‐ultramicroelectrode arrays
CA1279896C (fr)	1991-02-05	Microcapteur electrochimique
WO1996033404A1 (fr)	1996-10-24	Detecteur de gaz electrochimique utilise dans la detection du dioxyde d'azote
Rau et al.	1994	Characterization of a polypyrrole microsensor for nitrate and nitrite ions
US7736479B2 (en)	2010-06-15	Electrochemical sensor having nonporous working electrode
WO1995004271A1 (fr)	1995-02-09	Analyse de solutions liquides
Gao et al.	1993	An electrochemical Nafion® matrix oxygen sensor and the evaluation of oxygen permeation in coated films
GB2237291A (en)	1991-05-01	Method of bridging gaps in a substrate by electrodeposited film, for use in gas sensor manufacture
CA1189570A (fr)	1985-06-25	Methode et dispositif de mesure d'un flux d'hydrogene
JPH037263B2 (fr)	1991-02-01
Wallgren et al.	2009	A Nafion®-based co-planar electrode amperometric sensor for methanol determination in the gas phase
JPH04132949A (ja)	1992-05-07	酵素固定化電極