CA1282546C - Polymeres de propylene - Google Patents

Polymeres de propylene

Info

Publication number: CA1282546C
Authority: CA; Canada
Prior art keywords: polymer; copolymer; catalyst; propylene; ethylene
Prior art date: 1986-06-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000537818A

Other languages

English (en)

Inventor

Brian Jay Pellon

George Cyrus Allen

Michael Peyton Hughes

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rexene Products Co

Original Assignee

Rexene Products Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-06-30

Filing date

1987-05-25

Publication date

1991-04-02

1987-05-25 Application filed by Rexene Products Co filed Critical Rexene Products Co

1991-04-02 Application granted granted Critical

1991-04-02 Publication of CA1282546C publication Critical patent/CA1282546C/fr

2008-04-02 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229920001155 polypropylene Polymers 0.000 title abstract 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 15
239000005977 Ethylene Substances 0.000 claims description 15
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 13
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 12
229920001577 copolymer Polymers 0.000 claims description 11
230000035515 penetration Effects 0.000 claims description 9
239000010936 titanium Substances 0.000 claims description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
229910052719 titanium Inorganic materials 0.000 claims description 8
230000004927 fusion Effects 0.000 claims description 3
238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 claims description 2
229920005604 random copolymer Polymers 0.000 claims 1
229920000642 polymer Polymers 0.000 abstract description 46
-1 propylene, ethylene Chemical group 0.000 abstract description 8
239000000463 material Substances 0.000 abstract description 6
239000004831 Hot glue Substances 0.000 abstract description 3
239000004711 α-olefin Substances 0.000 abstract description 3
125000004432 carbon atom Chemical group C* 0.000 abstract description 2
238000002156 mixing Methods 0.000 abstract 1
239000003054 catalyst Substances 0.000 description 33
238000000034 method Methods 0.000 description 14
239000000203 mixture Substances 0.000 description 11
238000006116 polymerization reaction Methods 0.000 description 10
239000000047 product Substances 0.000 description 10
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
239000001257 hydrogen Substances 0.000 description 8
229910052739 hydrogen Inorganic materials 0.000 description 8
239000002002 slurry Substances 0.000 description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
239000003426 co-catalyst Substances 0.000 description 7
239000000178 monomer Substances 0.000 description 7
229920001585 atactic polymer Polymers 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
239000007787 solid Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
229910052782 aluminium Inorganic materials 0.000 description 5
239000006227 byproduct Substances 0.000 description 5
239000002655 kraft paper Substances 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
239000000853 adhesive Substances 0.000 description 4
230000001070 adhesive effect Effects 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
239000008187 granular material Substances 0.000 description 4
239000011777 magnesium Substances 0.000 description 4
229910052749 magnesium Inorganic materials 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
238000001816 cooling Methods 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
238000000386 microscopy Methods 0.000 description 3
229920001384 propylene homopolymer Polymers 0.000 description 3
238000010998 test method Methods 0.000 description 3
229910052721 tungsten Inorganic materials 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
238000005481 NMR spectroscopy Methods 0.000 description 2
229920006125 amorphous polymer Polymers 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
238000000113 differential scanning calorimetry Methods 0.000 description 2
238000001000 micrograph Methods 0.000 description 2
239000002480 mineral oil Substances 0.000 description 2
235000010446 mineral oil Nutrition 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
239000000123 paper Substances 0.000 description 2
230000008569 process Effects 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
238000004736 wide-angle X-ray diffraction Methods 0.000 description 2
RCYUVMCXOQTZOZ-FHQKDBNESA-N (z)-but-2-enedioic acid;2-[2-[2-[4-[(4-chlorophenyl)-phenylmethyl]piperazin-1-yl]ethoxy]ethoxy]ethanol;2-methyl-3-(2-methylphenyl)quinazolin-4-one Chemical compound OC(=O)\C=C/C(O)=O.OC(=O)\C=C/C(O)=O.CC1=CC=CC=C1N1C(=O)C2=CC=CC=C2N=C1C.C1CN(CCOCCOCCO)CCN1C(C=1C=CC(Cl)=CC=1)C1=CC=CC=C1 RCYUVMCXOQTZOZ-FHQKDBNESA-N 0.000 description 1
229920002799 BoPET Polymers 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
239000005041 Mylar™ Substances 0.000 description 1
MOMWFXLCFJOAFX-UHFFFAOYSA-N OOOOOOOO Chemical compound OOOOOOOO MOMWFXLCFJOAFX-UHFFFAOYSA-N 0.000 description 1
239000004264 Petrolatum Substances 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
230000004075 alteration Effects 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
238000003491 array Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000008901 benefit Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
150000001805 chlorine compounds Chemical group 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000013529 heat transfer fluid Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000012943 hotmelt Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229920001580 isotactic polymer Polymers 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
TWXDDNPPQUTEOV-FVGYRXGTSA-N methamphetamine hydrochloride Chemical compound Cl.CN[C@@H](C)CC1=CC=CC=C1 TWXDDNPPQUTEOV-FVGYRXGTSA-N 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229940066842 petrolatum Drugs 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
238000013031 physical testing Methods 0.000 description 1
239000000049 pigment Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
IOVGROKTTNBUGK-SJCJKPOMSA-N ritodrine Chemical compound N([C@@H](C)[C@H](O)C=1C=CC(O)=CC=1)CCC1=CC=C(O)C=C1 IOVGROKTTNBUGK-SJCJKPOMSA-N 0.000 description 1
238000007789 sealing Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
230000000707 stereoselective effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229920001576 syndiotactic polymer Polymers 0.000 description 1
YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

CA000537818A 1986-06-30 1987-05-25 Polymeres de propylene Expired - Fee Related CA1282546C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US88045386A	1986-06-30	1986-06-30
US880,453		1986-06-30

Publications (1)

Publication Number	Publication Date
CA1282546C true CA1282546C (fr)	1991-04-02

Family

ID=25376312

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000537818A Expired - Fee Related CA1282546C (fr)	1986-06-30	1987-05-25	Polymeres de propylene

Country Status (3)

Country	Link
JP (1)	JP2647385B2 (fr)
AU (1)	AU604243B2 (fr)
CA (1)	CA1282546C (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2015119758A1 (fr) *	2014-02-07	2015-08-13	Eastman Chemical Company	Copolymères amorphes de propylène-éthylène
US10308740B2 (en)	2014-02-07	2019-06-04	Eastman Chemical Company	Amorphous propylene-ethylene copolymers
US10647795B2 (en)	2014-02-07	2020-05-12	Eastman Chemical Company	Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en)	2014-02-07	2020-06-30	Eastman Chemical Company	Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10723824B2 (en)	2014-02-07	2020-07-28	Eastman Chemical Company	Adhesives comprising amorphous propylene-ethylene copolymers
US11267916B2 (en)	2014-02-07	2022-03-08	Eastman Chemical Company	Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4847340A (en) *	1986-06-30	1989-07-11	Rexene Products Company	Novel propylene polymerization process
US4736002A (en) *	1986-06-30	1988-04-05	El Paso Products Company	Novel propylene polymerization process

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1365501A (en) *	1971-02-26	1974-09-04	Ici Ltd	Copolymerisation of olefins

1987
- 1987-05-25 CA CA000537818A patent/CA1282546C/fr not_active Expired - Fee Related
- 1987-06-12 AU AU74167/87A patent/AU604243B2/en not_active Ceased
- 1987-06-26 JP JP62157959A patent/JP2647385B2/ja not_active Expired - Fee Related

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2015119758A1 (fr) *	2014-02-07	2015-08-13	Eastman Chemical Company	Copolymères amorphes de propylène-éthylène
US9382351B2 (en)	2014-02-07	2016-07-05	Eastman Chemical Company	Amorphous propylene-ethylene copolymers
US9399686B2 (en)	2014-02-07	2016-07-26	Eastman Chemical Company	Amorphous propylene-ethylene copolymers
US9428598B2 (en)	2014-02-07	2016-08-30	Eastman Chemical Company	Amorphous propylene-ethylene copolymers
US9593179B2 (en)	2014-02-07	2017-03-14	Eastman Chemical Company	Amorphous propylene-ethylene copolymers
US9611341B2 (en)	2014-02-07	2017-04-04	Eastman Chemical Company	Amorphous propylene-ethylene copolymers
US10214600B2 (en)	2014-02-07	2019-02-26	Eastman Chemical Company	Amorphpus propylene-ethylene copolymers
US10308740B2 (en)	2014-02-07	2019-06-04	Eastman Chemical Company	Amorphous propylene-ethylene copolymers
US10647795B2 (en)	2014-02-07	2020-05-12	Eastman Chemical Company	Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en)	2014-02-07	2020-06-30	Eastman Chemical Company	Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10725406B2 (en)	2014-02-07	2020-07-28	Eastman Chemical Company	Amorphous propylene-ethylene copolymers
US10723824B2 (en)	2014-02-07	2020-07-28	Eastman Chemical Company	Adhesives comprising amorphous propylene-ethylene copolymers
US11267916B2 (en)	2014-02-07	2022-03-08	Eastman Chemical Company	Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US11390701B2 (en)	2014-02-07	2022-07-19	Synthomer Adhesive Technologies Llc	Amorphous propylene-ethylene copolymers

Also Published As

Publication number	Publication date
AU7416787A (en)	1988-01-21
JPS63118306A (ja)	1988-05-23
JP2647385B2 (ja)	1997-08-27
AU604243B2 (en)	1990-12-13

Legal Events

Date	Code	Title	Description
2006-04-03	MKLA	Lapsed

Publication	Publication Date	Title
US4736002A (en)	1988-04-05	Novel propylene polymerization process
US4847340A (en)	1989-07-11	Novel propylene polymerization process
US4168361A (en)	1979-09-18	Random copolymer of propylene and 1-butene and process for its production
US4859757A (en)	1989-08-22	Novel propylene polymers
EP0660847B1 (fr)	2001-05-30	Copolymeres de 1-butene/propylene amorphes a haute resistance a la traction
CA1338368C (fr)	1996-06-04	Copolymeres de propylene cristallises
EP0335484B1 (fr)	1992-12-02	Procédé de copolymérisation de propylène
US5521251A (en)	1996-05-28	Propylene random copolymer composition
EP0077532A2 (fr)	1983-04-27	Compositions de polypropylène ayant une résistance au choc accrue à basse température et leur procédé de préparation
EP0435557B1 (fr)	1996-05-22	Composition catalytiques pour polymérisation d'oléfines activée pour le chlorure de diméthylaluminium
KR100201053B1 (ko)	1999-06-15	무정형 엘라스토머성 프로필렌 단독 중합체의 제조 방법
CA1282546C (fr)	1991-04-02	Polymeres de propylene
US4550145A (en)	1985-10-29	Process for the production of propylene block copolymers by a three step method
EP0251771B1 (fr)	1991-04-24	Polymères de propylène et leur préparation
HK1006463B (en)	1999-02-26	Process for the production of amorphous elastomeric propylene homopolymers
US4634745A (en)	1987-01-06	Terpolymer production
KR100304037B1 (ko)	2001-11-22	폴리프로필렌 적층 필름
CA2232947C (fr)	2008-05-20	Resine de polymere de propylene produit au moyen d'un catalyseur hautement actif, presentant une large plage de temperature de mise en oeuvre et articles realises a partir de ladite resine
US4900798A (en)	1990-02-13	Preparation of ethene polymers using a ziegler catalyst system
USH1254H (en)	1993-11-02	Polymerization process for butene-1 and alpha-olefin monomers
JPH0114247B2 (fr)	1989-03-10
JPS5998111A (ja)	1984-06-06	変性ランダム共重合体の製造方法
JPS62241912A (ja)	1987-10-22	環状オレフイン系ランダム共重合体の製法