CA1283100C - Preparation d'un sirop a teneur elevee en fructose a partir de substances naturelles contenant de l'inuline - Google Patents

Preparation d'un sirop a teneur elevee en fructose a partir de substances naturelles contenant de l'inuline

Info

Publication number: CA1283100C
Authority: CA; Canada
Prior art keywords: inulin; fructose; reducing sugars; ion exchange; liquid
Prior art date: 1986-05-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000510305A

Other languages

English (en)

Inventor

Per Gunnar Assarsson

Joseph Hideo Nagasuye

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ST-LAWRENCE REACTORS Ltd

Original Assignee

ST-LAWRENCE REACTORS LIMITED

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-05-29

Filing date

1986-05-29

Publication date

1991-04-16

1986-05-29 Application filed by ST-LAWRENCE REACTORS LIMITED filed Critical ST-LAWRENCE REACTORS LIMITED

1986-05-29 Priority to CA000510305A priority Critical patent/CA1283100C/fr

1991-04-16 Application granted granted Critical

1991-04-16 Publication of CA1283100C publication Critical patent/CA1283100C/fr

2008-04-16 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 title claims abstract description 41
229920001202 Inulin Polymers 0.000 title claims abstract description 39
229940029339 inulin Drugs 0.000 title claims abstract description 37
239000000463 material Substances 0.000 title claims abstract description 16
235000021433 fructose syrup Nutrition 0.000 title claims abstract description 15
238000002360 preparation method Methods 0.000 title description 2
238000000034 method Methods 0.000 claims abstract description 26
239000005715 Fructose Substances 0.000 claims abstract description 25
RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims abstract description 25
235000000346 sugar Nutrition 0.000 claims abstract description 25
229930091371 Fructose Natural products 0.000 claims abstract description 24
239000006188 syrup Substances 0.000 claims abstract description 24
235000020357 syrup Nutrition 0.000 claims abstract description 24
150000008163 sugars Chemical class 0.000 claims abstract description 21
239000007788 liquid Substances 0.000 claims abstract description 19
238000005342 ion exchange Methods 0.000 claims abstract description 18
150000002016 disaccharides Chemical class 0.000 claims abstract description 14
150000002772 monosaccharides Chemical class 0.000 claims abstract description 13
150000001720 carbohydrates Chemical class 0.000 claims abstract description 9
230000007717 exclusion Effects 0.000 claims abstract description 8
108090000623 proteins and genes Proteins 0.000 claims abstract description 7
102000004169 proteins and genes Human genes 0.000 claims abstract description 7
239000012467 final product Substances 0.000 claims abstract description 3
239000012530 fluid Substances 0.000 claims abstract description 3
150000004043 trisaccharides Chemical class 0.000 claims abstract description 3
238000001032 ion-exclusion chromatography Methods 0.000 claims abstract 2
239000011344 liquid material Substances 0.000 claims abstract 2
235000011389 fruit/vegetable juice Nutrition 0.000 claims description 20
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 18
230000007062 hydrolysis Effects 0.000 claims description 18
238000006460 hydrolysis reaction Methods 0.000 claims description 18
239000008103 glucose Substances 0.000 claims description 17
239000000047 product Substances 0.000 claims description 17
244000019459 Cynara cardunculus Species 0.000 claims description 11
235000019106 Cynara scolymus Nutrition 0.000 claims description 11
235000016520 artichoke thistle Nutrition 0.000 claims description 11
240000008892 Helianthus tuberosus Species 0.000 claims description 9
235000003230 Helianthus tuberosus Nutrition 0.000 claims description 9
239000007787 solid Substances 0.000 claims description 9
239000002253 acid Substances 0.000 claims description 8
230000009850 completed effect Effects 0.000 claims description 3
238000001704 evaporation Methods 0.000 claims description 3
230000008020 evaporation Effects 0.000 claims description 3
125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 3
238000010438 heat treatment Methods 0.000 claims description 2
-1 sugars disaccharides Chemical class 0.000 claims description 2
229960002737 fructose Drugs 0.000 description 18
229960001031 glucose Drugs 0.000 description 18
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 16
235000001727 glucose Nutrition 0.000 description 15
150000002500 ions Chemical class 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
229930006000 Sucrose Natural products 0.000 description 6
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 6
239000005720 sucrose Substances 0.000 description 6
ZFTFOHBYVDOAMH-XNOIKFDKSA-N (2r,3s,4s,5r)-5-[[(2r,3s,4s,5r)-5-[[(2r,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxymethyl]-3,4-dihydroxy-2-(hydroxymethyl)oxolan-2-yl]oxymethyl]-2-(hydroxymethyl)oxolane-2,3,4-triol Chemical class O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@@H]1[C@@H](O)[C@H](O)[C@](CO)(OC[C@@H]2[C@H]([C@H](O)[C@@](O)(CO)O2)O)O1 ZFTFOHBYVDOAMH-XNOIKFDKSA-N 0.000 description 5
229920002670 Fructan Polymers 0.000 description 5
239000000539 dimer Substances 0.000 description 5
239000000203 mixture Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
239000000284 extract Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
239000006227 byproduct Substances 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
239000001913 cellulose Substances 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
239000011707 mineral Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
229960005419 nitrogen Drugs 0.000 description 3
229920001467 poly(styrenesulfonates) Polymers 0.000 description 3
239000011347 resin Substances 0.000 description 3
229920005989 resin Polymers 0.000 description 3
238000003860 storage Methods 0.000 description 3
238000000108 ultra-filtration Methods 0.000 description 3
108090000790 Enzymes Proteins 0.000 description 2
102000004190 Enzymes Human genes 0.000 description 2
240000008042 Zea mays Species 0.000 description 2
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
235000002017 Zea mays subsp mays Nutrition 0.000 description 2
238000005903 acid hydrolysis reaction Methods 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
235000005822 corn Nutrition 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
239000008121 dextrose Substances 0.000 description 2
230000007071 enzymatic hydrolysis Effects 0.000 description 2
238000006047 enzymatic hydrolysis reaction Methods 0.000 description 2
239000012535 impurity Substances 0.000 description 2
238000006317 isomerization reaction Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000013055 pulp slurry Substances 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000013638 trimer Substances 0.000 description 2
238000005406 washing Methods 0.000 description 2
PJVXUVWGSCCGHT-ZPYZYFCMSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;(3s,4r,5r)-1,3,4,5,6-pentahydroxyhexan-2-one Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO PJVXUVWGSCCGHT-ZPYZYFCMSA-N 0.000 description 1
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
244000298479 Cichorium intybus Species 0.000 description 1
235000007542 Cichorium intybus Nutrition 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
244000115658 Dahlia pinnata Species 0.000 description 1
235000012040 Dahlia pinnata Nutrition 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
229920002488 Hemicellulose Polymers 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
150000001413 amino acids Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000003729 cation exchange resin Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
235000009508 confectionery Nutrition 0.000 description 1
230000000332 continued effect Effects 0.000 description 1
230000006378 damage Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000005837 enolization reaction Methods 0.000 description 1
230000002255 enzymatic effect Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
235000013305 food Nutrition 0.000 description 1
235000003599 food sweetener Nutrition 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
108010090785 inulinase Proteins 0.000 description 1
238000004255 ion exchange chromatography Methods 0.000 description 1
239000003456 ion exchange resin Substances 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
239000004571 lime Substances 0.000 description 1
150000002632 lipids Chemical class 0.000 description 1
230000002879 macerating effect Effects 0.000 description 1
239000012528 membrane Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
102000004196 processed proteins & peptides Human genes 0.000 description 1
108090000765 processed proteins & peptides Proteins 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000003765 sweetening agent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K11/00—Fructose
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin

Landscapes

Life Sciences & Earth Sciences (AREA)
Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Nutrition Science (AREA)
Engineering & Computer Science (AREA)
Food Science & Technology (AREA)
Polymers & Plastics (AREA)
Molecular Biology (AREA)
Biochemistry (AREA)
Organic Chemistry (AREA)
Jellies, Jams, And Syrups (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)

CA000510305A 1986-05-29 1986-05-29 Preparation d'un sirop a teneur elevee en fructose a partir de substances naturelles contenant de l'inuline Expired - Fee Related CA1283100C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000510305A CA1283100C (fr)	1986-05-29	1986-05-29	Preparation d'un sirop a teneur elevee en fructose a partir de substances naturelles contenant de l'inuline

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000510305A CA1283100C (fr)	1986-05-29	1986-05-29	Preparation d'un sirop a teneur elevee en fructose a partir de substances naturelles contenant de l'inuline

Publications (1)

Publication Number	Publication Date
CA1283100C true CA1283100C (fr)	1991-04-16

Family

ID=4133235

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000510305A Expired - Fee Related CA1283100C (fr)	1986-05-29	1986-05-29	Preparation d'un sirop a teneur elevee en fructose a partir de substances naturelles contenant de l'inuline

Country Status (1)

Country	Link
CA (1)	CA1283100C (fr)

1986
- 1986-05-29 CA CA000510305A patent/CA1283100C/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
2001-04-17	MKLA	Lapsed

Publication	Publication Date	Title
US5478732A (en)	1995-12-26	Process for the preparation of long-chain inulin with inulinase
KR0135075B1 (ko)	1998-04-20	식이섬유를 함유한 덱스트린의 제조방법
CA2196739C (fr)	2005-09-27	Preparation de produits a base d'inuline
US6663717B2 (en)	2003-12-16	Process for the fractionation of sugar beet pulp
MXPA97000916A (en)	1998-04-01	Preparation of inul products
JP4831420B2 (ja)	2011-12-07	糖の分離
US20070112187A1 (en)	2007-05-17	Separation process
Zeitoun et al.	2010	Twin-screw extrusion for hemicellulose recovery: Influence on extract purity and purification performance
US4547226A (en)	1985-10-15	Preparation of high fructose syrups from citrus residues
CN106800586A (zh)	2017-06-06	一种辣木蛋白质高效提取的方法
Jacquemin et al.	2015	Comparison of different twin-screw extraction conditions for the production of arabinoxylans
CA1100950A (fr)	1981-05-12	Traduction non-disponible
JPH0347832B2 (fr)	1991-07-22
JP2000333692A (ja)	2000-12-05	キシロオリゴ糖の製造方法
US4702839A (en)	1987-10-27	Process for the recovery of monosaccharides from poly-, oligo- and/or disaccharides containing tuberous plants by means of ultrafiltration
CA1283100C (fr)	1991-04-16	Preparation d'un sirop a teneur elevee en fructose a partir de substances naturelles contenant de l'inuline
WO1984000561A1 (fr)	1984-02-16	Preparation de sirops a forte teneur en fructose a partir de residus d'agrumes
CA2604328C (fr)	2011-12-06	Procede de purification et procede de production de cellobiose
US20040198965A1 (en)	2004-10-07	D-galactose isolation system
GB2407573A (en)	2005-05-04	Production of arabinose
JPS61271295A (ja)	1986-12-01	果糖縮合物の製造方法
KUSAKABE et al.	1985	Studies on the Mannanase of Streptomyces V. Preparation of Crystalline Mannobiose from Copra Mannan by a Mannanase System from Streptomyces sp.
Sablayrolles et al.	0	Comparison of different twin-screw extraction conditions for the production of arabinoxylans
GB2406335A (en)	2005-03-30	Separation of deoxy sugars
日下部功 et al.	1985	Studies on the mannanase of Streptomyces. V. Preparation of crystalline mannobiose from copra mannan by a mannanase system from Streptomyces sp.