CA1283511C - Laundry pre-spotter composition providing improved oily soil removal - Google Patents

Laundry pre-spotter composition providing improved oily soil removal

Info

Publication number: CA1283511C
Authority: CA; Canada
Prior art keywords: composition; alcohol; water; spotting; carbon atoms
Prior art date: 1986-09-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000544828A

Other languages

English (en)

French (fr)

Inventor

David Dean Clark

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Colgate Palmolive Co

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-09-02

Filing date

1987-08-19

Publication date

1991-04-30

1987-08-19 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1991-04-30 Application granted granted Critical

1991-04-30 Publication of CA1283511C publication Critical patent/CA1283511C/en

2008-04-30 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 190
239000002689 soil Substances 0.000 title claims abstract description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 94
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 64
239000004094 surface-active agent Substances 0.000 claims abstract description 40
239000002736 nonionic surfactant Substances 0.000 claims abstract description 34
239000004530 micro-emulsion Substances 0.000 claims abstract description 30
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 26
239000003960 organic solvent Substances 0.000 claims abstract description 22
-1 aliphatic primary Chemical class 0.000 claims abstract description 19
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 18
150000003333 secondary alcohols Chemical class 0.000 claims abstract description 14
238000005191 phase separation Methods 0.000 claims abstract description 13
235000020354 squash Nutrition 0.000 claims abstract description 12
239000002671 adjuvant Substances 0.000 claims abstract description 10
150000001412 amines Chemical class 0.000 claims abstract description 8
239000006184 cosolvent Substances 0.000 claims abstract description 8
239000007859 condensation product Substances 0.000 claims abstract description 7
150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 5
239000004744 fabric Substances 0.000 claims description 27
229940094933 n-dodecane Drugs 0.000 claims description 22
239000007788 liquid Substances 0.000 claims description 19
238000000034 method Methods 0.000 claims description 14
IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 claims description 13
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 10
150000003138 primary alcohols Chemical class 0.000 claims description 10
238000004900 laundering Methods 0.000 claims 1
239000000243 solution Substances 0.000 description 23
239000003921 oil Substances 0.000 description 21
239000000499 gel Substances 0.000 description 14
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 12
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 10
235000019198 oils Nutrition 0.000 description 10
239000002904 solvent Substances 0.000 description 10
239000003599 detergent Substances 0.000 description 9
238000009472 formulation Methods 0.000 description 7
OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
238000004140 cleaning Methods 0.000 description 5
238000010790 dilution Methods 0.000 description 5
239000012895 dilution Substances 0.000 description 5
150000002148 esters Chemical class 0.000 description 5
DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 5
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
235000019445 benzyl alcohol Nutrition 0.000 description 4
235000014113 dietary fatty acids Nutrition 0.000 description 4
238000004453 electron probe microanalysis Methods 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
KJPHTXTWFHVJIG-UHFFFAOYSA-N n-ethyl-2-[(6-methoxypyridin-3-yl)-(2-methylphenyl)sulfonylamino]-n-(pyridin-3-ylmethyl)acetamide Chemical compound C=1C=C(OC)N=CC=1N(S(=O)(=O)C=1C(=CC=CC=1)C)CC(=O)N(CC)CC1=CC=CN=C1 KJPHTXTWFHVJIG-UHFFFAOYSA-N 0.000 description 4
239000010665 pine oil Substances 0.000 description 4
229920004934 Dacron® Polymers 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
239000005020 polyethylene terephthalate Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
229920000742 Cotton Polymers 0.000 description 2
102000004190 Enzymes Human genes 0.000 description 2
108090000790 Enzymes Proteins 0.000 description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
150000002191 fatty alcohols Chemical class 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000002304 perfume Substances 0.000 description 2
210000002374 sebum Anatomy 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
238000005063 solubilization Methods 0.000 description 2
230000007928 solubilization Effects 0.000 description 2
238000005406 washing Methods 0.000 description 2
LHOKCCUPZYSAJG-UHFFFAOYSA-N 6-oxohexyl acetate Chemical compound CC(=O)OCCCCCC=O LHOKCCUPZYSAJG-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
229920001634 Copolyester Polymers 0.000 description 1
108091005804 Peptidases Proteins 0.000 description 1
229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
239000004365 Protease Substances 0.000 description 1
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000003158 alcohol group Chemical group 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
230000000844 anti-bacterial effect Effects 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
238000000149 argon plasma sintering Methods 0.000 description 1
239000003899 bactericide agent Substances 0.000 description 1
235000021168 barbecue Nutrition 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
229940105329 carboxymethylcellulose Drugs 0.000 description 1
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000004872 foam stabilizing agent Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
238000007654 immersion Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000006193 liquid solution Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000000693 micelle Substances 0.000 description 1
239000010705 motor oil Substances 0.000 description 1
239000004006 olive oil Substances 0.000 description 1
235000008390 olive oil Nutrition 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
235000015067 sauces Nutrition 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
239000000341 volatile oil Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA000544828A 1986-09-02 1987-08-19 Laundry pre-spotter composition providing improved oily soil removal Expired - Lifetime CA1283511C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US90271686A	1986-09-02	1986-09-02
US902,716		1986-09-02

Publications (1)

Publication Number	Publication Date
CA1283511C true CA1283511C (en)	1991-04-30

Family

ID=25416291

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000544828A Expired - Lifetime CA1283511C (en)	1986-09-02	1987-08-19	Laundry pre-spotter composition providing improved oily soil removal

Country Status (19)

Country	Link
JP (1)	JPS6368700A (da)
AR (1)	AR243928A1 (da)
AU (1)	AU597414B2 (da)
BE (1)	BE1001724A4 (da)
BR (1)	BR8704494A (da)
CA (1)	CA1283511C (da)
DE (1)	DE3728547A1 (da)
DK (1)	DK449787A (da)
ES (1)	ES2005285A6 (da)
FR (1)	FR2603300B1 (da)
GB (1)	GB2194547B (da)
HK (1)	HK97893A (da)
IL (1)	IL83641A (da)
IT (1)	IT1211751B (da)
MY (1)	MY101656A (da)
NZ (1)	NZ221523A (da)
PH (1)	PH24177A (da)
TR (1)	TR24203A (da)
ZA (1)	ZA876158B (da)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3636085A1 (de) *	1986-10-23	1988-04-28	Henkel Kgaa	Wasserarmes, pastenfoermiges praeparat
US4954286A (en) *	1988-04-14	1990-09-04	Lever Brothers Company	Fabric pretreatment cleaning compositions
GB8913881D0 (en) *	1989-06-16	1989-08-02	Unilever Plc	Detergent compositions
ES2100884T3 (es) *	1989-06-29	1997-07-01	Buckeye Int	Composiciones perfeccionadas de microemulsiones acuosas para la limpieza/desengrase que contienen un adyuvante.
US5035826A (en) *	1989-09-22	1991-07-30	Colgate-Palmolive Company	Liquid crystal detergent composition
US5585034A (en) *	1991-11-21	1996-12-17	Colgate-Palmolive Co.	Gelled near tricritical point compositions
GB9225540D0 (en) *	1992-12-07	1993-01-27	Ici Plc	Cleaning compositions
AU671895B2 (en) *	1993-04-12	1996-09-12	Colgate-Palmolive Company, The	Tricritical point composition
US5750487A (en) *	1993-04-12	1998-05-12	Colgate-Palmolive Co.	Tricritical point compositions
US5643861A (en) *	1994-02-04	1997-07-01	Colgate-Palmolive Co.	Near tricritical point compositions containing a bleach and/or a disinfecting agent
US5527486A (en) *	1994-02-04	1996-06-18	Colgate-Palmolive Co.	Near tricritical point compositions
US5665268A (en) *	1994-02-04	1997-09-09	Deguertechin; Louis Oldenhove	Near tricritical point compositions
US5527485A (en) *	1994-02-04	1996-06-18	Colgate-Palmolive Co.	Near tricritical point compositions
AU1894695A (en) *	1994-03-31	1995-10-23	Unilever Plc	Detergent compositions
CA2173136A1 (en) *	1994-03-31	1995-10-12	Peter Robert Garrett	Detergent compositions
GB9413612D0 (en) *	1994-07-06	1994-08-24	Unilever Plc	Surfactant-oil microemulsion concentrates
CN1079823C (zh) *	1994-12-21	2002-02-27	花王株式会社	液体洗涤剂组合物
EP1010749B1 (en) *	1995-03-27	2006-02-22	The Procter & Gamble Company	Activated liquid bleaching compositions
DE19517815A1 (de) *	1995-05-18	1996-11-21	Henkel Ecolab Gmbh & Co Ohg	Flüssiges wasserhaltiges Mittel zur Reinigung von textilen Oberflächen
CA2238482C (en) *	1995-11-27	2005-04-12	The Procter & Gamble Company	Composition for treating stains on laundry items and methods of treatment
EP0776966B1 (en)	1995-12-02	2002-09-11	The Procter & Gamble Company	Liquid bleaching compositions packaged in spray-type dispenser and a process for pretreating fabrics therewith
DE19612811A1 (de) *	1996-03-30	1996-11-21	Astrid Grose	Vorbehandlungsmittel für stark öl- und fettverschmutzte Textilien in Form homogener, isotroper Mikroemulsionen
US5851976A (en) *	1997-12-08	1998-12-22	Colgate Palmolive Company	Microemulsion all purpose liquid cleaning compositions
DE10205134A1 (de) *	2002-02-07	2003-08-21	Henkel Kgaa	Reinigungspaste
US20040266643A1 (en) *	2003-06-27	2004-12-30	The Procter & Gamble Company	Fabric article treatment composition for use in a lipophilic fluid system
TWI400330B (zh) *	2005-12-28	2013-07-01	Kao Corp	Liquid detergent
JP4996970B2 (ja) *	2006-05-18	2012-08-08	花王株式会社	液体漂白性洗浄剤組成物
GB201021822D0 (en) *	2010-12-23	2011-02-02	Reckitt & Colman Overseas	Cleaning composition and method
DE102014202990A1 (de) *	2014-02-19	2015-08-20	Henkel Ag & Co. Kgaa	Konzentrate
EP3115447A1 (en) *	2015-07-09	2017-01-11	The Procter and Gamble Company	Method of pretreating fabrics
KR20230115301A (ko) *	2020-12-09	2023-08-02	바스프 에스이	C13 - 탄화수소 혼합물 및 그의 용도

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL179362A (nl) *	1952-06-30	1953-06-24	Metallgesellschaft Ag	Werkwijze ter bereiding van een reinigingsemulsie
JPS5139250B2 (da) *	1972-04-20	1976-10-27
FR2262692B1 (da) *	1974-02-28	1977-03-04	Raffinage Cie Francaise
NL8000452A (nl) *	1979-02-07	1980-08-11	Unilever Nv	Voorbehandelingsmiddel voor wasgoed.
GB2049722A (en) *	1979-05-05	1980-12-31	Barnes R I	A Cleansing Material
US4438009A (en) *	1981-08-14	1984-03-20	S. C. Johnson & Son, Inc.	Low solvent laundry pre-spotting composition

1987
- 1987-08-19 CA CA000544828A patent/CA1283511C/en not_active Expired - Lifetime
- 1987-08-19 MY MYPI87001376A patent/MY101656A/en unknown
- 1987-08-19 ZA ZA876158A patent/ZA876158B/xx unknown
- 1987-08-20 NZ NZ221523A patent/NZ221523A/xx unknown
- 1987-08-21 AU AU77335/87A patent/AU597414B2/en not_active Ceased
- 1987-08-23 IL IL83641A patent/IL83641A/xx not_active IP Right Cessation
- 1987-08-25 PH PH35734A patent/PH24177A/en unknown
- 1987-08-27 DE DE19873728547 patent/DE3728547A1/de not_active Withdrawn
- 1987-08-27 DK DK449787A patent/DK449787A/da not_active Application Discontinuation
- 1987-08-31 TR TR87/0601A patent/TR24203A/xx unknown
- 1987-09-01 ES ES8702539A patent/ES2005285A6/es not_active Expired
- 1987-09-01 IT IT8748342A patent/IT1211751B/it active
- 1987-09-01 GB GB8720556A patent/GB2194547B/en not_active Expired - Lifetime
- 1987-09-01 BR BR8704494A patent/BR8704494A/pt not_active Application Discontinuation
- 1987-09-02 AR AR87308597A patent/AR243928A1/es active
- 1987-09-02 BE BE8700978A patent/BE1001724A4/fr not_active IP Right Cessation
- 1987-09-02 FR FR8712215A patent/FR2603300B1/fr not_active Expired - Fee Related
- 1987-09-02 JP JP62220073A patent/JPS6368700A/ja active Pending
1993
- 1993-09-23 HK HK978/93A patent/HK97893A/xx unknown

Also Published As

Publication number	Publication date
JPS6368700A (ja)	1988-03-28
BE1001724A4 (fr)	1990-02-20
BR8704494A (pt)	1988-04-19
IL83641A0 (en)	1988-01-31
ZA876158B (en)	1989-04-26
IL83641A (en)	1990-11-05
DK449787D0 (da)	1987-08-27
FR2603300B1 (fr)	1993-05-28
IT1211751B (it)	1989-11-03
NZ221523A (en)	1990-07-26
FR2603300A1 (fr)	1988-03-04
AU597414B2 (en)	1990-05-31
AR243928A1 (es)	1993-09-30
GB2194547B (en)	1990-07-11
DE3728547A1 (de)	1988-03-03
AU7733587A (en)	1988-03-10
PH24177A (en)	1990-03-22
HK97893A (en)	1993-09-30
TR24203A (tr)	1991-07-01
GB2194547A (en)	1988-03-09
DK449787A (da)	1988-03-03
IT8748342A0 (it)	1987-09-01
ES2005285A6 (es)	1989-03-01
GB8720556D0 (en)	1987-10-07
MY101656A (en)	1991-12-31

Legal Events

Date	Code	Title	Description
2000-05-01	MKLA	Lapsed

Publication	Publication Date	Title
CA1283511C (en)	1991-04-30	Laundry pre-spotter composition providing improved oily soil removal
US4909962A (en)	1990-03-20	Laundry pre-spotter comp. providing improved oily soil removal
US5415812A (en)	1995-05-16	Light duty microemulsion liquid detergent composition
US5585034A (en)	1996-12-17	Gelled near tricritical point compositions
US4595527A (en)	1986-06-17	Aqueous laundry prespotting composition
CA1230534A (en)	1987-12-22	Stabilized oil-in-water cleaning microemulsions
CA1236372A (en)	1988-05-10	Liquid detergents with solvent
US3935129A (en)	1976-01-27	Liquid cleaning compositions
JPS6121599B2 (da)	1986-05-28
US5643861A (en)	1997-07-01	Near tricritical point compositions containing a bleach and/or a disinfecting agent
US6468954B2 (en)	2002-10-22	Blood, coffee or fruit juice stain remover in an alkaline composition
EP0803567A2 (en)	1997-10-29	Aqueous cleaning composition providing water and oil repellency to fibre substrates
JPH03207799A (ja)	1991-09-11	液晶洗剤組成物
EP0210270A1 (en)	1987-02-04	Hard surface cleaning composition and cleaning method using same
CA2270730A1 (en)	1999-11-01	Stable alkaline emulsion cleaners
JP2002506924A (ja)	2002-03-05	液体多相洗剤
CA1230535A (en)	1987-12-22	Cleaning compositions with solvent
US4861516A (en)	1989-08-29	Laundry pretreatment composition for oily and greasy soil
US6146427A (en)	2000-11-14	Method for cleaning hydrocarbon-containing greases and oils from fabric in laundry washing applications
JP7350047B2 (ja)	2023-09-25	衣料用液体洗浄剤組成物
JP3610434B2 (ja)	2005-01-12	非イオン界面活性剤
CA2143108A1 (en)	1994-03-03	Liquid cleaning compositions comprising primary alkyl sulphate and non-ionic surfactants
JPH0631413B2 (ja)	1994-04-27	予備しみ抜き性洗濯洗剤
CA2173137A1 (en)	1995-10-12	Detergent compositions
US4588516A (en)	1986-05-13	Cleaning liquid and process of using same