CA1284277C - Method of and device for storing and transforming heat and generatingcold - Google Patents
Method of and device for storing and transforming heat and generatingcoldInfo
- Publication number
- CA1284277C CA1284277C CA000552268A CA552268A CA1284277C CA 1284277 C CA1284277 C CA 1284277C CA 000552268 A CA000552268 A CA 000552268A CA 552268 A CA552268 A CA 552268A CA 1284277 C CA1284277 C CA 1284277C
- Authority
- CA
- Canada
- Prior art keywords
- hydride
- heat
- temperature
- metal
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 18
- 230000001131 transforming effect Effects 0.000 title claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 55
- 239000001257 hydrogen Substances 0.000 claims abstract description 55
- 229910012375 magnesium hydride Inorganic materials 0.000 claims abstract description 43
- 150000004678 hydrides Chemical class 0.000 claims abstract description 29
- 238000010494 dissociation reaction Methods 0.000 claims abstract description 13
- 229910052987 metal hydride Inorganic materials 0.000 claims abstract description 11
- 150000004681 metal hydrides Chemical class 0.000 claims abstract description 11
- 230000005593 dissociations Effects 0.000 claims abstract description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 52
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 47
- 239000011777 magnesium Substances 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910001122 Mischmetal Inorganic materials 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- IXQWNVPHFNLUGD-UHFFFAOYSA-N iron titanium Chemical compound [Ti].[Fe] IXQWNVPHFNLUGD-UHFFFAOYSA-N 0.000 claims description 2
- 229910000599 Cr alloy Inorganic materials 0.000 claims 1
- 229910000640 Fe alloy Inorganic materials 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 229910000914 Mn alloy Inorganic materials 0.000 claims 1
- 229910001069 Ti alloy Inorganic materials 0.000 claims 1
- 229910000756 V alloy Inorganic materials 0.000 claims 1
- 229910001093 Zr alloy Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 238000011084 recovery Methods 0.000 abstract description 18
- RSHAOIXHUHAZPM-UHFFFAOYSA-N magnesium hydride Chemical compound [MgH2] RSHAOIXHUHAZPM-UHFFFAOYSA-N 0.000 abstract 4
- 238000005338 heat storage Methods 0.000 description 32
- 238000003860 storage Methods 0.000 description 11
- 235000001055 magnesium Nutrition 0.000 description 10
- 229940091250 magnesium supplement Drugs 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 239000007787 solid Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000001816 cooling Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- -1 Mg2NiH4 for instance Chemical compound 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 238000004378 air conditioning Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000005057 refrigeration Methods 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- 239000011232 storage material Substances 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 229910005438 FeTi Inorganic materials 0.000 description 2
- 229910003310 Ni-Al Inorganic materials 0.000 description 2
- 229910003271 Ni-Fe Inorganic materials 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010022998 Irritability Diseases 0.000 description 1
- 229910018561 MmNi5 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940099990 ogen Drugs 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003334 potential effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/16—Materials undergoing chemical reactions when used
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Central Heating Systems (AREA)
- Vending Machines For Individual Products (AREA)
- Forklifts And Lifting Vehicles (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
- Electrotherapy Devices (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3639545.5 | 1986-11-20 | ||
| DE3639545A DE3639545C1 (de) | 1986-11-20 | 1986-11-20 | Verfahren zur Waermespeicherung und -transformation sowie Kaelteerzeugung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1284277C true CA1284277C (en) | 1991-05-21 |
Family
ID=6314301
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000552268A Expired - Lifetime CA1284277C (en) | 1986-11-20 | 1987-11-19 | Method of and device for storing and transforming heat and generatingcold |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4829772A (da) |
| EP (1) | EP0271732B1 (da) |
| JP (1) | JP2711274B2 (da) |
| AT (1) | ATE71130T1 (da) |
| AU (1) | AU602467B2 (da) |
| CA (1) | CA1284277C (da) |
| DE (2) | DE3639545C1 (da) |
| DK (1) | DK163252C (da) |
| ES (1) | ES2027683T3 (da) |
| IE (1) | IE59097B1 (da) |
| ZA (1) | ZA878711B (da) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4126960A1 (de) * | 1991-08-14 | 1993-02-18 | Zeolith Tech | Sorptionsapparat zum kuehlen und/oder heizen |
| DE4132440A1 (de) * | 1991-09-28 | 1993-05-27 | Emitec Emissionstechnologie | Anordnung zur aufheizung eines abgaskatalysators |
| US5347828A (en) * | 1993-03-23 | 1994-09-20 | United Technologies Corporation | Organic hydride/metal hydride heat pump |
| DE10360303B4 (de) * | 2003-12-20 | 2007-11-22 | Airbus Deutschland Gmbh | Heizsystem für den Einsatz in Bordküchen von Verkehrsmitteln sowie ein Verfahren zur Erwärmung von Nahrungsmitteln an Bord von Verkehrsmitteln, insbesondere Luftfahrzeugen |
| PL202005B1 (pl) * | 2004-11-19 | 2009-05-29 | Politechnika & Lstrok Odzka In | Urządzenie do hartowania z zamkniętym obiegiem wodoru |
| US20120266863A1 (en) * | 2011-04-20 | 2012-10-25 | Surendra Saxena | Solar-Hydrogen Hybrid Storage System for Naval and Other Uses |
| DE102014006372A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Schichten eines Wasserstoffspeichers und deren Herstellung |
| DE102014006368A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Schüttfähiges, hydrierbares Material zur Verwendung in einem Wasserstoffspeicher |
| DE102014006376A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Wasserstoffspeichernde Komponente aus einer Schmelze |
| DE102014006369A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Wasserstoffspeicher rnit einem Verbundmaterial und ein Verfahren zur Herstellung |
| DE102014006379A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Wasserstoffspeichernde Komponenten aus Schlicker nebst Vorrichtung und Verfahren dafür |
| DE102014006374A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Vorrichtung zur Herstellung eines Rohlings nebst Verfahren hierzu und Rohling |
| DE102014006373A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Wasserstoffspeicher mit kompensierter Volumenänderung |
| DE102014006371A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Wasserstoffspeicher-Herstellvorrichtung nebst Verfahren hierzu und Wasserstoffspeicher |
| DE102014006366A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Verfahren und Vorrichtung zur strukturweisen Herstellung eines Hydridspeichers |
| DE102014006377A1 (de) | 2014-05-05 | 2015-11-05 | Gkn Sinter Metals Engineering Gmbh | Wasserstoffspeicher mit einem hydrierbaren Material und einer Matrix |
| JP6036747B2 (ja) * | 2014-05-09 | 2016-11-30 | 株式会社豊田中央研究所 | ガス貯蔵・供給システム |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4161211A (en) * | 1975-06-30 | 1979-07-17 | International Harvester Company | Methods of and apparatus for energy storage and utilization |
| GB1503850A (en) * | 1975-08-19 | 1978-03-15 | Us Energy | Method and apparatus for thermal energy storage |
| US4096639A (en) * | 1976-11-08 | 1978-06-27 | The International Nickel Company, Inc. | Nickel-mischmetal-calcium alloys for hydrogen storage |
| DE2715990A1 (de) * | 1977-04-09 | 1978-10-12 | Daimler Benz Ag | Standheizung durch hydride in wasserstoff-fahrzeugen |
| DE2750463A1 (de) * | 1977-11-11 | 1979-05-17 | Daimler Benz Ag | Brennkraftmaschine |
| DE2800903C2 (de) * | 1978-01-10 | 1982-11-25 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zur Energiespeicherung in Form von Wärme |
| DE3340492A1 (de) * | 1983-11-09 | 1985-05-15 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendung |
| DE3247361A1 (de) * | 1982-12-22 | 1984-06-28 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zur abtrennung und reinigung von wasserstoff |
| DE3247360A1 (de) * | 1982-12-22 | 1984-07-05 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zur herstellung aktiver magnetsiumhdrid-magnesium-wasserstoffspeichersysteme |
| US4178987A (en) * | 1978-07-12 | 1979-12-18 | Standard Oil Company, A Corporation Of Indiana | Moving bed hydride/dehydride systems |
| JPS5546372A (en) * | 1978-09-28 | 1980-04-01 | Matsushita Electric Ind Co Ltd | Heat controlling device |
| DE2921451A1 (de) * | 1979-05-26 | 1980-12-04 | Daimler Benz Ag | Verfahren zum vorwaermen von kraftfahrzeugen mit verbrennungsmotor |
| JPS5795563A (en) * | 1980-11-13 | 1982-06-14 | Sekisui Chemical Co Ltd | Heat pump apparatus |
| US4433063A (en) * | 1981-01-19 | 1984-02-21 | Mpd Technology Corporation | Hydrogen sorbent composition |
| DE3145019A1 (de) * | 1981-11-12 | 1983-05-19 | Linde Ag, 6200 Wiesbaden | Verfahren zum erhitzen eines waermetraegers mit einer hydrid-waermepumpe |
| US4402187A (en) * | 1982-05-12 | 1983-09-06 | Mpd Technology Corporation | Hydrogen compressor |
| JPS59125367A (ja) * | 1982-12-29 | 1984-07-19 | 松下電器産業株式会社 | 携帯用冷却装置 |
| JPS60218562A (ja) * | 1984-04-13 | 1985-11-01 | 株式会社日立製作所 | ケミカルヒ−トポンプ |
| US4599867A (en) * | 1985-01-25 | 1986-07-15 | Retallick William B | Hydrogen storage cell |
-
1986
- 1986-11-20 DE DE3639545A patent/DE3639545C1/de not_active Expired
-
1987
- 1987-11-16 US US07/121,330 patent/US4829772A/en not_active Expired - Lifetime
- 1987-11-18 EP EP87117016A patent/EP0271732B1/en not_active Expired - Lifetime
- 1987-11-18 DE DE8787117016T patent/DE3775734D1/de not_active Expired - Lifetime
- 1987-11-18 AT AT87117016T patent/ATE71130T1/de not_active IP Right Cessation
- 1987-11-18 ES ES198787117016T patent/ES2027683T3/es not_active Expired - Lifetime
- 1987-11-19 IE IE311787A patent/IE59097B1/en not_active IP Right Cessation
- 1987-11-19 CA CA000552268A patent/CA1284277C/en not_active Expired - Lifetime
- 1987-11-20 ZA ZA878711A patent/ZA878711B/xx unknown
- 1987-11-20 AU AU81447/87A patent/AU602467B2/en not_active Ceased
- 1987-11-20 JP JP62294993A patent/JP2711274B2/ja not_active Expired - Lifetime
- 1987-11-20 DK DK612287A patent/DK163252C/da not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US4829772A (en) | 1989-05-16 |
| DK612287D0 (da) | 1987-11-20 |
| ATE71130T1 (de) | 1992-01-15 |
| EP0271732A2 (en) | 1988-06-22 |
| JPS63148060A (ja) | 1988-06-20 |
| JP2711274B2 (ja) | 1998-02-10 |
| ZA878711B (en) | 1988-05-17 |
| AU8144787A (en) | 1988-05-26 |
| DE3639545C1 (de) | 1988-06-01 |
| EP0271732B1 (en) | 1992-01-02 |
| IE873117L (en) | 1988-05-20 |
| DK612287A (da) | 1988-05-21 |
| AU602467B2 (en) | 1990-10-11 |
| DK163252B (da) | 1992-02-10 |
| DE3775734D1 (de) | 1992-02-13 |
| ES2027683T3 (es) | 1992-06-16 |
| DK163252C (da) | 1992-06-29 |
| IE59097B1 (en) | 1994-01-12 |
| EP0271732A3 (en) | 1988-07-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |