CA1284557C - Methode de preparation de la pate a papier a partir de matiere brute lignocellulosique - Google Patents

Methode de preparation de la pate a papier a partir de matiere brute lignocellulosique

Info

Publication number: CA1284557C
Authority: CA; Canada
Prior art keywords: stage; pulp; acid; hydrogen peroxide; liquor
Prior art date: 1986-02-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000507591A

Other languages

English (en)

Inventor

Lauri Aukusti Laamanen

Jorma Juhani Sundquist

Seppo Veli-Matti Kauliomaki

Ilkka Yrjo Paavo Wartiovaara

Kristiina Johanna Poppius

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

KESKUSLABORATORIO - CENTRALLABORATORIUM Oy AB

Original Assignee

KESKUSLABORATORIO - CENTRALLABORATORIUM Oy AB

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-02-11

Filing date

1986-04-25

Publication date

1991-06-04

1986-02-11 Priority claimed from FI860609A external-priority patent/FI74750C/fi

1986-04-25 Application filed by KESKUSLABORATORIO - CENTRALLABORATORIUM Oy AB filed Critical KESKUSLABORATORIO - CENTRALLABORATORIUM Oy AB

1991-06-04 Application granted granted Critical

1991-06-04 Publication of CA1284557C publication Critical patent/CA1284557C/fr

2008-06-04 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000002994 raw material Substances 0.000 title claims abstract description 22
238000004519 manufacturing process Methods 0.000 title claims description 5
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 115
238000000034 method Methods 0.000 claims abstract description 75
230000008569 process Effects 0.000 claims abstract description 60
238000010411 cooking Methods 0.000 claims abstract description 52
238000011282 treatment Methods 0.000 claims abstract description 35
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 33
239000000243 solution Substances 0.000 claims abstract description 23
239000012670 alkaline solution Substances 0.000 claims abstract description 5
150000004967 organic peroxy acids Chemical class 0.000 claims abstract description 4
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 57
150000002978 peroxides Chemical class 0.000 claims description 37
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 30
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 30
238000004061 bleaching Methods 0.000 claims description 29
235000019253 formic acid Nutrition 0.000 claims description 28
239000003513 alkali Substances 0.000 claims description 24
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 23
150000004965 peroxy acids Chemical class 0.000 claims description 22
239000002253 acid Substances 0.000 claims description 19
239000002023 wood Substances 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 13
241001263092 Alchornea latifolia Species 0.000 claims description 10
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 8
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 7
238000009835 boiling Methods 0.000 claims description 7
229960003330 pentetic acid Drugs 0.000 claims description 7
239000003381 stabilizer Substances 0.000 claims description 7
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
239000013543 active substance Substances 0.000 claims description 3
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 3
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims 2
229910052943 magnesium sulfate Inorganic materials 0.000 claims 1
235000019341 magnesium sulphate Nutrition 0.000 claims 1
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 abstract description 6
SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 abstract description 5
229960002163 hydrogen peroxide Drugs 0.000 description 46
229940013688 formic acid Drugs 0.000 description 24
238000004537 pulping Methods 0.000 description 22
239000000126 substance Substances 0.000 description 16
229920005610 lignin Polymers 0.000 description 8
235000018185 Betula X alpestris Nutrition 0.000 description 7
235000018212 Betula X uliginosa Nutrition 0.000 description 7
235000011054 acetic acid Nutrition 0.000 description 7
235000008331 Pinus X rigitaeda Nutrition 0.000 description 6
241000018646 Pinus brutia Species 0.000 description 6
235000011613 Pinus brutia Nutrition 0.000 description 6
230000007613 environmental effect Effects 0.000 description 6
239000003054 catalyst Substances 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
239000002655 kraft paper Substances 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
241000218657 Picea Species 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
150000001735 carboxylic acids Chemical class 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
230000007423 decrease Effects 0.000 description 4
230000003247 decreasing effect Effects 0.000 description 4
230000001590 oxidative effect Effects 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
150000001805 chlorine compounds Chemical class 0.000 description 3
150000002431 hydrogen Chemical class 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
239000003265 pulping liquor Substances 0.000 description 3
238000011084 recovery Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
239000005864 Sulphur Substances 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000002411 adverse Effects 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000008044 alkali metal hydroxides Chemical class 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
-1 carboxylic acids peroxyacids Chemical class 0.000 description 2
230000001627 detrimental effect Effects 0.000 description 2
OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000011121 hardwood Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
239000000123 paper Substances 0.000 description 2
239000011087 paperboard Substances 0.000 description 2
239000011122 softwood Substances 0.000 description 2
241000894007 species Species 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
235000011149 sulphuric acid Nutrition 0.000 description 2
241000609240 Ambelania acida Species 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
239000004155 Chlorine dioxide Substances 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
229920002522 Wood fibre Polymers 0.000 description 1
OGIIWTRTOXDWEH-UHFFFAOYSA-N [O].[O-][O+]=O Chemical compound [O].[O-][O+]=O OGIIWTRTOXDWEH-UHFFFAOYSA-N 0.000 description 1
HYJODZUSLXOFNC-UHFFFAOYSA-N [S].[Cl] Chemical compound [S].[Cl] HYJODZUSLXOFNC-UHFFFAOYSA-N 0.000 description 1
150000001243 acetic acids Chemical class 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
239000010905 bagasse Substances 0.000 description 1
235000010338 boric acid Nutrition 0.000 description 1
125000005619 boric acid group Chemical class 0.000 description 1
238000001354 calcination Methods 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
235000019398 chlorine dioxide Nutrition 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
229940035564 duration Drugs 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
HQVFCQRVQFYGRJ-UHFFFAOYSA-N formic acid;hydrate Chemical compound O.OC=O HQVFCQRVQFYGRJ-UHFFFAOYSA-N 0.000 description 1
150000004674 formic acids Chemical class 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
239000012978 lignocellulosic material Substances 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
150000004972 metal peroxides Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
235000011007 phosphoric acid Nutrition 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000010902 straw Substances 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000001117 sulphuric acid Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
210000002268 wool Anatomy 0.000 description 1

Landscapes

Paper (AREA)

CA000507591A 1986-02-11 1986-04-25 Methode de preparation de la pate a papier a partir de matiere brute lignocellulosique Expired - Lifetime CA1284557C (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
FI860609		1986-02-11
FI860609A FI74750C (fi)	1985-03-22	1986-02-11	Foerfarande foer framstaellning av blekt cellulosamassa utav ligninhaltigt raomaterial.
FIPCTF186/00028		1986-03-24
PCT/FI1986/000028 WO1986005529A1 (fr)	1985-03-22	1986-03-24	Procede de preparation de pate a papier blanchie a partir de matieres premieres lignocellulosiques

Publications (1)

Publication Number	Publication Date
CA1284557C true CA1284557C (fr)	1991-06-04

Family

ID=26157899

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000507591A Expired - Lifetime CA1284557C (fr)	1986-02-11	1986-04-25	Methode de preparation de la pate a papier a partir de matiere brute lignocellulosique

Country Status (1)

Country	Link
CA (1)	CA1284557C (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112127192A (zh) *	2019-06-24	2020-12-25	广州腾龙材料科技有限公司	复合脱色碱式增白剂及其制备方法与应用

1986
- 1986-04-25 CA CA000507591A patent/CA1284557C/fr not_active Expired - Lifetime

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112127192A (zh) *	2019-06-24	2020-12-25	广州腾龙材料科技有限公司	复合脱色碱式增白剂及其制备方法与应用

Legal Events

Date	Code	Title	Description
2005-06-06	MKLA	Lapsed

Publication	Publication Date	Title
US4793898A (en)	1988-12-27	Process for bleaching organic peroxyacid cooked material with an alkaline solution of hydrogen peroxide
US4576609A (en)	1986-03-18	Process for the treatment of cellulosic materials with oxidizing agents and microwaves
US6258207B1 (en)	2001-07-10	Alkaline peroxide mechanical pulping of non-woody species
CA2270524C (fr)	2008-02-19	Procede de fabrication de pulpe par cuisson a l'acide formique effectuee en une seule operation et par lavage a l'acide performique
US3652388A (en)	1972-03-28	Bleaching and delignification of partially delignified pulp with a mixture of chlorine and chlorine dioxide
US8152960B2 (en)	2012-04-10	Lignocellulosic fibrous material made of wood
EP0250422B1 (fr)	1990-06-13	Procede de preparation de pate a papier blanchie de matieres lignocellulosiques
US5411635A (en)	1995-05-02	Ozone/peroxymonosulfate process for delignifying a lignocellulosic material
US5431781A (en)	1995-07-11	Process for the delignification of a chemical paper pulp with organic peroxy acid
Kubes et al.	1980	Alkaline pulping with additives. A review
JPH1181173A (ja)	1999-03-26	漂白パルプの製造方法
EP0789798B1 (fr)	1998-06-24	Procede de delignification et de blanchiment de cellulose chimique
WO2003083208A1 (fr)	2003-10-09	Procede de blanchiment de pulpe non ligneuse contenant de la lignocellulose
JPH0672385B2 (ja)	1994-09-14	リグノセルロース材料の漂白方法
CA1284557C (fr)	1991-06-04	Methode de preparation de la pate a papier a partir de matiere brute lignocellulosique
US3458394A (en)	1969-07-29	Pulping wood chips with peracetic acid and chlorine dioxide
WO1994018386A1 (fr)	1994-08-18	Procede ameliore et composition de delignification d'un materiau lignocellulosique
KR100228740B1 (ko)	1999-11-01	고수율기계펄프의 표백방법
JP2000110089A (ja)	2000-04-18	漂白パルプの製造方法
CA2258443A1 (fr)	1999-07-22	Procede de blanchiment de pate comprenant une etape finale d'avivage a l'aide de sel d'acide peroxymonosulfurique
JPH10331084A (ja)	1998-12-15	パルプ化用溶液及びパルプの製造方法
LÖNNBERG	2001	2.1 Wood fibre sources
JPH05279978A (ja)	1993-10-26	リグノセルロース物質の漂白方法
KR19990036671A (ko)	1999-05-25	화학 제지용 펄프의 표백법
WO1987007314A1 (fr)	1987-12-03	Procede de preblanchiment de pulpes de cellulose chimiquement traitees

CA1284557C - Methode de preparation de la pate a papier a partir de matiere brute lignocellulosique - Google Patents

Info

Links

Landscapes

Applications Claiming Priority (4)

Publications (1)

Family

ID=26157899

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

Similar Documents

Legal Events