CA1284980C - Tamis moleculaires de carbone absorbant le mercure - Google Patents

Tamis moleculaires de carbone absorbant le mercure

Info

Publication number: CA1284980C
Authority: CA; Canada
Prior art keywords: mercury; molecular sieve; impregnated; carbon molecular; carbon
Prior art date: 1983-11-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000526206A

Other languages

English (en)

Inventor

Thomas M. Matviya

Robert S. Gebhard

Michael Greenbank

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Calgon Carbon Corp

Original Assignee

Calgon Carbon Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-11-03

Filing date

1986-12-23

Publication date

1991-06-18

1986-12-23 Application filed by Calgon Carbon Corp filed Critical Calgon Carbon Corp

1986-12-23 Priority to CA000526206A priority Critical patent/CA1284980C/fr

1991-06-18 Application granted granted Critical

1991-06-18 Publication of CA1284980C publication Critical patent/CA1284980C/fr

2008-06-18 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 114
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims abstract description 104
229910052799 carbon Inorganic materials 0.000 title claims abstract description 78
239000002808 molecular sieve Substances 0.000 title claims abstract description 56
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 56
229910052753 mercury Inorganic materials 0.000 title claims abstract description 40
239000003463 adsorbent Substances 0.000 title abstract description 42
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 40
239000007789 gas Substances 0.000 claims abstract description 36
239000000463 material Substances 0.000 claims abstract description 27
229910052757 nitrogen Inorganic materials 0.000 claims abstract description 20
238000000034 method Methods 0.000 claims abstract description 15
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 50
229910052717 sulfur Inorganic materials 0.000 claims description 43
239000011593 sulfur Substances 0.000 claims description 43
239000010457 zeolite Substances 0.000 claims description 11
235000013162 Cocos nucifera Nutrition 0.000 claims description 10
244000060011 Cocos nucifera Species 0.000 claims description 10
229910021536 Zeolite Inorganic materials 0.000 claims description 9
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
239000003245 coal Substances 0.000 claims description 7
235000014643 Orbignya martiana Nutrition 0.000 claims description 5
244000021150 Orbignya martiana Species 0.000 claims description 5
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
239000003345 natural gas Substances 0.000 claims description 2
150000003568 thioethers Chemical class 0.000 claims 1
239000000203 mixture Substances 0.000 description 16
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
239000001301 oxygen Substances 0.000 description 9
229910052760 oxygen Inorganic materials 0.000 description 9
239000011148 porous material Substances 0.000 description 9
238000012360 testing method Methods 0.000 description 8
229920006395 saturated elastomer Polymers 0.000 description 6
238000001179 sorption measurement Methods 0.000 description 6
238000000926 separation method Methods 0.000 description 5
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
238000005470 impregnation Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 3
238000009792 diffusion process Methods 0.000 description 3
150000003384 small molecules Chemical class 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
230000002411 adverse Effects 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
239000010931 gold Substances 0.000 description 2
-1 high efficiency Chemical compound 0.000 description 2
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
238000000746 purification Methods 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
WRTMQOHKMFDUKX-UHFFFAOYSA-N triiodide Chemical compound I[I-]I WRTMQOHKMFDUKX-UHFFFAOYSA-N 0.000 description 2
101100172879 Caenorhabditis elegans sec-5 gene Proteins 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910019093 NaOCl Inorganic materials 0.000 description 1
240000009305 Pometia pinnata Species 0.000 description 1
235000017284 Pometia pinnata Nutrition 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
241000212342 Sium Species 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
239000003570 air Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
239000003830 anthracite Substances 0.000 description 1
239000002802 bituminous coal Substances 0.000 description 1
230000000903 blocking effect Effects 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000012159 carrier gas Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000000571 coke Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000011109 contamination Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
239000003814 drug Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
235000013305 food Nutrition 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
238000010926 purge Methods 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000012216 screening Methods 0.000 description 1
238000007873 sieving Methods 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
150000003463 sulfur Chemical class 0.000 description 1
239000011135 tin Substances 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
VITRLXDSBBVNCZ-UHFFFAOYSA-K trichloroiron;hydrate Chemical compound O.Cl[Fe](Cl)Cl VITRLXDSBBVNCZ-UHFFFAOYSA-K 0.000 description 1

Landscapes

Solid-Sorbent Or Filter-Aiding Compositions (AREA)

CA000526206A 1983-11-03 1986-12-23 Tamis moleculaires de carbone absorbant le mercure Expired - Fee Related CA1284980C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000526206A CA1284980C (fr)	1983-11-03	1986-12-23	Tamis moleculaires de carbone absorbant le mercure

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US54847183A	1983-11-03	1983-11-03
CA000526206A CA1284980C (fr)	1983-11-03	1986-12-23	Tamis moleculaires de carbone absorbant le mercure

Publications (1)

Publication Number	Publication Date
CA1284980C true CA1284980C (fr)	1991-06-18

Family

ID=25671188

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000526206A Expired - Fee Related CA1284980C (fr)	1983-11-03	1986-12-23	Tamis moleculaires de carbone absorbant le mercure

Country Status (1)

Country	Link
CA (1)	CA1284980C (fr)

1986
- 1986-12-23 CA CA000526206A patent/CA1284980C/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
2000-06-19	MKLA	Lapsed

Publication	Publication Date	Title
US6491740B1 (en)	2002-12-10	Metallo-organic polymers for gas separation and purification
US4775396A (en)	1988-10-04	Selective adsorption of CO2 on zeolites
CA1081135A (fr)	1980-07-08	Adsorption selective de mercure contenu dans des courants gazeux
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US5244641A (en)	1993-09-14	Absorption of hydrogen sulfide and absorbent composition therefor
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EP0271618A1 (fr)	1988-06-22	Tamis moléculaires de carbone pour l'absorption de mercure
EP0145539B1 (fr)	1990-01-10	Carbones absorbant le mercure et tamis moléculaires carbonacés
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US5895520A (en)	1999-04-20	Method of separating noxious substances from exhaust gases
US3616602A (en)	1971-11-02	Low-temperature purification of fluids
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WO2005061421A1 (fr)	2005-07-07	Elimination regeneratrice de monoxyde de carbone en traces
JPH0233416B2 (fr)	1990-07-27
US4442077A (en)	1984-04-10	Method of removing hydrides of phosphorus, arsenic, antimony and bismuth from hydrocarbon and non-hydrocarbon streams
JPH01164418A (ja)	1989-06-28	二酸化炭素の除去方法
Ray	1983	The separation and purification of gases using solid adsorbents
CA1167236A (fr)	1984-05-15	Separation de l'acide chlorhydrique des melanges gazeux
JPS60241931A (ja)	1985-11-30	圧力変動式吸着分離用の吸着剤
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