CA1292974C - Methode de preparation d'un catalyseur a l'argent - Google Patents

Methode de preparation d'un catalyseur a l'argent

Info

Publication number: CA1292974C
Authority: CA; Canada
Prior art keywords: silver; compound; carrier; process according; aluminium
Prior art date: 1987-04-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000533855A

Other languages

English (en)

Inventor

Gosse Boxhoorn

Aan Hendrik Klazinga

Otto Mente Velthuis

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Canada Ltd

Original Assignee

Shell Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-04-03

Filing date

1987-04-03

Publication date

1991-12-10

1987-04-03 Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd

1987-04-03 Priority to CA000533855A priority Critical patent/CA1292974C/fr

1991-12-10 Application granted granted Critical

1991-12-10 Publication of CA1292974C publication Critical patent/CA1292974C/fr

2008-12-10 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 50
229910052709 silver Inorganic materials 0.000 title claims abstract description 49
239000004332 silver Substances 0.000 title claims abstract description 46
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 45
238000000034 method Methods 0.000 title claims abstract description 36
238000002360 preparation method Methods 0.000 title claims abstract description 17
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 20
239000000203 mixture Substances 0.000 claims abstract description 15
229910052751 metal Inorganic materials 0.000 claims abstract description 13
239000002184 metal Substances 0.000 claims abstract description 13
150000001399 aluminium compounds Chemical class 0.000 claims abstract description 12
238000001354 calcination Methods 0.000 claims abstract description 12
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 11
239000005977 Ethylene Substances 0.000 claims abstract description 11
150000004812 organic fluorine compounds Chemical class 0.000 claims abstract description 11
229940100890 silver compound Drugs 0.000 claims abstract description 11
150000003379 silver compounds Chemical class 0.000 claims abstract description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 8
230000000737 periodic effect Effects 0.000 claims abstract description 8
238000007254 oxidation reaction Methods 0.000 claims abstract description 7
230000003647 oxidation Effects 0.000 claims abstract description 6
238000002156 mixing Methods 0.000 claims abstract description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 36
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 claims description 16
229910052783 alkali metal Inorganic materials 0.000 claims description 15
150000001340 alkali metals Chemical class 0.000 claims description 12
229910052792 caesium Inorganic materials 0.000 claims description 12
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 12
-1 alkane carboxylic acid Chemical class 0.000 claims description 11
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 8
239000011591 potassium Substances 0.000 claims description 7
229910052701 rubidium Inorganic materials 0.000 claims description 7
150000003839 salts Chemical class 0.000 claims description 7
229910052700 potassium Inorganic materials 0.000 claims description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
239000002245 particle Substances 0.000 claims description 5
125000004429 atom Chemical group 0.000 claims description 3
150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
229910001854 alkali hydroxide Inorganic materials 0.000 claims description 2
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
150000001336 alkenes Chemical class 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
150000002148 esters Chemical class 0.000 claims description 2
229920000642 polymer Polymers 0.000 claims description 2
150000001875 compounds Chemical class 0.000 claims 1
239000001301 oxygen Substances 0.000 description 19
229910052760 oxygen Inorganic materials 0.000 description 19
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 18
239000000243 solution Substances 0.000 description 18
238000006243 chemical reaction Methods 0.000 description 17
229960005363 aluminium oxide Drugs 0.000 description 10
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 8
238000012360 testing method Methods 0.000 description 8
239000007864 aqueous solution Substances 0.000 description 7
239000003513 alkali Substances 0.000 description 6
XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 description 6
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 6
239000007789 gas Substances 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
239000002253 acid Substances 0.000 description 4
229910001961 silver nitrate Inorganic materials 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
230000001419 dependent effect Effects 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000007858 starting material Substances 0.000 description 3
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
229940037003 alum Drugs 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
239000004411 aluminium Substances 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
239000000969 carrier Substances 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
238000005259 measurement Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
229960005419 nitrogen Drugs 0.000 description 2
239000011148 porous material Substances 0.000 description 2
235000011164 potassium chloride Nutrition 0.000 description 2
239000001103 potassium chloride Substances 0.000 description 2
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
239000000843 powder Substances 0.000 description 2
NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
238000013112 stability test Methods 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 description 1
LRMSQVBRUNSOJL-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)F LRMSQVBRUNSOJL-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
RLUCLSNBJDVJCG-UHFFFAOYSA-L C=C.C(C(=O)[O-])(=O)[O-].[Ag+2] Chemical group C=C.C(C(=O)[O-])(=O)[O-].[Ag+2] RLUCLSNBJDVJCG-UHFFFAOYSA-L 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical class CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
229910001593 boehmite Inorganic materials 0.000 description 1
KOPBYBDAPCDYFK-UHFFFAOYSA-N caesium oxide Chemical compound [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 1
229910001942 caesium oxide Inorganic materials 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
150000001734 carboxylic acid salts Chemical class 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
230000004927 fusion Effects 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
150000004694 iodide salts Chemical class 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
150000003893 lactate salts Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
150000003891 oxalate salts Chemical class 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
150000002926 oxygen Chemical class 0.000 description 1
229920006389 polyphenyl polymer Polymers 0.000 description 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
239000004323 potassium nitrate Substances 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000003134 recirculating effect Effects 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Inorganic materials [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 1
229910001952 rubidium oxide Inorganic materials 0.000 description 1
CWBWCLMMHLCMAM-UHFFFAOYSA-M rubidium(1+);hydroxide Chemical compound [OH-].[Rb+].[Rb+] CWBWCLMMHLCMAM-UHFFFAOYSA-M 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
150000003378 silver Chemical class 0.000 description 1
LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 description 1
229910001958 silver carbonate Inorganic materials 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
229910001923 silver oxide Inorganic materials 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
150000003892 tartrate salts Chemical class 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Catalysts (AREA)

CA000533855A 1987-04-03 1987-04-03 Methode de preparation d'un catalyseur a l'argent Expired - Fee Related CA1292974C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000533855A CA1292974C (fr)	1987-04-03	1987-04-03	Methode de preparation d'un catalyseur a l'argent

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000533855A CA1292974C (fr)	1987-04-03	1987-04-03	Methode de preparation d'un catalyseur a l'argent

Publications (1)

Publication Number	Publication Date
CA1292974C true CA1292974C (fr)	1991-12-10

Family

ID=4135364

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000533855A Expired - Fee Related CA1292974C (fr)	1987-04-03	1987-04-03	Methode de preparation d'un catalyseur a l'argent

Country Status (1)

Country	Link
CA (1)	CA1292974C (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN113694941A (zh) *	2020-05-20	2021-11-26	中国石油化工股份有限公司	一种负载型金属催化剂及其制备方法与应用
CN113713795A (zh) *	2020-05-25	2021-11-30	中国石油化工股份有限公司	一种复合氧化物载体及其制备方法

1987
- 1987-04-03 CA CA000533855A patent/CA1292974C/fr not_active Expired - Fee Related

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN113694941A (zh) *	2020-05-20	2021-11-26	中国石油化工股份有限公司	一种负载型金属催化剂及其制备方法与应用
CN113694941B (zh) *	2020-05-20	2024-05-07	中国石油化工股份有限公司	一种负载型金属催化剂及其制备方法与应用
CN113713795A (zh) *	2020-05-25	2021-11-30	中国石油化工股份有限公司	一种复合氧化物载体及其制备方法
CN113713795B (zh) *	2020-05-25	2024-05-07	中国石油化工股份有限公司	一种复合氧化物载体及其制备方法

Legal Events

Date	Code	Title	Description
2006-12-11	MKLA	Lapsed

Publication	Publication Date	Title
EP0243996B1 (fr)	1991-10-16	Procédé pour la préparation d'un catalyseur contenant de l'argent
US4806518A (en)	1989-02-21	Process for the preparation of a silver-containing ethylene oxide catalyst and the catalyst prepared by the process
EP0207550B1 (fr)	1990-09-19	Procédé de préparation d'un catalyseur contenant de l'argent
US4742034A (en)	1988-05-03	Silver ethylene oxide catalyst and process for preparation of the catalyst
EP0207542B1 (fr)	1989-05-24	Procédé de préparation d'un catalyseur contenant de l'argent
US4728634A (en)	1988-03-01	Ethylene oxide catalyst
CA1298270C (fr)	1992-03-31	Methode de preparation d'un catalyseur renfermant de l'argent
CA1292974C (fr)	1991-12-10	Methode de preparation d'un catalyseur a l'argent
CA1276619C (fr)	1990-11-20	Methode de preparation d'un catalyseur a l'argent