CA1293074C - Compositions de scellement termofusibles - Google Patents

Compositions de scellement termofusibles

Info

Publication number: CA1293074C
Authority: CA; Canada
Prior art keywords: blocks; composition; block; resin; weight
Prior art date: 1987-03-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000531823A

Other languages

English (en)

Inventor

Steven Soohyun Chin

Andrea Sanders

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Canada Ltd

Original Assignee

Shell Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-03-12

Filing date

1987-03-12

Publication date

1991-12-10

1987-03-12 Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd

1987-03-12 Priority to CA000531823A priority Critical patent/CA1293074C/fr

1991-12-10 Application granted granted Critical

1991-12-10 Publication of CA1293074C publication Critical patent/CA1293074C/fr

2008-12-10 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 87
239000000565 sealant Substances 0.000 title claims abstract description 65
239000012943 hotmelt Substances 0.000 title claims abstract description 32
239000011347 resin Substances 0.000 claims abstract description 56
229920005989 resin Polymers 0.000 claims abstract description 56
229920000642 polymer Polymers 0.000 claims abstract description 32
229920000359 diblock copolymer Polymers 0.000 claims abstract description 18
239000004793 Polystyrene Substances 0.000 claims abstract description 13
229920002223 polystyrene Polymers 0.000 claims abstract description 13
150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 8
229920001577 copolymer Polymers 0.000 claims abstract description 7
150000001993 dienes Chemical class 0.000 claims abstract description 7
229920006030 multiblock copolymer Polymers 0.000 claims abstract description 5
KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 claims abstract description 3
230000015572 biosynthetic process Effects 0.000 claims abstract description 3
238000000926 separation method Methods 0.000 claims abstract description 3
229920001400 block copolymer Polymers 0.000 claims description 72
239000004014 plasticizer Substances 0.000 claims description 11
239000000945 filler Substances 0.000 claims description 7
230000009477 glass transition Effects 0.000 claims description 4
239000000049 pigment Substances 0.000 claims description 4
239000005062 Polybutadiene Substances 0.000 claims description 3
239000003963 antioxidant agent Substances 0.000 claims description 3
229920002857 polybutadiene Polymers 0.000 claims description 3
229920001195 polyisoprene Polymers 0.000 claims description 3
229920005990 polystyrene resin Polymers 0.000 claims description 2
230000003078 antioxidant effect Effects 0.000 claims 1
229920002102 polyvinyl toluene Polymers 0.000 claims 1
239000000326 ultraviolet stabilizing agent Substances 0.000 claims 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract description 2
238000009472 formulation Methods 0.000 description 33
229920002633 Kraton (polymer) Polymers 0.000 description 27
239000011521 glass Substances 0.000 description 18
238000012360 testing method Methods 0.000 description 17
229920001971 elastomer Polymers 0.000 description 15
230000005540 biological transmission Effects 0.000 description 14
239000005060 rubber Substances 0.000 description 14
239000000758 substrate Substances 0.000 description 11
239000000853 adhesive Substances 0.000 description 10
230000001070 adhesive effect Effects 0.000 description 10
239000003381 stabilizer Substances 0.000 description 10
230000000694 effects Effects 0.000 description 9
239000004743 Polypropylene Substances 0.000 description 8
229920001155 polypropylene Polymers 0.000 description 8
229920006395 saturated elastomer Polymers 0.000 description 8
230000008901 benefit Effects 0.000 description 7
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
230000008878 coupling Effects 0.000 description 6
238000010168 coupling process Methods 0.000 description 6
238000005859 coupling reaction Methods 0.000 description 6
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 6
108700015862 A-B-A triblock copolymer Proteins 0.000 description 5
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 5
239000004411 aluminium Substances 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
229910052782 aluminium Inorganic materials 0.000 description 5
XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 5
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 5
239000004615 ingredient Substances 0.000 description 5
238000002156 mixing Methods 0.000 description 5
239000003921 oil Substances 0.000 description 5
-1 polybutylenes Polymers 0.000 description 5
239000002904 solvent Substances 0.000 description 5
239000002318 adhesion promoter Substances 0.000 description 4
239000003112 inhibitor Substances 0.000 description 4
229920000428 triblock copolymer Polymers 0.000 description 4
229910000831 Steel Inorganic materials 0.000 description 3
230000015556 catabolic process Effects 0.000 description 3
238000006731 degradation reaction Methods 0.000 description 3
239000003822 epoxy resin Substances 0.000 description 3
230000006872 improvement Effects 0.000 description 3
238000010128 melt processing Methods 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
229920000647 polyepoxide Polymers 0.000 description 3
229920006124 polyolefin elastomer Polymers 0.000 description 3
230000003014 reinforcing effect Effects 0.000 description 3
238000010058 rubber compounding Methods 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000010959 steel Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
239000013032 Hydrocarbon resin Substances 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
150000001491 aromatic compounds Chemical class 0.000 description 2
230000004888 barrier function Effects 0.000 description 2
239000006229 carbon black Substances 0.000 description 2
235000019241 carbon black Nutrition 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000007906 compression Methods 0.000 description 2
230000006835 compression Effects 0.000 description 2
238000001816 cooling Methods 0.000 description 2
239000007822 coupling agent Substances 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
229920006270 hydrocarbon resin Polymers 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
238000000034 method Methods 0.000 description 2
239000000178 monomer Substances 0.000 description 2
150000001282 organosilanes Chemical class 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
229920001568 phenolic resin Polymers 0.000 description 2
239000005011 phenolic resin Substances 0.000 description 2
150000003097 polyterpenes Polymers 0.000 description 2
239000000047 product Substances 0.000 description 2
230000002787 reinforcement Effects 0.000 description 2
150000003505 terpenes Chemical class 0.000 description 2
235000007586 terpenes Nutrition 0.000 description 2
230000009974 thixotropic effect Effects 0.000 description 2
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical class C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
RYUJRXVZSJCHDZ-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC(C)C)OC1=CC=CC=C1 RYUJRXVZSJCHDZ-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
241000338118 Dulus Species 0.000 description 1
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
229920002367 Polyisobutene Polymers 0.000 description 1
101001012040 Pseudomonas aeruginosa (strain ATCC 15692 / DSM 22644 / CIP 104116 / JCM 14847 / LMG 12228 / 1C / PRS 101 / PAO1) Immunomodulating metalloprotease Proteins 0.000 description 1
206010037660 Pyrexia Diseases 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
230000006750 UV protection Effects 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
239000012964 benzotriazole Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000010382 chemical cross-linking Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910052570 clay Inorganic materials 0.000 description 1
239000003245 coal Substances 0.000 description 1
238000013329 compounding Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000013020 final formulation Substances 0.000 description 1
229920006158 high molecular weight polymer Polymers 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
239000011256 inorganic filler Substances 0.000 description 1
229910003475 inorganic filler Inorganic materials 0.000 description 1
238000000281 laser microprobe mass spectrometry Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002924 oxiranes Chemical class 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
230000035515 penetration Effects 0.000 description 1
239000012466 permeate Substances 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
239000002530 phenolic antioxidant Substances 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920006389 polyphenyl polymer Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
238000010926 purge Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000004589 rubber sealant Substances 0.000 description 1
238000010008 shearing Methods 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
WIJVUKXVPNVPAQ-UHFFFAOYSA-N silyl 2-methylprop-2-enoate Chemical class CC(=C)C(=O)O[SiH3] WIJVUKXVPNVPAQ-UHFFFAOYSA-N 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
229920006132 styrene block copolymer Polymers 0.000 description 1
239000000126 substance Substances 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
239000011269 tar Substances 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
239000013008 thixotropic agent Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Landscapes

Adhesives Or Adhesive Processes (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA000531823A 1987-03-12 1987-03-12 Compositions de scellement termofusibles Expired - Fee Related CA1293074C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000531823A CA1293074C (fr)	1987-03-12	1987-03-12	Compositions de scellement termofusibles

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000531823A CA1293074C (fr)	1987-03-12	1987-03-12	Compositions de scellement termofusibles

Publications (1)

Publication Number	Publication Date
CA1293074C true CA1293074C (fr)	1991-12-10

Family

ID=4135160

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000531823A Expired - Fee Related CA1293074C (fr)	1987-03-12	1987-03-12	Compositions de scellement termofusibles

Country Status (1)

Country	Link
CA (1)	CA1293074C (fr)

1987
- 1987-03-12 CA CA000531823A patent/CA1293074C/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
2005-12-12	MKLA	Lapsed

Publication	Publication Date	Title
EP0238135B1 (fr)	1992-12-02	Composition d'étanchéité fusible
JP5468258B2 (ja)	2014-04-09	ホットメルトシーラントおよび発泡体代替ガスケット材料
JP3556224B2 (ja)	2004-08-18	接着剤用多ブロック水素化ポリマー
US5183705A (en)	1993-02-02	Pressure-sensitive adhesive composition having high shear strength
CN1139646C (zh)	2004-02-25	密封胶组合物
EP0001306B1 (fr)	1982-07-21	Composition adhésive fusible à chaud
US4101482A (en)	1978-07-18	Sealant based on mixture of unsaturated and hydrogenated block copolymers
US7470740B2 (en)	2008-12-30	Peelable hot melt adhesive
US7297741B2 (en)	2007-11-20	Pressure sensitive adhesives from high molecular weight block copolymers having a high fraction of diblock copolymer
CA2040113A1 (fr)	1991-10-12	Copolymere bloc styrene-isoprene-styrene pour adhesif thermofusible a faible viscosite et faible temperature d'application
GB1596428A (en)	1981-08-26	Hot melt adhesive composition as well as a process for preparing the same
US4138378A (en)	1979-02-06	Liquid polyalkene in thermoplastic elastomer sealant formulation
EP0322055B1 (fr)	1994-07-06	Composition d'enduit
CA1293074C (fr)	1991-12-10	Compositions de scellement termofusibles
CA1331412C (fr)	1994-08-09	Produit de scellement thermofusible, reticulable chimiquement
EP1584654B1 (fr)	2006-12-20	Produit d'étanchéité à base de caoutchouc butyl
USH1622H (en)	1996-12-03	Hydrogenated diblock copolymers for adhesives and sealants with improved resistance to degradation
US4248759A (en)	1981-02-03	Construction adhesive
JP2548559C (fr)	1999-02-10
US4180514A (en)	1979-12-25	Adhesion promoter and method of preparation
JPH05239400A (ja)	1993-09-17	車両下部コーティング組成物
JPH0284422A (ja)	1990-03-26	液状重合体組成物
JP2854893B2 (ja)	1999-02-10	架橋可能なホットメルトシーラント
Gun	2013	Wilmington, Delaware 19894