CA1293905C - Composition detergente liquide, non ionique et non aqueuse pour lessive, contenant un agent stabilisateur a base de compose d'ammonium quaternaire - Google Patents

Composition detergente liquide, non ionique et non aqueuse pour lessive, contenant un agent stabilisateur a base de compose d'ammonium quaternaire

Info

Publication number: CA1293905C
Authority: CA; Canada
Prior art keywords: weight; quaternary ammonium; salt; composition; agent
Prior art date: 1985-08-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000516238A

Other languages

English (en)

Inventor

Guy Broze

Danielle Bastin-Coia

Leo Laitem

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Colgate Palmolive Co

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-08-20

Filing date

1986-08-19

Publication date

1992-01-07

1986-08-19 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1992-01-07 Application granted granted Critical

1992-01-07 Publication of CA1293905C publication Critical patent/CA1293905C/fr

2009-01-07 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 167
239000003599 detergent Substances 0.000 title claims abstract description 107
239000007788 liquid Substances 0.000 title claims abstract description 83
239000003381 stabilizer Substances 0.000 title claims abstract description 47
238000000034 method Methods 0.000 title claims abstract description 8
125000001453 quaternary ammonium group Chemical group 0.000 title description 14
239000002736 nonionic surfactant Substances 0.000 claims abstract description 69
150000003839 salts Chemical class 0.000 claims abstract description 55
-1 cationic quaternary ammonium salt Chemical class 0.000 claims description 101
239000003795 chemical substances by application Substances 0.000 claims description 65
125000000217 alkyl group Chemical group 0.000 claims description 63
125000004432 carbon atom Chemical group C* 0.000 claims description 47
239000002245 particle Substances 0.000 claims description 40
150000003242 quaternary ammonium salts Chemical class 0.000 claims description 34
239000007844 bleaching agent Substances 0.000 claims description 33
229910019142 PO4 Inorganic materials 0.000 claims description 25
239000010452 phosphate Substances 0.000 claims description 24
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical class [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 19
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
239000012190 activator Substances 0.000 claims description 18
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 17
235000014113 dietary fatty acids Nutrition 0.000 claims description 17
239000000194 fatty acid Substances 0.000 claims description 17
229930195729 fatty acid Natural products 0.000 claims description 17
150000002148 esters Chemical class 0.000 claims description 16
102000004190 Enzymes Human genes 0.000 claims description 15
108090000790 Enzymes Proteins 0.000 claims description 15
150000004665 fatty acids Chemical class 0.000 claims description 15
150000001450 anions Chemical class 0.000 claims description 14
239000004744 fabric Substances 0.000 claims description 14
230000002401 inhibitory effect Effects 0.000 claims description 13
125000002091 cationic group Chemical group 0.000 claims description 12
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 12
239000003352 sequestering agent Substances 0.000 claims description 12
230000003287 optical effect Effects 0.000 claims description 11
125000002947 alkylene group Chemical group 0.000 claims description 10
239000002304 perfume Substances 0.000 claims description 10
229910052783 alkali metal Inorganic materials 0.000 claims description 9
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 9
238000004140 cleaning Methods 0.000 claims description 9
239000002202 Polyethylene glycol Substances 0.000 claims description 6
239000002518 antifoaming agent Substances 0.000 claims description 6
239000003112 inhibitor Substances 0.000 claims description 6
229910021645 metal ion Inorganic materials 0.000 claims description 6
229920001223 polyethylene glycol Polymers 0.000 claims description 6
239000002532 enzyme inhibitor Substances 0.000 claims description 5
239000002671 adjuvant Substances 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 4
229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 4
REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical group [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 4
JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical group O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 4
239000006174 pH buffer Substances 0.000 claims description 4
238000004383 yellowing Methods 0.000 claims description 4
230000007797 corrosion Effects 0.000 claims description 3
238000005260 corrosion Methods 0.000 claims description 3
239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 claims description 3
239000003002 pH adjusting agent Substances 0.000 claims description 3
229920000388 Polyphosphate Polymers 0.000 claims description 2
238000009826 distribution Methods 0.000 claims description 2
125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims description 2
239000001205 polyphosphate Substances 0.000 claims description 2
235000011176 polyphosphates Nutrition 0.000 claims description 2
229910052816 inorganic phosphate Inorganic materials 0.000 claims 2
239000012459 cleaning agent Substances 0.000 claims 1
239000004094 surface-active agent Substances 0.000 abstract description 29
239000000725 suspension Substances 0.000 abstract description 18
229920003023 plastic Polymers 0.000 abstract description 8
239000004033 plastic Substances 0.000 abstract description 8
150000003863 ammonium salts Chemical group 0.000 abstract description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 38
150000001875 compounds Chemical class 0.000 description 37
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 30
239000002253 acid Substances 0.000 description 30
235000021317 phosphate Nutrition 0.000 description 24
239000000047 product Substances 0.000 description 24
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 23
238000009472 formulation Methods 0.000 description 17
239000007787 solid Substances 0.000 description 16
238000000227 grinding Methods 0.000 description 15
150000002191 fatty alcohols Chemical class 0.000 description 14
235000019832 sodium triphosphate Nutrition 0.000 description 14
238000003860 storage Methods 0.000 description 14
238000007792 addition Methods 0.000 description 13
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
239000003760 tallow Substances 0.000 description 12
239000000654 additive Substances 0.000 description 11
235000019270 ammonium chloride Nutrition 0.000 description 11
229940088598 enzyme Drugs 0.000 description 11
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
230000002378 acidificating effect Effects 0.000 description 10
239000011734 sodium Substances 0.000 description 10
229910052708 sodium Inorganic materials 0.000 description 10
238000005406 washing Methods 0.000 description 10
229940014800 succinic anhydride Drugs 0.000 description 9
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 9
FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 8
125000000129 anionic group Chemical group 0.000 description 8
125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
239000004615 ingredient Substances 0.000 description 8
239000000463 material Substances 0.000 description 8
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 8
235000021286 stilbenes Nutrition 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical class CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
229920002125 Sokalan® Polymers 0.000 description 7
235000019441 ethanol Nutrition 0.000 description 7
230000006872 improvement Effects 0.000 description 7
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 6
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
235000012216 bentonite Nutrition 0.000 description 6
230000036961 partial effect Effects 0.000 description 6
230000000087 stabilizing effect Effects 0.000 description 6
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 6
ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 description 5
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 5
125000003545 alkoxy group Chemical group 0.000 description 5
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
239000001768 carboxy methyl cellulose Substances 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
230000007423 decrease Effects 0.000 description 5
239000000975 dye Substances 0.000 description 5
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
239000011591 potassium Substances 0.000 description 5
229910052700 potassium Inorganic materials 0.000 description 5
150000003856 quaternary ammonium compounds Chemical class 0.000 description 5
229920006395 saturated elastomer Polymers 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 5
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 5
239000000243 solution Substances 0.000 description 5
SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
229910002651 NO3 Inorganic materials 0.000 description 4
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
108091005804 Peptidases Proteins 0.000 description 4
229920002257 Plurafac® Polymers 0.000 description 4
239000004365 Protease Substances 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
150000008064 anhydrides Chemical class 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
239000006185 dispersion Substances 0.000 description 4
229960001484 edetic acid Drugs 0.000 description 4
238000007046 ethoxylation reaction Methods 0.000 description 4
238000001879 gelation Methods 0.000 description 4
150000004820 halides Chemical class 0.000 description 4
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
238000002156 mixing Methods 0.000 description 4
150000002903 organophosphorus compounds Chemical class 0.000 description 4
150000004965 peroxy acids Chemical class 0.000 description 4
150000003254 radicals Chemical class 0.000 description 4
239000000126 substance Substances 0.000 description 4
239000010457 zeolite Substances 0.000 description 4
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 3
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 3
239000000440 bentonite Substances 0.000 description 3
229910000278 bentonite Inorganic materials 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
239000011575 calcium Substances 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
150000007942 carboxylates Chemical class 0.000 description 3
150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
230000002209 hydrophobic effect Effects 0.000 description 3
TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 3
108010003855 mesentericopeptidase Proteins 0.000 description 3
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
150000002978 peroxides Chemical class 0.000 description 3
238000005191 phase separation Methods 0.000 description 3
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
235000019419 proteases Nutrition 0.000 description 3
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
150000004760 silicates Chemical class 0.000 description 3
229910018626 Al(OH) Inorganic materials 0.000 description 2
239000004382 Amylase Substances 0.000 description 2
102000013142 Amylases Human genes 0.000 description 2
108010065511 Amylases Proteins 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
229940120146 EDTMP Drugs 0.000 description 2
235000010469 Glycine max Nutrition 0.000 description 2
244000068988 Glycine max Species 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
229930182556 Polyacetal Natural products 0.000 description 2
239000004721 Polyphenylene oxide Substances 0.000 description 2
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
235000021355 Stearic acid Nutrition 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910052910 alkali metal silicate Inorganic materials 0.000 description 2
150000005215 alkyl ethers Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 2
229940063655 aluminum stearate Drugs 0.000 description 2
235000019418 amylase Nutrition 0.000 description 2
239000003945 anionic surfactant Substances 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
150000001721 carbon Chemical group 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
239000003093 cationic surfactant Substances 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
239000007859 condensation product Substances 0.000 description 2
230000001276 controlling effect Effects 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000032050 esterification Effects 0.000 description 2
238000005886 esterification reaction Methods 0.000 description 2
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
239000010419 fine particle Substances 0.000 description 2
229940051250 hexylene glycol Drugs 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
150000002443 hydroxylamines Chemical class 0.000 description 2
229920003063 hydroxymethyl cellulose Polymers 0.000 description 2
229940031574 hydroxymethyl cellulose Drugs 0.000 description 2
230000005764 inhibitory process Effects 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000010412 laundry washing Methods 0.000 description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
229910052901 montmorillonite Inorganic materials 0.000 description 2
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
238000005457 optimization Methods 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
229960003330 pentetic acid Drugs 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
239000000049 pigment Substances 0.000 description 2
229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
229920000570 polyether Polymers 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
229920006324 polyoxymethylene Polymers 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000002829 reductive effect Effects 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000002002 slurry Substances 0.000 description 2
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
230000003381 solubilizing effect Effects 0.000 description 2
239000008117 stearic acid Substances 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
150000003457 sulfones Chemical class 0.000 description 2
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
239000002562 thickening agent Substances 0.000 description 2
150000003852 triazoles Chemical class 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
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235000007686 potassium Nutrition 0.000 description 1
229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
239000011736 potassium bicarbonate Substances 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
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IFIDXBCRSWOUSB-UHFFFAOYSA-M potassium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate Chemical compound [K+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-M 0.000 description 1
GHTWQCXOBQMUHR-UHFFFAOYSA-M potassium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [K+].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC([O-])=O GHTWQCXOBQMUHR-UHFFFAOYSA-M 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
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230000001105 regulatory effect Effects 0.000 description 1
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235000015424 sodium Nutrition 0.000 description 1
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FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
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HELHAJAZNSDZJO-UHFFFAOYSA-L sodium tartrate Chemical class [Na+].[Na+].[O-]C(=O)C(O)C(O)C([O-])=O HELHAJAZNSDZJO-UHFFFAOYSA-L 0.000 description 1
ODBPOHVSVJZQRX-UHFFFAOYSA-M sodium;[2-[2-[bis(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]methyl-hydroxyphosphinate Chemical compound [Na+].OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)([O-])=O ODBPOHVSVJZQRX-UHFFFAOYSA-M 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000012265 solid product Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
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BDOBMVIEWHZYDL-UHFFFAOYSA-N tetrachlorosalicylanilide Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC=C1 BDOBMVIEWHZYDL-UHFFFAOYSA-N 0.000 description 1
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235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000004753 textile Substances 0.000 description 1
230000008719 thickening Effects 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical class OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
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238000009736 wetting Methods 0.000 description 1

Landscapes

Detergent Compositions (AREA)

CA000516238A 1985-08-20 1986-08-19 Composition detergente liquide, non ionique et non aqueuse pour lessive, contenant un agent stabilisateur a base de compose d'ammonium quaternaire Expired - Lifetime CA1293905C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US76756885A	1985-08-20	1985-08-20
US767,568		1985-08-20

Publications (1)

Publication Number	Publication Date
CA1293905C true CA1293905C (fr)	1992-01-07

Family

ID=25079879

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000516238A Expired - Lifetime CA1293905C (fr)	1985-08-20	1986-08-19	Composition detergente liquide, non ionique et non aqueuse pour lessive, contenant un agent stabilisateur a base de compose d'ammonium quaternaire

Country Status (6)

Country	Link
JP (1)	JPS6270500A (fr)
CA (1)	CA1293905C (fr)
PH (1)	PH24181A (fr)
TR (1)	TR27070A (fr)
ZA (1)	ZA865751B (fr)
ZM (1)	ZM6986A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US11046915B2 (en)	2018-12-21	2021-06-29	Henkel IP & Holding GmbH	Use of polyglycols to control rheology of unit dose detergent compositions
US11118141B2 (en)	2018-12-21	2021-09-14	Henkel IP & Holding GmbH	Use of alkoxylated polyamines to control rheology of unit dose detergent compositions
US11242499B2 (en)	2019-08-21	2022-02-08	Henkel IP & Holding GmbH	Use of glycol ethers and alkyl alcohol blends to control surfactant composition rheology
US11306279B2 (en)	2019-08-21	2022-04-19	Henkel Ag & Co. Kgaa	Use of glycol ether to control rheology of unit dose detergent pack
US11414625B2 (en)	2019-12-07	2022-08-16	Henkel Ag & Co. Kgaa	Use of tertiary amines and alkyl alcohol blends to control surfactant composition rheology
US11629313B2 (en)	2019-12-07	2023-04-18	Henkel Ag & Co. Kgaa	Use of tertiary amine to control rheology of unit dose detergent pack
US11773261B2 (en)	2019-08-21	2023-10-03	Henkel Ag & Co. Kgaa	Use of poloxamers and alkyl alcohol blends to control surfactant composition rheology
CN117776932A (zh) *	2023-12-22	2024-03-29	烟台先进材料与绿色制造山东省实验室	一种离子液体型多功能清净剂及其制备方法和应用
US12084633B2 (en)	2020-12-15	2024-09-10	Henkel Ag & Co. Kgaa	Unit dose laundry detergent compositions containing soil release polymers

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ZA974226B (en) *	1996-05-17	1998-12-28	Procter & Gamble	Detergent composition
JP7004537B2 (ja) *	2016-09-30	2022-01-21	ライオン株式会社	粒子分散洗浄剤組成物

1986
- 1986-07-31 ZA ZA865751A patent/ZA865751B/xx unknown
- 1986-08-06 ZM ZM6986A patent/ZM6986A1/xx unknown
- 1986-08-12 PH PH34124A patent/PH24181A/en unknown
- 1986-08-19 CA CA000516238A patent/CA1293905C/fr not_active Expired - Lifetime
- 1986-08-20 TR TR45386A patent/TR27070A/xx unknown
- 1986-08-20 JP JP61195128A patent/JPS6270500A/ja active Pending

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US11046915B2 (en)	2018-12-21	2021-06-29	Henkel IP & Holding GmbH	Use of polyglycols to control rheology of unit dose detergent compositions
US11118141B2 (en)	2018-12-21	2021-09-14	Henkel IP & Holding GmbH	Use of alkoxylated polyamines to control rheology of unit dose detergent compositions
US11242499B2 (en)	2019-08-21	2022-02-08	Henkel IP & Holding GmbH	Use of glycol ethers and alkyl alcohol blends to control surfactant composition rheology
US11306279B2 (en)	2019-08-21	2022-04-19	Henkel Ag & Co. Kgaa	Use of glycol ether to control rheology of unit dose detergent pack
US11773261B2 (en)	2019-08-21	2023-10-03	Henkel Ag & Co. Kgaa	Use of poloxamers and alkyl alcohol blends to control surfactant composition rheology
US11414625B2 (en)	2019-12-07	2022-08-16	Henkel Ag & Co. Kgaa	Use of tertiary amines and alkyl alcohol blends to control surfactant composition rheology
US11629313B2 (en)	2019-12-07	2023-04-18	Henkel Ag & Co. Kgaa	Use of tertiary amine to control rheology of unit dose detergent pack
US12084633B2 (en)	2020-12-15	2024-09-10	Henkel Ag & Co. Kgaa	Unit dose laundry detergent compositions containing soil release polymers
CN117776932A (zh) *	2023-12-22	2024-03-29	烟台先进材料与绿色制造山东省实验室	一种离子液体型多功能清净剂及其制备方法和应用

Also Published As

Publication number	Publication date
PH24181A (en)	1990-03-22
JPS6270500A (ja)	1987-03-31
ZA865751B (en)	1988-03-30
TR27070A (tr)	1994-10-12
ZM6986A1 (en)	1988-04-29

Legal Events

Date	Code	Title	Description
1999-01-07	MKLA	Lapsed

Publication	Publication Date	Title
AU592812B2 (en)	1990-01-25	Built detergent compositions containing stabilizing agents
US4806260A (en)	1989-02-21	Built nonaqueous liquid nonionic laundry detergent composition containing acid terminated nonionic surfactant and quarternary ammonium softener and method of use
US4830782A (en)	1989-05-16	Hot water wash cycle built nonaqueous liquid nonionic laundry detergent composition containing amphoteric surfactant and method of use
US4661280A (en)	1987-04-28	Built liquid laundry detergent composition containing salt of higher fatty acid stabilizer and method of use
US4769168A (en)	1988-09-06	Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent composition and method of use
CA1283016C (fr)	1991-04-16	Melange liquide de detergent pour le blanchiment et methode d'utilisation
AU598017B2 (en)	1990-06-14	Liquid nonionic laundry detergent composition and method of use
US4648983A (en)	1987-03-10	Built non aqueous liquid nonionic laundry detergent composition containing urea stabilizer and method of use
CA1305006C (fr)	1992-07-14	Compositions detergentes liquides non-aqueuses, pour la lessive
US4767558A (en)	1988-08-30	Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent composition and method of use
US4690771A (en)	1987-09-01	Phosphate free nonaqueous liquid nonionic laundry detergent composition and method of use
US4839084A (en)	1989-06-13	Built liquid laundry detergent composition containing an alkaline earth metal or zinc salt of higher fatty acid liquefying agent and method of use
US4891148A (en)	1990-01-02	Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent comopsition and method of use
US4789496A (en)	1988-12-06	Built nonaqueous liquid nonionic laundry detergent composition containing
AU599017B2 (en)	1990-07-12	Liquid laundry detergent-bleach composition and method of use
GB2194536A (en)	1988-03-09	Polyether surfactants used in nonaqueous liquid nonionic laundry detergent compositions
US4873012A (en)	1989-10-10	Built nonaqueous liquid nonioinic laundry detergent composition containing hexylene glycol and method of use
US4647393A (en)	1987-03-03	Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent composition and method of use
AU602362B2 (en)	1990-10-11	Built nonaqueous liquid nonionic laundry detergent composition containing hexylene glycol and method of use
GB2194955A (en)	1988-03-23	High foam nonaqueous liquid nonionic laundry detergent composition
GB2208653A (en)	1989-04-12	Phosphate free or low phosphate laundry detergent
US4781856A (en)	1988-11-01	Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent composition and method of use
CA1291691C (fr)	1991-11-05	Composition detersive liquide non-aqueuse et non-ionique sans phosphate, et son mode d'emploi pour la lessive
NZ219396A (en)	1990-11-27	Complex of ammonium softener and acid-terminated nonionic surfactant in fabric-treating compositions
NZ222281A (en)	1990-11-27	Detergent compositions containing hexylene glycol

CA1293905C - Composition detergente liquide, non ionique et non aqueuse pour lessive, contenant un agent stabilisateur a base de compose d'ammonium quaternaire - Google Patents

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Publications (1)

Family

ID=25079879

Family Applications (1)

Country Status (6)

Cited By (9)

Families Citing this family (2)

Cited By (9)

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