CA1295529C - Controle de la corrosion dans des systemes aqueux - Google Patents

Controle de la corrosion dans des systemes aqueux

Info

Publication number: CA1295529C
Authority: CA; Canada
Prior art keywords: boiler; scavenger; added; oxygen; phloroglucinol
Prior art date: 1986-04-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000535662A

Other languages

English (en)

Inventor

Dionisio G. Cuisia

John W. Rudolph

Murrell L. Salutsky

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co

Original Assignee

WR Grace and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-04-28

Filing date

1987-04-27

Publication date

1992-02-11

1987-04-27 Application filed by WR Grace and Co filed Critical WR Grace and Co

1992-02-11 Application granted granted Critical

1992-02-11 Publication of CA1295529C publication Critical patent/CA1295529C/fr

2009-02-11 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000005260 corrosion Methods 0.000 title claims abstract description 25
230000007797 corrosion Effects 0.000 title claims abstract description 24
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
229960001553 phloroglucinol Drugs 0.000 claims abstract description 38
JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 claims abstract description 37
QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 claims abstract description 34
229940123973 Oxygen scavenger Drugs 0.000 claims abstract description 16
239000007864 aqueous solution Substances 0.000 claims abstract description 13
229910052751 metal Inorganic materials 0.000 claims abstract description 13
239000002184 metal Substances 0.000 claims abstract description 13
150000003839 salts Chemical class 0.000 claims abstract description 7
150000002739 metals Chemical class 0.000 claims abstract description 6
125000000217 alkyl group Chemical group 0.000 claims abstract description 4
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
239000001257 hydrogen Substances 0.000 claims abstract description 4
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 40
229910052760 oxygen Inorganic materials 0.000 claims description 40
239000001301 oxygen Substances 0.000 claims description 40
238000000034 method Methods 0.000 claims description 29
239000002516 radical scavenger Substances 0.000 claims description 17
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
229910000831 Steel Inorganic materials 0.000 claims description 7
239000010959 steel Substances 0.000 claims description 7
238000005273 aeration Methods 0.000 claims description 5
229910052742 iron Inorganic materials 0.000 claims description 5
125000002444 phloroglucinyl group Chemical group [H]OC1=C([H])C(O[H])=C(*)C(O[H])=C1[H] 0.000 claims 4
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 29
150000001875 compounds Chemical class 0.000 description 20
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 16
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 10
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
-1 aryl amine compounds Chemical class 0.000 description 8
AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 8
239000000243 solution Substances 0.000 description 8
150000004053 quinones Chemical class 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 6
230000002000 scavenging effect Effects 0.000 description 6
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 6
239000003054 catalyst Substances 0.000 description 5
229940079877 pyrogallol Drugs 0.000 description 5
239000000654 additive Substances 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000003112 inhibitor Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
239000012736 aqueous medium Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000003638 chemical reducing agent Substances 0.000 description 3
150000002443 hydroxylamines Chemical class 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
235000010265 sodium sulphite Nutrition 0.000 description 3
239000000126 substance Substances 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
150000001413 amino acids Chemical class 0.000 description 2
150000004056 anthraquinones Chemical class 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
150000001555 benzenes Chemical class 0.000 description 2
AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 2
RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 2
239000003814 drug Substances 0.000 description 2
239000000975 dye Substances 0.000 description 2
239000012527 feed solution Substances 0.000 description 2
150000008282 halocarbons Chemical class 0.000 description 2
150000005204 hydroxybenzenes Chemical class 0.000 description 2
230000002401 inhibitory effect Effects 0.000 description 2
230000005764 inhibitory process Effects 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
239000002904 solvent Substances 0.000 description 2
CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
DBCKMJVEAUXWJJ-UHFFFAOYSA-N 2,3-dichlorobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Cl)=C1Cl DBCKMJVEAUXWJJ-UHFFFAOYSA-N 0.000 description 1
CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229930192627 Naphthoquinone Natural products 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
239000012190 activator Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
UIFJOXOHICDFDO-UHFFFAOYSA-N benzene-1,3,5-triol Chemical compound OC1=CC(O)=CC(O)=C1.OC1=CC(O)=CC(O)=C1 UIFJOXOHICDFDO-UHFFFAOYSA-N 0.000 description 1
ZYGHJZDHTFUPRJ-UHFFFAOYSA-N benzo-alpha-pyrone Natural products C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
235000010216 calcium carbonate Nutrition 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003224 coccidiostatic agent Substances 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
235000001671 coumarin Nutrition 0.000 description 1
150000004775 coumarins Chemical class 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
239000003989 dielectric material Substances 0.000 description 1
229940120503 dihydroxyacetone Drugs 0.000 description 1
150000005205 dihydroxybenzenes Chemical class 0.000 description 1
238000007599 discharging Methods 0.000 description 1
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
229910000397 disodium phosphate Inorganic materials 0.000 description 1
235000019800 disodium phosphate Nutrition 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
239000003925 fat Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
150000002429 hydrazines Chemical class 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical group 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000002790 naphthalenes Chemical class 0.000 description 1
150000002791 naphthoquinones Chemical class 0.000 description 1
239000003921 oil Substances 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
238000005554 pickling Methods 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
230000003134 recirculating effect Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000000523 sample Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/12—Oxygen-containing compounds
- C23F11/122—Alcohols; Aldehydes; Ketones

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Life Sciences & Earth Sciences (AREA)
Hydrology & Water Resources (AREA)
Environmental & Geological Engineering (AREA)
Water Supply & Treatment (AREA)
Preventing Corrosion Or Incrustation Of Metals (AREA)

CA000535662A 1986-04-28 1987-04-27 Controle de la corrosion dans des systemes aqueux Expired - Lifetime CA1295529C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US85656086A	1986-04-28	1986-04-28
US856,560		1986-04-28

Publications (1)

Publication Number	Publication Date
CA1295529C true CA1295529C (fr)	1992-02-11

Family

ID=25323948

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000535662A Expired - Lifetime CA1295529C (fr)	1986-04-28	1987-04-27	Controle de la corrosion dans des systemes aqueux

Country Status (5)

Country	Link
JP (1)	JPS62260079A (fr)
AU (1)	AU7190487A (fr)
CA (1)	CA1295529C (fr)
GB (1)	GB2189781A (fr)
ZA (1)	ZA872662B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS61272392A (ja) *	1985-05-28	1986-12-02	Kurita Water Ind Ltd	緑青除去方法
US5512243A (en) *	1995-04-11	1996-04-30	Betz Laboratories, Inc.	Cyclohexanedione oxygen scavengers

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2522522A1 (fr) *	1982-01-27	1983-09-09	Leuna Werke Veb	Procede pour ameliorer l'activite initiale de l'hydrazine activee

1987
- 1987-04-14 ZA ZA872662A patent/ZA872662B/xx unknown
- 1987-04-23 AU AU71904/87A patent/AU7190487A/en not_active Abandoned
- 1987-04-25 JP JP62101167A patent/JPS62260079A/ja active Pending
- 1987-04-27 CA CA000535662A patent/CA1295529C/fr not_active Expired - Lifetime
- 1987-04-27 GB GB08709922A patent/GB2189781A/en not_active Withdrawn

Also Published As

Publication number	Publication date
JPS62260079A (ja)	1987-11-12
ZA872662B (en)	1987-10-02
GB8709922D0 (en)	1987-06-03
GB2189781A (en)	1987-11-04
AU7190487A (en)	1987-10-29

Legal Events

Date	Code	Title	Description
1995-08-12	MKLA	Lapsed

Publication	Publication Date	Title
EP0161822B1 (fr)	1990-02-07	Composition et procédé pour la désoxygénation des systèmes aqueux
US4269717A (en)	1981-05-26	Boiler additives for oxygen scavenging
US4278635A (en)	1981-07-14	Method for deoxygenation of water
US4487745A (en)	1984-12-11	Oximes as oxygen scavengers
US5244600A (en)	1993-09-14	Method of scavenging oxygen in aqueous systems
US4617129A (en)	1986-10-14	Scale inhibition
EP0216586B2 (fr)	1993-01-27	Erythorbate de sodium stabilisé et son utilisation comme inhibiteur de corrosion
US4895703A (en)	1990-01-23	Trihydroxybenzene boiler corrosion inhibitor compositions and method
US4980128A (en)	1990-12-25	Control of corrosion in aqueous systems
EP0297916B1 (fr)	1992-05-13	Contrôle de la corrosion dans des systèmes aqueux
EP0215655B1 (fr)	1990-01-10	Procédé d'inhibition de la corrosion de chaudières et compositions à cet effet
US20020100896A1 (en)	2002-08-01	Oxygen scavenger
EP0538969B1 (fr)	1998-05-27	Composition et procédé pour inhiber l'incrustation et la corrosion, utilisant des acides naphthylamine polycarboxyliques
FI97627B (fi)	1996-10-15	Koostumus ja menetelmä korroosion estämiseksi
CA1295529C (fr)	1992-02-11	Controle de la corrosion dans des systemes aqueux
US5135681A (en)	1992-08-04	Substituted carboxymethoxysuccinic acid corrosion inhibitors
CA1052086A (fr)	1979-04-10	Traitement de l'eau de chaudiere
US4512909A (en)	1985-04-23	Use of a hydroquinone compound with hydrazine (1:1 molar ratio) as an oxygen-scavenging and a corrosion-inhibiting agent
US3096147A (en)	1963-07-02	Process for inhibiting corrosion in acid solutions with guanamine-propylene oxide condensation product
US5073339A (en)	1991-12-17	Method of inhibiting corrosion and scale formation in aqueous systems
KR20190067015A (ko)	2019-06-14	카보히드라지드를 포함하는 발전소 보일러 계통의 수처리 색조용 조성물
EP0565371A2 (fr)	1993-10-13	Tampon double pour chaudières