CA1299135C - Procede electrolytique de mise en couleur de l'aluminium - Google Patents

Procede electrolytique de mise en couleur de l'aluminium

Info

Publication number: CA1299135C
Authority: CA; Canada
Prior art keywords: aluminum material; material substrate; substrate according; nickel; electrolytically coloring
Prior art date: 1984-12-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000528589A

Other languages

English (en)

Inventor

Tahei Asada

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ASEDA TAHEI

Sebun Shiizu KK

Corona Enterprises Inc

Original Assignee

ASEDA TAHEI

Sebun Shiizu KK

Corona Enterprises Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-12-17

Filing date

1987-01-30

Publication date

1992-04-21

1984-12-17 Priority claimed from JP59264494A external-priority patent/JPS61143593A/ja

1987-01-30 Application filed by ASEDA TAHEI, Sebun Shiizu KK, Corona Enterprises Inc filed Critical ASEDA TAHEI

1987-01-30 Priority to CA000528589A priority Critical patent/CA1299135C/fr

1992-04-21 Application granted granted Critical

1992-04-21 Publication of CA1299135C publication Critical patent/CA1299135C/fr

2009-04-21 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229910052782 aluminium Inorganic materials 0.000 title claims abstract description 84
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 83
239000000463 material Substances 0.000 title claims abstract description 70
238000004040 coloring Methods 0.000 title claims abstract description 53
238000000034 method Methods 0.000 title claims abstract description 51
230000008569 process Effects 0.000 title claims abstract description 50
239000011248 coating agent Substances 0.000 claims abstract description 21
238000000576 coating method Methods 0.000 claims abstract description 21
150000002815 nickel Chemical class 0.000 claims abstract description 19
150000003751 zinc Chemical class 0.000 claims abstract description 14
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims abstract description 13
229910001453 nickel ion Inorganic materials 0.000 claims abstract description 13
239000003153 chemical reaction reagent Substances 0.000 claims abstract description 10
239000000758 substrate Substances 0.000 claims description 34
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 18
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
238000005868 electrolysis reaction Methods 0.000 claims description 9
229910052943 magnesium sulfate Inorganic materials 0.000 claims description 9
235000019341 magnesium sulphate Nutrition 0.000 claims description 9
229910052759 nickel Inorganic materials 0.000 claims description 9
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 8
229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 8
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 8
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 8
229910000368 zinc sulfate Inorganic materials 0.000 claims description 8
229960001763 zinc sulfate Drugs 0.000 claims description 8
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 7
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 claims description 4
SDGNNLQZAPXALR-UHFFFAOYSA-N 3-sulfophthalic acid Chemical compound OC(=O)C1=CC=CC(S(O)(=O)=O)=C1C(O)=O SDGNNLQZAPXALR-UHFFFAOYSA-N 0.000 claims description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 4
238000007743 anodising Methods 0.000 claims description 4
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
239000004327 boric acid Substances 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
239000000174 gluconic acid Substances 0.000 claims description 4
235000012208 gluconic acid Nutrition 0.000 claims description 4
KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 claims description 4
150000003839 salts Chemical class 0.000 claims description 4
235000005074 zinc chloride Nutrition 0.000 claims description 4
239000011592 zinc chloride Substances 0.000 claims description 4
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical group [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 3
235000018660 ammonium molybdate Nutrition 0.000 claims description 3
239000011609 ammonium molybdate Substances 0.000 claims description 3
229940010552 ammonium molybdate Drugs 0.000 claims description 3
DAPUDVOJPZKTSI-UHFFFAOYSA-L ammonium nickel sulfate Chemical compound [NH4+].[NH4+].[Ni+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DAPUDVOJPZKTSI-UHFFFAOYSA-L 0.000 claims description 3
238000013329 compounding Methods 0.000 claims description 3
230000009977 dual effect Effects 0.000 claims description 3
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical class [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 3
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 3
239000011975 tartaric acid Substances 0.000 claims description 3
235000002906 tartaric acid Nutrition 0.000 claims description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 6
239000003086 colorant Substances 0.000 abstract description 5
239000003115 supporting electrolyte Substances 0.000 abstract description 3
235000010210 aluminium Nutrition 0.000 description 47
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
238000005260 corrosion Methods 0.000 description 8
230000007797 corrosion Effects 0.000 description 8
230000008021 deposition Effects 0.000 description 7
229960003390 magnesium sulfate Drugs 0.000 description 7
229910052725 zinc Inorganic materials 0.000 description 6
239000011701 zinc Substances 0.000 description 6
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
239000000470 constituent Substances 0.000 description 5
238000007796 conventional method Methods 0.000 description 5
239000011148 porous material Substances 0.000 description 5
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
229910052921 ammonium sulfate Inorganic materials 0.000 description 4
235000011130 ammonium sulphate Nutrition 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
-1 citric aci.d Chemical compound 0.000 description 3
KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
238000005299 abrasion Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
229910000765 intermetallic Inorganic materials 0.000 description 2
208000014451 palmoplantar keratoderma and congenital alopecia 2 Diseases 0.000 description 2
238000007747 plating Methods 0.000 description 2
229910000838 Al alloy Inorganic materials 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
229910000906 Bronze Inorganic materials 0.000 description 1
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical group [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
229910052728 basic metal Inorganic materials 0.000 description 1
150000003818 basic metals Chemical class 0.000 description 1
235000013405 beer Nutrition 0.000 description 1
239000010974 bronze Substances 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000010276 construction Methods 0.000 description 1
230000005518 electrochemistry Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
FYYHWMGAXLPEAU-OUBTZVSYSA-N magnesium-25 atom Chemical compound [25Mg] FYYHWMGAXLPEAU-OUBTZVSYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
150000002739 metals Chemical group 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1

Landscapes

Electroplating And Plating Baths Therefor (AREA)

CA000528589A 1984-12-17 1987-01-30 Procede electrolytique de mise en couleur de l'aluminium Expired - Fee Related CA1299135C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000528589A CA1299135C (fr)	1984-12-17	1987-01-30	Procede electrolytique de mise en couleur de l'aluminium

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP59264494A JPS61143593A (ja)	1984-12-17	1984-12-17	アルミニウム材の電解着色法
CA000528589A CA1299135C (fr)	1984-12-17	1987-01-30	Procede electrolytique de mise en couleur de l'aluminium

Publications (1)

Publication Number	Publication Date
CA1299135C true CA1299135C (fr)	1992-04-21

Family

ID=25671221

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000528589A Expired - Fee Related CA1299135C (fr)	1984-12-17	1987-01-30	Procede electrolytique de mise en couleur de l'aluminium

Country Status (1)

Country	Link
CA (1)	CA1299135C (fr)

1987
- 1987-01-30 CA CA000528589A patent/CA1299135C/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1995-10-22	MKLA	Lapsed

Publication	Publication Date	Title
US4021315A (en)	1977-05-03	Process for electrolytic coloring of the anodic oxide film on aluminum or aluminum base alloys
CA1076988A (fr)	1980-05-06	Electrodeposition de metaux sous haute densite de courant
CA2028107A1 (fr)	1990-11-17	Procede de traitement superficiel de l'aluminium ou d'un alliage d'aluminium
US4470897A (en)	1984-09-11	Method of electroplating a corrosion-resistant zinc-containing deposit
Sheasby et al.	1974	The electrolytic colouring of anodized aluminium
CA1129805A (fr)	1982-08-17	Electrodeposition a l'alliage de ruthenium et d'iridium
US3795590A (en)	1974-03-05	Process for coloring aluminum and alloys of aluminum having an anodized surface
US4806226A (en)	1989-02-21	Process for electrolytically coloring aluminum material
US4299671A (en)	1981-11-10	Bath composition and method for electrodepositing cobalt-zinc alloys simulating a chromium plating
CA1299135C (fr)	1992-04-21	Procede electrolytique de mise en couleur de l'aluminium
GB2116588A (en)	1983-09-28	Electroplated zinc-cobalt alloy
JPS6141998B2 (fr)	1986-09-18
US4591416A (en)	1986-05-27	Chromate composition and process for treating zinc-nickel alloys
US2355505A (en)	1944-08-08	Electrodeposition of bright zinc
US20030178314A1 (en)	2003-09-25	Stainless steel electrolytic coating
EP0121361B1 (fr)	1987-06-16	Procédé de coloration pour produits d'aluminium anodisé
EP0843027B1 (fr)	2001-08-08	Procédé de coloration électrolytique de matériau en aluminium
US4138294A (en)	1979-02-06	Acid zinc electroplating process and composition
US2307551A (en)	1943-01-05	Method of producing a white, platinumlike color chromium plate and the product thereof and bath therefor
JPS604920B2 (ja)	1985-02-07	耐摩耗性良好な黒色ロジウムメッキ被覆物品の製造方法
EP0229665B1 (fr)	1990-11-22	Produit brillant de teinte dorée et son procédé de fabrication
RU2377344C1 (ru)	2009-12-27	Электролит и способ нанесения покрытия сплавом олово-кобальт
US3658665A (en)	1972-04-25	Electrolytic method for producing a colored anodized layer on aluminum and alloys of aluminum
Krishnan et al.	1991	Electrodeposition of Zinc From a Noncyanide Alkaline Bath
CA1193572A (fr)	1985-09-17	Methode de deposition d'un enduit anodique teinte sur des articles en alliage d'aluminium coule