CA1299842C - Reduction de la quantite d'affluent de regeneration - Google Patents

Reduction de la quantite d'affluent de regeneration

Info

Publication number: CA1299842C
Authority: CA; Canada
Prior art keywords: regeneration; absorbent; stream; effluent; sulfur
Prior art date: 1986-09-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000547247A

Other languages

English (en)

Inventor

Min-Hsiun Lee

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BP Corp North America Inc

Original Assignee

BP Corp North America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-09-30

Filing date

1987-09-18

Publication date

1992-05-05

1987-09-18 Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc

1992-05-05 Application granted granted Critical

1992-05-05 Publication of CA1299842C publication Critical patent/CA1299842C/fr

2009-05-05 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

230000008929 regeneration Effects 0.000 title claims abstract description 141
238000011069 regeneration method Methods 0.000 title claims abstract description 141
239000002250 absorbent Substances 0.000 title claims description 112
230000002745 absorbent Effects 0.000 title claims description 112
230000000153 supplemental effect Effects 0.000 title claims description 11
238000001816 cooling Methods 0.000 title description 11
229910044991 metal oxide Inorganic materials 0.000 title description 6
150000004706 metal oxides Chemical class 0.000 title description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 55
229910052717 sulfur Inorganic materials 0.000 claims abstract description 38
239000011593 sulfur Substances 0.000 claims abstract description 38
239000006096 absorbing agent Substances 0.000 claims description 68
238000000034 method Methods 0.000 claims description 38
150000003464 sulfur compounds Chemical class 0.000 claims description 32
230000008569 process Effects 0.000 claims description 20
239000003085 diluting agent Substances 0.000 claims description 12
238000011084 recovery Methods 0.000 claims description 8
230000001172 regenerating effect Effects 0.000 claims description 6
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 122
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 96
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 62
229910000037 hydrogen sulfide Inorganic materials 0.000 description 62
239000011787 zinc oxide Substances 0.000 description 60
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 54
229910052760 oxygen Inorganic materials 0.000 description 54
239000001301 oxygen Substances 0.000 description 54
239000007789 gas Substances 0.000 description 48
230000009102 absorption Effects 0.000 description 47
238000010521 absorption reaction Methods 0.000 description 47
229940065278 sulfur compound Drugs 0.000 description 28
229910052984 zinc sulfide Inorganic materials 0.000 description 28
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 27
238000006243 chemical reaction Methods 0.000 description 21
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 20
238000010926 purge Methods 0.000 description 20
241000894007 species Species 0.000 description 20
238000005984 hydrogenation reaction Methods 0.000 description 15
239000003054 catalyst Substances 0.000 description 13
230000009467 reduction Effects 0.000 description 8
238000006722 reduction reaction Methods 0.000 description 8
229910001868 water Inorganic materials 0.000 description 8
230000003197 catalytic effect Effects 0.000 description 7
238000010438 heat treatment Methods 0.000 description 7
150000004763 sulfides Chemical class 0.000 description 7
239000000463 material Substances 0.000 description 6
238000001179 sorption measurement Methods 0.000 description 6
238000006555 catalytic reaction Methods 0.000 description 5
230000000670 limiting effect Effects 0.000 description 5
230000001590 oxidative effect Effects 0.000 description 5
239000000126 substance Substances 0.000 description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 4
238000010276 construction Methods 0.000 description 4
230000003247 decreasing effect Effects 0.000 description 4
230000000694 effects Effects 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
239000005083 Zinc sulfide Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
238000012544 monitoring process Methods 0.000 description 3
239000007800 oxidant agent Substances 0.000 description 3
238000005192 partition Methods 0.000 description 3
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 3
ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
238000007792 addition Methods 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000000151 deposition Methods 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
-1 for example Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000008188 pellet Substances 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
238000007670 refining Methods 0.000 description 2
102200060543 rs1060505037 Human genes 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
230000019635 sulfation Effects 0.000 description 2
238000005670 sulfation reaction Methods 0.000 description 2
238000011144 upstream manufacturing Methods 0.000 description 2
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
NINIDFKCEFEMDL-AKLPVKDBSA-N Sulfur-35 Chemical compound [35S] NINIDFKCEFEMDL-AKLPVKDBSA-N 0.000 description 1
241000746181 Therates Species 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910001570 bauxite Inorganic materials 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
238000004891 communication Methods 0.000 description 1
230000006854 communication Effects 0.000 description 1
239000002826 coolant Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000011143 downstream manufacturing Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000004513 sizing Methods 0.000 description 1
WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
235000010234 sodium benzoate Nutrition 0.000 description 1
239000004299 sodium benzoate Substances 0.000 description 1
229910052950 sphalerite Inorganic materials 0.000 description 1
230000002311 subsequent effect Effects 0.000 description 1
125000000101 thioether group Chemical group 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
239000002918 waste heat Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
229960001763 zinc sulfate Drugs 0.000 description 1
229910000368 zinc sulfate Inorganic materials 0.000 description 1

Landscapes

Treating Waste Gases (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

CA000547247A 1986-09-30 1987-09-18 Reduction de la quantite d'affluent de regeneration Expired - Lifetime CA1299842C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US91328986A	1986-09-30	1986-09-30
US913,289		1986-09-30

Publications (1)

Publication Number	Publication Date
CA1299842C true CA1299842C (fr)	1992-05-05

Family

ID=25433134

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000547247A Expired - Lifetime CA1299842C (fr)	1986-09-30	1987-09-18	Reduction de la quantite d'affluent de regeneration

Country Status (1)

Country	Link
CA (1)	CA1299842C (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2017165106A1 (fr) *	2016-03-23	2017-09-28	Exxonmobil Research And Engineering Company	Traitement d'unité claus d'un gaz résiduaire d'arrêt

1987
- 1987-09-18 CA CA000547247A patent/CA1299842C/fr not_active Expired - Lifetime

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2017165106A1 (fr) *	2016-03-23	2017-09-28	Exxonmobil Research And Engineering Company	Traitement d'unité claus d'un gaz résiduaire d'arrêt
CN109071226A (zh) *	2016-03-23	2018-12-21	埃克森美孚研究工程公司	停车尾气的克劳斯单元处理
US10188988B2 (en)	2016-03-23	2019-01-29	Exxonmobil Research And Engineering Company	Claus unit treatment of shutdown tail gas
CN109071226B (zh) *	2016-03-23	2019-11-22	埃克森美孚研究工程公司	停车尾气的克劳斯单元处理
US10618005B2 (en)	2016-03-23	2020-04-14	Exxonmobil Research And Engineering Company	Claus unit treatment of shutdown tail gas

Legal Events

Date	Code	Title	Description
2009-05-05	MKEX	Expiry

Publication	Publication Date	Title
US4533529A (en)	1985-08-06	Sulfur recovery process
US3764665A (en)	1973-10-09	Combined sulfur oxides acceptance-sulfur recovery process
US8500851B2 (en)	2013-08-06	Multiple fixed-fluidized beds for contaminant removal
US4797268A (en)	1989-01-10	Sulfur recovery process using metal oxide absorbent with regenerator recycle to Claus catalytic reactor
US7901646B2 (en)	2011-03-08	System and method for sulfur recovery
CA1168024A (fr)	1984-05-29	Procede claus, basse temperature, avec elimination d'eau
EP0073074B1 (fr)	1987-11-25	Procédé pour réduire le contenu total en soufre d'un gaz d'alimentation à haut contenu en CO2
GB2105315A (en)	1983-03-23	Production of sulphur from a gas containing h 2 s
US4849202A (en)	1989-07-18	Sulfur recovery process using metal oxide absorbent with reducing gas purge
US4871521A (en)	1989-10-03	Sulfur recovery process using metal oxide absorbent with improved purge
EP0046061A1 (fr)	1982-02-17	Procédé pour la séparation sélective de l'hydrogène sulfuré des mélanges de gaz contenant de l'anhydride carbonique et de l'hydrogène sulfuré
EP0159730A2 (fr)	1985-10-30	Procédé pour l'élimination de composés soufrés de gaz d'échappement
US4954331A (en)	1990-09-04	Sulfur recovery process using metal oxide absorbent
JPH02180614A (ja)	1990-07-13	高温還元性ガスの精製プロセスにおけるイオウ回収方法
US4769229A (en)	1988-09-06	Sulfur recovery process using metal oxide absorber feed for regeneration
CA1296508C (fr)	1992-03-03	Elimination d'une partie de la vapeur d'eau apres regeneration d'un oxyde metallique absorbant, afin de deruire le debit de recyclage
GB2190683A (en)	1987-11-25	Method for purifying high-temperature reducing gas
CA1290551C (fr)	1991-10-15	Methode de recuperation du soufre a l'aide d'un absorbant d'oxyde metallique
EP0256741B1 (fr)	1992-02-26	Procédé de récupération de soufre par une purge avec un gaz réducteur en utilisant des absorbants d'oxydes métalliques
US4793976A (en)	1988-12-27	Sulfur recovery system
US4913637A (en)	1990-04-03	Sulfur recovery system
WO2001052974A1 (fr)	2001-07-26	Procede pour eliminer des composes sulfures de melanges gazeux
CA1117276A (fr)	1982-02-02	Procede d'extraction du sulfure d'hydrogene dans des melanges gazeux
JPH0790137B2 (ja)	1995-10-04	高温還元性ガスの精製方法
EP0318086A1 (fr)	1989-05-31	Procédé pour regénérer un adsorbant carbonacé chargé d'acide sulfurique et d'eau