CA1304883C - Preparation of homopolymers and copolymers of propene using a ziegler-natta catalyst system - Google Patents

Preparation of homopolymers and copolymers of propene using a ziegler-natta catalyst system

Info

Publication number: CA1304883C
Authority: CA; Canada
Prior art keywords: titanium; stage; component; solid; carrier
Prior art date: 1987-04-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000564511A

Other languages

English (en)

French (fr)

Inventor

Jurgen Kerth

Ralf Zolk

Rainer Alexander Werner

Gunther Schweier

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Novolen Technology Holdings CV

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-04-25

Filing date

1988-04-19

Publication date

1992-07-07

1988-04-19 Application filed by BASF SE filed Critical BASF SE

1992-07-07 Application granted granted Critical

1992-07-07 Publication of CA1304883C publication Critical patent/CA1304883C/en

2009-07-07 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 22
239000011954 Ziegler–Natta catalyst Substances 0.000 title claims abstract description 6
238000002360 preparation method Methods 0.000 title claims description 14
229920001577 copolymer Polymers 0.000 title claims description 5
229920001519 homopolymer Polymers 0.000 title claims description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 40
239000010936 titanium Substances 0.000 claims abstract description 39
229910052719 titanium Inorganic materials 0.000 claims abstract description 39
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 36
238000000034 method Methods 0.000 claims abstract description 34
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 23
239000007790 solid phase Substances 0.000 claims abstract description 20
239000011777 magnesium Substances 0.000 claims abstract description 16
150000002901 organomagnesium compounds Chemical class 0.000 claims abstract description 16
239000000741 silica gel Substances 0.000 claims abstract description 16
229910002027 silica gel Inorganic materials 0.000 claims abstract description 16
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 15
229910052749 magnesium Inorganic materials 0.000 claims abstract description 15
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 13
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 13
239000000460 chlorine Substances 0.000 claims abstract description 13
229910052801 chlorine Inorganic materials 0.000 claims abstract description 13
229930195733 hydrocarbon Natural products 0.000 claims abstract description 13
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 13
229910000077 silane Inorganic materials 0.000 claims abstract description 13
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 12
239000012320 chlorinating reagent Substances 0.000 claims abstract description 9
150000003021 phthalic acid derivatives Chemical class 0.000 claims abstract description 9
239000007788 liquid Substances 0.000 claims abstract description 7
LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 claims abstract description 4
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 4
239000003054 catalyst Substances 0.000 claims description 23
229910052782 aluminium Inorganic materials 0.000 claims description 15
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
238000006116 polymerization reaction Methods 0.000 claims description 15
125000004432 carbon atom Chemical group C* 0.000 claims description 11
238000002156 mixing Methods 0.000 claims description 10
239000000126 substance Substances 0.000 claims description 9
125000000217 alkyl group Chemical group 0.000 claims description 8
239000000203 mixture Substances 0.000 claims description 8
239000000178 monomer Substances 0.000 claims description 8
239000002245 particle Substances 0.000 claims description 8
239000007791 liquid phase Substances 0.000 claims description 6
239000000377 silicon dioxide Substances 0.000 claims description 6
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
239000003795 chemical substances by application Substances 0.000 claims description 4
229910052681 coesite Inorganic materials 0.000 claims description 4
229910052906 cristobalite Inorganic materials 0.000 claims description 4
-1 ethylphenyl Chemical group 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
229910052710 silicon Inorganic materials 0.000 claims description 4
239000010703 silicon Substances 0.000 claims description 4
235000012239 silicon dioxide Nutrition 0.000 claims description 4
229910052682 stishovite Inorganic materials 0.000 claims description 4
229910052905 tridymite Inorganic materials 0.000 claims description 4
101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 claims description 3
238000000605 extraction Methods 0.000 claims description 3
239000011148 porous material Substances 0.000 claims description 3
229920006395 saturated elastomer Polymers 0.000 claims description 3
125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims description 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
229910052593 corundum Inorganic materials 0.000 claims description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
229920001155 polypropylene Polymers 0.000 claims description 2
239000011541 reaction mixture Substances 0.000 claims description 2
229910001845 yogo sapphire Inorganic materials 0.000 claims description 2
239000000306 component Substances 0.000 abstract description 45
229920000642 polymer Polymers 0.000 abstract description 11
239000000543 intermediate Substances 0.000 abstract 1
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 20
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
235000013350 formula milk Nutrition 0.000 description 11
235000001055 magnesium Nutrition 0.000 description 10
229940091250 magnesium supplement Drugs 0.000 description 10
239000000047 product Substances 0.000 description 6
238000003756 stirring Methods 0.000 description 6
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
150000001335 aliphatic alkanes Chemical class 0.000 description 3
238000001914 filtration Methods 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
150000002367 halogens Chemical class 0.000 description 3
239000012071 phase Substances 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
229910052796 boron Inorganic materials 0.000 description 2
239000000969 carrier Substances 0.000 description 2
230000002301 combined effect Effects 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
AAMBIAPMLISIDH-UHFFFAOYSA-N dimethoxy-bis(2-methylphenyl)silane Chemical compound C=1C=CC=C(C)C=1[Si](OC)(OC)C1=CC=CC=C1C AAMBIAPMLISIDH-UHFFFAOYSA-N 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000000499 gel Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
229910000041 hydrogen chloride Inorganic materials 0.000 description 2
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
239000007787 solid Substances 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical group CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
VBFBBEDUJWNHHL-UHFFFAOYSA-N [Cl].[Cl].[Cl].[Cl].[Ti] Chemical compound [Cl].[Cl].[Cl].[Cl].[Ti] VBFBBEDUJWNHHL-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
MCOQHIWZJUDQIC-UHFFFAOYSA-N barban Chemical compound ClCC#CCOC(=O)NC1=CC=CC(Cl)=C1 MCOQHIWZJUDQIC-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
GPUADMRJQVPIAS-QCVDVZFFSA-M cerivastatin sodium Chemical compound [Na+].COCC1=C(C(C)C)N=C(C(C)C)C(\C=C\[C@@H](O)C[C@@H](O)CC([O-])=O)=C1C1=CC=C(F)C=C1 GPUADMRJQVPIAS-QCVDVZFFSA-M 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
TUZXHLFJEVFZAF-UHFFFAOYSA-N diethoxy-bis(2-methylphenyl)silane Chemical compound C=1C=CC=C(C)C=1[Si](OCC)(OCC)C1=CC=CC=C1C TUZXHLFJEVFZAF-UHFFFAOYSA-N 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000002140 halogenating effect Effects 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
229940035429 isobutyl alcohol Drugs 0.000 description 1
238000002955 isolation Methods 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
150000005673 monoalkenes Chemical class 0.000 description 1
230000000877 morphologic effect Effects 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
AJQDYNXUEQUEFI-UHFFFAOYSA-N phenyl(2,2,2-triethoxyethyl)silane Chemical compound C(C)OC(C[SiH2]C1=CC=CC=C1)(OCC)OCC AJQDYNXUEQUEFI-UHFFFAOYSA-N 0.000 description 1
PARWUHTVGZSQPD-UHFFFAOYSA-N phenylsilane Chemical compound [SiH3]C1=CC=CC=C1 PARWUHTVGZSQPD-UHFFFAOYSA-N 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
125000000612 phthaloyl group Chemical group C(C=1C(C(=O)*)=CC=CC1)(=O)* 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
WBYKGOGDEZGLDO-UHFFFAOYSA-N triethoxy-(2-methylphenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1C WBYKGOGDEZGLDO-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CA000564511A 1987-04-25 1988-04-19 Preparation of homopolymers and copolymers of propene using a ziegler-natta catalyst system Expired - Lifetime CA1304883C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DEP3713943.6		1987-04-25
DE19873713943 DE3713943A1 (de)	1987-04-25	1987-04-25	Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems

Publications (1)

Publication Number	Publication Date
CA1304883C true CA1304883C (en)	1992-07-07

Family

ID=6326327

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000564511A Expired - Lifetime CA1304883C (en)	1987-04-25	1988-04-19	Preparation of homopolymers and copolymers of propene using a ziegler-natta catalyst system

Country Status (8)

Country	Link
EP (1)	EP0288845B1 (de)
JP (1)	JP2594311B2 (de)
AR (1)	AR245149A1 (de)
AT (1)	ATE62697T1 (de)
AU (1)	AU600353B2 (de)
CA (1)	CA1304883C (de)
DE (2)	DE3713943A1 (de)
ES (1)	ES2021782B3 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3730022A1 (de) *	1987-09-08	1989-03-16	Basf Ag	Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
DE3829519A1 (de) *	1988-08-31	1990-03-01	Basf Ag	Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
DE3830195A1 (de) *	1988-09-06	1990-03-15	Basf Ag	Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
FI90083C (fi) *	1990-12-20	1993-12-27	Neste Oy	Foer olefinpolymerisation avsett stereospecifikt katalysatorsystem
US5773537A (en) *	1992-05-19	1998-06-30	Basf Aktiengesellschaft	Ziegler-natta catalyst systems containing specific organosilicon compounds
US6184328B1 (en)	1994-09-07	2001-02-06	Showa Denko Kabushiki Kaisha	Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production
CN1100069C (zh) *	1994-05-12	2003-01-29	昭和电工株式会社	丙烯系聚合物及其制法
EP2113520B1 (de)	2001-11-01	2015-10-07	Idemitsu Kosan Co., Ltd.	Feststoffkatalysatorkomponente zur olefinpolymerisation, katalysator zur olefinpolymerisation und verfahren zur herstellung eines olefinpolymers
KR100989997B1 (ko)	2002-05-24	2010-10-26	이데미쓰 고산 가부시키가이샤	마그네슘 화합물, 올레핀 중합용 고체 촉매 성분, 올레핀중합용 촉매 및 폴리올레핀의 제조방법
US7737069B2 (en)	2004-04-23	2010-06-15	Idemitsu Kosan Co., Ltd.	Magnesium compound, catalyst for olefin polymerization and method for producing olefin polymer
US20070219326A1 (en)	2004-08-03	2007-09-20	Idemitsu Kosan Co., Ltd.	Magnesium Compound, Solid Catalyst Component, Olefin Polymerization Catalyst, and Method for Producing Olefin Polymer
CN101014558A (zh)	2004-08-24	2007-08-08	出光兴产株式会社	镁化合物、固体催化剂成分、烯烃聚合催化剂和聚烯烃的制造方法
US7329626B2 (en)	2004-09-07	2008-02-12	Lummus Novolen Technology Gmbh	Ziegler-Natta catalyst, preparation, and use for the polymerization of alkenes

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3062482D1 (en) *	1979-01-10	1983-05-05	Ici Plc	Olefine polymerisation catalyst and the production and use thereof
IT1209255B (it) *	1980-08-13	1989-07-16	Montedison Spa	Catalizzatori per la polimerizzazione di olefine.
US4565796A (en) *	1984-08-06	1986-01-21	Exxon Research & Engineering Co.	Polymerization catalyst, production and use
DE3629583A1 (de) *	1986-08-30	1988-03-03	Basf Ag	Verfahren zum herstellen von homo- und copolymerisaten des propylens mittels eines ziegler-natta-katalysatorsystems
DE3629932A1 (de) *	1986-09-03	1988-03-10	Basf Ag	Verfahren zum herstellen von homo- und copolymerisaten des propylens mittels eines ziegler-natta-katalysatorsystems
DE3711919A1 (de) *	1987-04-08	1988-10-27	Basf Ag	Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems

1987
- 1987-04-25 DE DE19873713943 patent/DE3713943A1/de not_active Withdrawn
1988
- 1988-04-16 ES ES88106087T patent/ES2021782B3/es not_active Expired - Lifetime
- 1988-04-16 EP EP88106087A patent/EP0288845B1/de not_active Expired - Lifetime
- 1988-04-16 DE DE8888106087T patent/DE3862417D1/de not_active Expired - Lifetime
- 1988-04-16 AT AT88106087T patent/ATE62697T1/de not_active IP Right Cessation
- 1988-04-19 CA CA000564511A patent/CA1304883C/en not_active Expired - Lifetime
- 1988-04-22 AR AR88310633A patent/AR245149A1/es active
- 1988-04-22 JP JP63098495A patent/JP2594311B2/ja not_active Expired - Fee Related
- 1988-04-26 AU AU15087/88A patent/AU600353B2/en not_active Ceased

Also Published As

Publication number	Publication date
JPS63280707A (ja)	1988-11-17
DE3862417D1 (de)	1991-05-23
ES2021782B3 (es)	1991-11-16
AR245149A1 (es)	1993-12-30
EP0288845A3 (en)	1989-03-22
EP0288845B1 (de)	1991-04-17
DE3713943A1 (de)	1988-11-03
JP2594311B2 (ja)	1997-03-26
EP0288845A2 (de)	1988-11-02
ATE62697T1 (de)	1991-05-15
AU600353B2 (en)	1990-08-09
AU1508788A (en)	1988-10-27

Legal Events

Date	Code	Title	Description
2007-07-09	MKLA	Lapsed

Publication	Publication Date	Title
US4857613A (en)	1989-08-15	Preparation of homopolymers and copolymers of propene using a Ziegler-Natta catalyst system
US5288824A (en)	1994-02-22	Preparation of homo- and copolymers of propene by means of a Ziegler-Natta catalyst system
US4107414A (en)	1978-08-15	Process for the stereoregular polymerization of alpha olefins
US5773537A (en)	1998-06-30	Ziegler-natta catalyst systems containing specific organosilicon compounds
CA1304883C (en)	1992-07-07	Preparation of homopolymers and copolymers of propene using a ziegler-natta catalyst system
US4156063A (en)	1979-05-22	Process for the stereoregular polymerization of alpha olefins
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