CA1306084C - Preparation de matieres de charge pour papier - Google Patents
Preparation de matieres de charge pour papierInfo
- Publication number
- CA1306084C CA1306084C CA000561950A CA561950A CA1306084C CA 1306084 C CA1306084 C CA 1306084C CA 000561950 A CA000561950 A CA 000561950A CA 561950 A CA561950 A CA 561950A CA 1306084 C CA1306084 C CA 1306084C
- Authority
- CA
- Canada
- Prior art keywords
- filler
- flocculated
- paper
- process according
- filler material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000945 filler Substances 0.000 title claims abstract description 96
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000002245 particle Substances 0.000 claims abstract description 46
- 239000002002 slurry Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 30
- 230000008569 process Effects 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000008394 flocculating agent Substances 0.000 claims abstract description 18
- 238000010008 shearing Methods 0.000 claims abstract description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 76
- 229920002472 Starch Polymers 0.000 claims description 47
- 235000019698 starch Nutrition 0.000 claims description 47
- 239000008107 starch Substances 0.000 claims description 45
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 42
- 239000000123 paper Substances 0.000 claims description 35
- 125000002091 cationic group Chemical group 0.000 claims description 32
- 239000007787 solid Substances 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 239000011087 paperboard Substances 0.000 claims description 7
- 235000010216 calcium carbonate Nutrition 0.000 description 36
- 230000014759 maintenance of location Effects 0.000 description 26
- 239000000835 fiber Substances 0.000 description 20
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 238000011068 loading method Methods 0.000 description 8
- 235000019426 modified starch Nutrition 0.000 description 8
- 235000010215 titanium dioxide Nutrition 0.000 description 7
- 229920000881 Modified starch Polymers 0.000 description 6
- 239000004927 clay Substances 0.000 description 6
- 239000002655 kraft paper Substances 0.000 description 6
- 238000005189 flocculation Methods 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 238000004513 sizing Methods 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000016615 flocculation Effects 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- -1 lithopone Chemical compound 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000011121 hardwood Substances 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229920006320 anionic starch Polymers 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000009172 bursting Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000003311 flocculating effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 238000003921 particle size analysis Methods 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- AQXWTIGNZRWREN-UHFFFAOYSA-L 3-chloropropyl(trimethyl)azanium;1-chloro-3-pyridin-1-ium-1-ylpropan-2-ol;dichloride Chemical compound [Cl-].[Cl-].C[N+](C)(C)CCCCl.ClCC(O)C[N+]1=CC=CC=C1 AQXWTIGNZRWREN-UHFFFAOYSA-L 0.000 description 1
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical group [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 description 1
- JAFYGQGKGCCBMC-UHFFFAOYSA-M 4-chlorobut-1-enyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)C=CCCCl JAFYGQGKGCCBMC-UHFFFAOYSA-M 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 241001161507 Titanus Species 0.000 description 1
- MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- PLRSNUWXOYYMKP-UHFFFAOYSA-M chloromethyl-(3-hydroxypropyl)-dimethylazanium;chloride Chemical compound [Cl-].ClC[N+](C)(C)CCCO PLRSNUWXOYYMKP-UHFFFAOYSA-M 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000010452 phosphate Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000001038 titanium pigment Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paper (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/045,221 US4799964A (en) | 1985-07-29 | 1987-04-29 | Preparation of filler compositions for paper |
| US045,221 | 1987-04-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1306084C true CA1306084C (fr) | 1992-08-11 |
Family
ID=21936683
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000561950A Expired - Lifetime CA1306084C (fr) | 1987-04-29 | 1988-03-21 | Preparation de matieres de charge pour papier |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1306084C (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009036271A1 (fr) * | 2007-09-12 | 2009-03-19 | Nalco Company | Préfloculation de charge contrôlable utilisant un système à deux polymères |
| US8088213B2 (en) | 2007-09-12 | 2012-01-03 | Nalco Company | Controllable filler prefloculation using a dual polymer system |
| EP2914774A4 (fr) * | 2012-11-01 | 2016-06-29 | Nalco Co | Préfloculation de charges utilisées dans la fabrication de papier |
| US9487916B2 (en) | 2007-09-12 | 2016-11-08 | Nalco Company | Method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in papermaking |
| US9752283B2 (en) | 2007-09-12 | 2017-09-05 | Ecolab Usa Inc. | Anionic preflocculation of fillers used in papermaking |
-
1988
- 1988-03-21 CA CA000561950A patent/CA1306084C/fr not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009036271A1 (fr) * | 2007-09-12 | 2009-03-19 | Nalco Company | Préfloculation de charge contrôlable utilisant un système à deux polymères |
| US8088213B2 (en) | 2007-09-12 | 2012-01-03 | Nalco Company | Controllable filler prefloculation using a dual polymer system |
| US9487916B2 (en) | 2007-09-12 | 2016-11-08 | Nalco Company | Method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in papermaking |
| US9752283B2 (en) | 2007-09-12 | 2017-09-05 | Ecolab Usa Inc. | Anionic preflocculation of fillers used in papermaking |
| US10145067B2 (en) | 2007-09-12 | 2018-12-04 | Ecolab Usa Inc. | Method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in papermaking |
| EP2914774A4 (fr) * | 2012-11-01 | 2016-06-29 | Nalco Co | Préfloculation de charges utilisées dans la fabrication de papier |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed | ||
| MKEC | Expiry (correction) |
Effective date: 20121205 |