CA1306085C - Agregation de kaolinite a l'aide de composes organosilicies - Google Patents

Agregation de kaolinite a l'aide de composes organosilicies

Info

Publication number: CA1306085C
Authority: CA; Canada
Prior art keywords: kaolin; feed; weight; clay; silicon compound
Prior art date: 1988-10-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000581316A

Other languages

English (en)

Inventor

Rasik H. Raythatha

Joshua O. Brannen, Iii

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ECC America Inc

Original Assignee

ECC America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-10-26

Filing date

1988-10-26

Publication date

1992-08-11

1988-10-26 Application filed by ECC America Inc filed Critical ECC America Inc

1988-10-26 Priority to CA000581316A priority Critical patent/CA1306085C/fr

1992-08-11 Application granted granted Critical

1992-08-11 Publication of CA1306085C publication Critical patent/CA1306085C/fr

2009-08-11 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 title claims abstract description 63
238000004220 aggregation Methods 0.000 title claims abstract description 27
230000002776 aggregation Effects 0.000 title claims abstract description 27
229910052622 kaolinite Inorganic materials 0.000 title abstract description 20
150000003961 organosilicon compounds Chemical class 0.000 title abstract description 8
239000000049 pigment Substances 0.000 claims abstract description 68
235000012211 aluminium silicate Nutrition 0.000 claims abstract description 44
239000005995 Aluminium silicate Substances 0.000 claims abstract description 43
239000000945 filler Substances 0.000 claims abstract description 33
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 23
230000004931 aggregating effect Effects 0.000 claims abstract description 21
239000003795 chemical substances by application Substances 0.000 claims abstract description 21
238000000576 coating method Methods 0.000 claims abstract description 18
239000011248 coating agent Substances 0.000 claims abstract description 16
150000003377 silicon compounds Chemical class 0.000 claims abstract description 15
238000002156 mixing Methods 0.000 claims abstract description 14
LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims abstract description 12
238000000149 argon plasma sintering Methods 0.000 claims abstract description 10
238000000034 method Methods 0.000 claims description 83
239000000047 product Substances 0.000 claims description 42
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 24
239000002245 particle Substances 0.000 claims description 24
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 16
229910000077 silane Inorganic materials 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 12
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 11
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 11
150000001875 compounds Chemical class 0.000 claims description 11
229910000019 calcium carbonate Inorganic materials 0.000 claims description 10
239000001110 calcium chloride Substances 0.000 claims description 10
229910001628 calcium chloride Inorganic materials 0.000 claims description 10
230000002708 enhancing effect Effects 0.000 claims description 10
125000000217 alkyl group Chemical group 0.000 claims description 7
238000004519 manufacturing process Methods 0.000 claims description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
-1 alkaline earth metal salts Chemical class 0.000 claims description 6
229910021529 ammonia Inorganic materials 0.000 claims description 5
239000006227 byproduct Substances 0.000 claims description 5
239000007788 liquid Substances 0.000 claims description 4
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 4
230000003287 optical effect Effects 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 3
150000003839 salts Chemical class 0.000 claims description 3
229910052710 silicon Inorganic materials 0.000 claims description 2
WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical compound [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 claims 4
ULOIAOPTGWSNHU-UHFFFAOYSA-N 2-butyl radical Chemical compound C[CH]CC ULOIAOPTGWSNHU-UHFFFAOYSA-N 0.000 claims 4
229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
229910001420 alkaline earth metal ion Inorganic materials 0.000 claims 1
239000010703 silicon Substances 0.000 claims 1
239000010419 fine particle Substances 0.000 abstract description 4
239000004927 clay Substances 0.000 description 98
239000011800 void material Substances 0.000 description 43
239000000123 paper Substances 0.000 description 30
230000008569 process Effects 0.000 description 27
239000000126 substance Substances 0.000 description 26
238000011068 loading method Methods 0.000 description 20
239000002002 slurry Substances 0.000 description 10
239000007858 starting material Substances 0.000 description 9
238000009826 distribution Methods 0.000 description 8
230000000694 effects Effects 0.000 description 8
239000012467 final product Substances 0.000 description 7
238000004062 sedimentation Methods 0.000 description 7
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
230000001965 increasing effect Effects 0.000 description 6
229910001510 metal chloride Inorganic materials 0.000 description 6
238000001354 calcination Methods 0.000 description 5
238000009472 formulation Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
VOLGAXAGEUPBDM-UHFFFAOYSA-N $l^{1}-oxidanylethane Chemical compound CC[O] VOLGAXAGEUPBDM-UHFFFAOYSA-N 0.000 description 4
239000000463 material Substances 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
238000012545 processing Methods 0.000 description 4
239000007921 spray Substances 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
238000005299 abrasion Methods 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
238000001035 drying Methods 0.000 description 3
230000006872 improvement Effects 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
239000011707 mineral Substances 0.000 description 3
239000004033 plastic Substances 0.000 description 3
229920003023 plastic Polymers 0.000 description 3
239000011148 porous material Substances 0.000 description 3
239000004408 titanium dioxide Substances 0.000 description 3
AOAUDAYOMHDUEU-UHFFFAOYSA-N 3-silylpropane-1-thiol Chemical class [SiH3]CCCS AOAUDAYOMHDUEU-UHFFFAOYSA-N 0.000 description 2
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
125000002877 alkyl aryl group Chemical group 0.000 description 2
125000003710 aryl alkyl group Chemical group 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000008199 coating composition Substances 0.000 description 2
229920001971 elastomer Polymers 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
238000011049 filling Methods 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
238000005259 measurement Methods 0.000 description 2
WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical group [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000011087 paperboard Substances 0.000 description 2
239000008188 pellet Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000843 powder Substances 0.000 description 2
229940088417 precipitated calcium carbonate Drugs 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
239000005049 silicon tetrachloride Substances 0.000 description 2
125000004149 thio group Chemical group *S* 0.000 description 2
238000009736 wetting Methods 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910018957 MClx Inorganic materials 0.000 description 1
MZZSDCJQCLYLLL-UHFFFAOYSA-N Secalonsaeure A Natural products COC(=O)C12OC3C(CC1=C(O)CC(C)C2O)C(=CC=C3c4ccc(O)c5C(=O)C6=C(O)CC(C)C(O)C6(Oc45)C(=O)OC)O MZZSDCJQCLYLLL-UHFFFAOYSA-N 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
229910001617 alkaline earth metal chloride Inorganic materials 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
230000000332 continued effect Effects 0.000 description 1
239000013058 crude material Substances 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
238000005906 dihydroxylation reaction Methods 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000000428 dust Substances 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
239000003623 enhancer Substances 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000005189 flocculation Methods 0.000 description 1
230000016615 flocculation Effects 0.000 description 1
238000007429 general method Methods 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
230000031700 light absorption Effects 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
230000009972 noncorrosive effect Effects 0.000 description 1
239000003605 opacifier Substances 0.000 description 1
238000013021 overheating Methods 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000002310 reflectometry Methods 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
239000005060 rubber Substances 0.000 description 1
239000013049 sediment Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
238000012360 testing method Methods 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1

Landscapes

Paper (AREA)
Pigments, Carbon Blacks, Or Wood Stains (AREA)

CA000581316A 1988-10-26 1988-10-26 Agregation de kaolinite a l'aide de composes organosilicies Expired - Fee Related CA1306085C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000581316A CA1306085C (fr)	1988-10-26	1988-10-26	Agregation de kaolinite a l'aide de composes organosilicies

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000581316A CA1306085C (fr)	1988-10-26	1988-10-26	Agregation de kaolinite a l'aide de composes organosilicies

Publications (1)

Publication Number	Publication Date
CA1306085C true CA1306085C (fr)	1992-08-11

Family

ID=4138979

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000581316A Expired - Fee Related CA1306085C (fr)	1988-10-26	1988-10-26	Agregation de kaolinite a l'aide de composes organosilicies

Country Status (1)

Country	Link
CA (1)	CA1306085C (fr)

1988
- 1988-10-26 CA CA000581316A patent/CA1306085C/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1997-08-11	MKLA	Lapsed

Publication	Publication Date	Title
US4818294A (en)	1989-04-04	Kaolinite aggregation using organo-silicon compounds
US4117191A (en)	1978-09-26	Composite silicate pigment
EP0585411B1 (fr)	1995-12-06	Pigments composites opacifiants au dioxyde de titane calcine et au kaolin, procedes de preparation et d'utilisation
US4806167A (en)	1989-02-21	Kaolin aggregation using combination of organic and inorganic bases
AU659815B2 (en)	1995-06-01	Aggregated composite mineral pigments
US4826536A (en)	1989-05-02	Structured kaolin pigments
US5236989A (en)	1993-08-17	Aggregated composite mineral pigments
US4816074A (en)	1989-03-28	Kaolinite aggregation using sodium silicate
US4851048A (en)	1989-07-25	Structured kaolin pigment and process for manufacture thereof
US5551975A (en)	1996-09-03	Structured pigment compositions, methods for preparation and use
US5449402A (en)	1995-09-12	Modified inorganic pigments, methods of preparation, and compositions containing the same
US4026721A (en)	1977-05-31	Composite silicate pigment
CA1142811A (fr)	1983-03-15	Pigment naturel de kaolin modifie en suface a l'aide d'un gel d'hydrate anionique de al.sub.2o.sub.3-sio.sub.2 et d'un liant polymerique
US4072537A (en)	1978-02-07	Composite silicate pigment
US4820554A (en)	1989-04-11	Coated paper and process
US5458680A (en)	1995-10-17	Method of producing aggregated composite pigments using organic silicon compounds
US4935062A (en)	1990-06-19	Kaolinite aggregation using organo-silicon compounds
US4626290A (en)	1986-12-02	Inorganic filler and process for production thereof
GB2102829A (en)	1983-02-09	Opacifying pigments for paper
US5232495A (en)	1993-08-03	Method of producing aggregated kaolinite pigment using organic silicon compounds
CA2479597C (fr)	2011-11-01	Voile fibreux et procede de fabrication associe
AU585942B2 (en)	1989-06-29	Structured kaolin pigments
US5690728A (en)	1997-11-25	Way to synthesize structured composite premium pigments
CA1306085C (fr)	1992-08-11	Agregation de kaolinite a l'aide de composes organosilicies
US5298066A (en)	1994-03-29	Method of producing aggregated kaolinite pigment using organic silicon compounds