CA1309791C - Procede permettant d'ameliorer l'aspect d'un fini multicouche - Google Patents

Procede permettant d'ameliorer l'aspect d'un fini multicouche

Info

Publication number: CA1309791C
Authority: CA; Canada
Prior art keywords: weight; coating composition; guide; coating; polymer
Prior art date: 1986-09-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000553472A

Other languages

English (en)

Inventor

David C.K. Chang

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee

EI Du Pont de Nemours and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-09-11

Filing date

1987-12-03

Publication date

1992-11-03

1986-09-11 Priority claimed from US06/906,195 external-priority patent/US4731290A/en

1987-12-03 Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co

1987-12-03 Priority to CA000553472A priority Critical patent/CA1309791C/fr

1992-11-03 Application granted granted Critical

1992-11-03 Publication of CA1309791C publication Critical patent/CA1309791C/fr

2009-11-03 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 25
239000008199 coating composition Substances 0.000 claims abstract description 49
238000000576 coating method Methods 0.000 claims abstract description 45
239000011248 coating agent Substances 0.000 claims abstract description 44
239000000049 pigment Substances 0.000 claims abstract description 22
239000004816 latex Substances 0.000 claims abstract description 21
229920000126 latex Polymers 0.000 claims abstract description 21
239000000758 substrate Substances 0.000 claims abstract description 14
239000003431 cross linking reagent Substances 0.000 claims abstract description 13
239000008365 aqueous carrier Substances 0.000 claims abstract description 5
239000000203 mixture Substances 0.000 claims description 17
239000011230 binding agent Substances 0.000 claims description 13
229920000642 polymer Polymers 0.000 claims description 13
IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 10
-1 alkyl methacrylate Chemical compound 0.000 claims description 9
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 8
229920000877 Melamine resin Polymers 0.000 claims description 8
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 8
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
238000001035 drying Methods 0.000 claims description 5
125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
238000004132 cross linking Methods 0.000 claims description 2
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 2
229920000058 polyacrylate Polymers 0.000 claims 9
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 3
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 22
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 10
239000008367 deionised water Substances 0.000 description 8
229910021641 deionized water Inorganic materials 0.000 description 8
229920005989 resin Polymers 0.000 description 8
239000011347 resin Substances 0.000 description 8
239000002987 primer (paints) Substances 0.000 description 7
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 5
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 5
229920000728 polyester Polymers 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
229910000831 Steel Inorganic materials 0.000 description 4
238000005507 spraying Methods 0.000 description 4
239000010959 steel Substances 0.000 description 4
229920003270 Cymel® Polymers 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
229910001870 ammonium persulfate Inorganic materials 0.000 description 3
238000007590 electrostatic spraying Methods 0.000 description 3
239000000178 monomer Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
RPOTYPSPQZVIJY-UHFFFAOYSA-N 1-aminopentan-3-ol Chemical compound CCC(O)CCN RPOTYPSPQZVIJY-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
239000004593 Epoxy Substances 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
229920000180 alkyd Polymers 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
238000002156 mixing Methods 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 description 1
GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
229920006397 acrylic thermoplastic Polymers 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000000676 alkoxyimino group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
229920006020 amorphous polyamide Polymers 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229960002887 deanol Drugs 0.000 description 1
125000004386 diacrylate group Chemical group 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
239000012972 dimethylethanolamine Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000000975 dye Substances 0.000 description 1
238000004070 electrodeposition Methods 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
239000003822 epoxy resin Substances 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
150000007974 melamines Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
LKEDKQWWISEKSW-UHFFFAOYSA-N nonyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCOC(=O)C(C)=C LKEDKQWWISEKSW-UHFFFAOYSA-N 0.000 description 1
MDYPDLBFDATSCF-UHFFFAOYSA-N nonyl prop-2-enoate Chemical compound CCCCCCCCCOC(=O)C=C MDYPDLBFDATSCF-UHFFFAOYSA-N 0.000 description 1
NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
229940065472 octyl acrylate Drugs 0.000 description 1
ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
239000012860 organic pigment Substances 0.000 description 1
150000002917 oxazolidines Chemical class 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
230000002335 preservative effect Effects 0.000 description 1
239000013615 primer Substances 0.000 description 1
QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
235000015096 spirit Nutrition 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
150000003673 urethanes Chemical class 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Landscapes

Application Of Or Painting With Fluid Materials (AREA)

CA000553472A 1986-09-11 1987-12-03 Procede permettant d'ameliorer l'aspect d'un fini multicouche Expired - Lifetime CA1309791C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000553472A CA1309791C (fr)	1986-09-11	1987-12-03	Procede permettant d'ameliorer l'aspect d'un fini multicouche

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/906,195 US4731290A (en)	1986-09-11	1986-09-11	Process for improving the appearance of a multilayer finish
CA000553472A CA1309791C (fr)	1986-09-11	1987-12-03	Procede permettant d'ameliorer l'aspect d'un fini multicouche

Publications (1)

Publication Number	Publication Date
CA1309791C true CA1309791C (fr)	1992-11-03

Family

ID=25671616

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000553472A Expired - Lifetime CA1309791C (fr)	1986-09-11	1987-12-03	Procede permettant d'ameliorer l'aspect d'un fini multicouche

Country Status (1)

Country	Link
CA (1)	CA1309791C (fr)

1987
- 1987-12-03 CA CA000553472A patent/CA1309791C/fr not_active Expired - Lifetime

Legal Events

Date	Code	Title	Description
1995-05-03	MKLA	Lapsed

Publication	Publication Date	Title
US4731290A (en)	1988-03-15	Process for improving the appearance of a multilayer finish
US5397646A (en)	1995-03-14	Waterbased coating compositions of methylol(meth)acrylamide acrylic polymer, polyurethane and melamine crosslinking agent
US5104922A (en)	1992-04-14	Stable aqueous aluminum flake dispersion
US4954559A (en)	1990-09-04	Waterbased methylol (meth) acrylamide acrylic polymer and polyurethane containing coating composition
US5266406A (en)	1993-11-30	Waterbased methylol (meth)acrylamide acrylic polymer and an acrylic hydrosol coating composition
EP0320552A1 (fr)	1989-06-21	Procédé d'amélioration de l'apparence d'un revêtement multicouche
CA2062302C (fr)	2003-07-29	Couche de base en suspension aqueuse et finition transparente a haute teneur en solides pour substrats automobiles a apparence amelioree
US5006413A (en)	1991-04-09	Waterbased methylol (meth)acrylamide acrylic polymer and polyurethane containing coating composition
US4849480A (en)	1989-07-18	Crosslinked polymer microparticle
US4147674A (en)	1979-04-03	Aqueous coating composition of an acrylic-vinyl oxazoline ester polymer
US20090136729A1 (en)	2009-05-28	Method of forming brilliant multi-layered coating film
KR19980703484A (ko)	1998-11-05	복층 도막 형성방법
JPH0160512B2 (fr)	1989-12-22
US5219916A (en)	1993-06-15	Waterbased methylol (meth)acrylamide acrylic polymer and an acrylic hydrosol coating composition
JPH0625566A (ja)	1994-02-01	非常に微細なマイカを含む非メタリック塗料組成物
JPH0739557B2 (ja)	1995-05-01	コーティング組成物用レオロジーコントロール剤
JPS6123225B2 (fr)	1986-06-04
JP4896299B2 (ja)	2012-03-14	光輝性塗料組成物、塗膜形成方法および塗装物
JPS5819353B2 (ja)	1983-04-18	メタリック塗装仕上げ方法
JP2001072933A (ja)	2001-03-21	光輝性塗料組成物、塗膜形成方法及び複層塗膜
DE19655104A1 (de)	1999-07-29	Aerosolgrundierbeschichtungszusammensetzung sowie ihre Verwendung zur Beschichtung von Kunststoffsubstraten
JP2002233815A (ja)	2002-08-20	光輝性塗膜形成方法および塗装物
JPH01171682A (ja)	1989-07-06	多層仕上げ塗りの外観を改良する方法
JP2000288465A (ja)	2000-10-17	自動車ボディの塗装法
JPH06212119A (ja)	1994-08-02	水をベースとしたアクリルシラン及びポリウレタンを含有するコーティング組成物