CA1310145C - Flottation de minerais et agents de flottation de mineraux utilises a cette fin - Google Patents

Flottation de minerais et agents de flottation de mineraux utilises a cette fin

Info

Publication number: CA1310145C
Authority: CA; Canada
Prior art keywords: employed; mineral; mercaptan; tricyclodecenyl; flotation
Prior art date: 1988-12-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000606500A

Other languages

English (en)

Inventor

Kenneth B. Kimble

Gary D. Macdonell

Harold Wayne Mark

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Phillips Petroleum Co

Original Assignee

Phillips Petroleum Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-12-19

Filing date

1989-07-24

Publication date

1992-11-10

1989-07-24 Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co

1992-11-10 Application granted granted Critical

1992-11-10 Publication of CA1310145C publication Critical patent/CA1310145C/fr

2009-11-10 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 109
239000011707 mineral Substances 0.000 title claims abstract description 109
239000008396 flotation agent Substances 0.000 title claims abstract description 64
238000005188 flotation Methods 0.000 title claims description 30
238000000034 method Methods 0.000 claims abstract description 78
230000008569 process Effects 0.000 claims abstract description 69
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 21
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims abstract description 18
239000012141 concentrate Substances 0.000 claims abstract description 18
229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 18
150000001875 compounds Chemical class 0.000 claims abstract description 16
238000011084 recovery Methods 0.000 claims abstract description 13
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 46
VTXVGVNLYGSIAR-UHFFFAOYSA-N decane-1-thiol Chemical compound CCCCCCCCCCS VTXVGVNLYGSIAR-UHFFFAOYSA-N 0.000 claims description 24
239000010931 gold Substances 0.000 claims description 19
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 15
229910052737 gold Inorganic materials 0.000 claims description 15
238000009291 froth flotation Methods 0.000 claims description 14
239000007787 solid Substances 0.000 claims description 12
229910052751 metal Inorganic materials 0.000 claims description 11
239000002184 metal Substances 0.000 claims description 11
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 10
239000003795 chemical substances by application Substances 0.000 claims description 7
238000006243 chemical reaction Methods 0.000 claims description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
239000000203 mixture Substances 0.000 description 14
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 12
239000002002 slurry Substances 0.000 description 12
235000008504 concentrate Nutrition 0.000 description 10
239000002270 dispersing agent Substances 0.000 description 9
239000011701 zinc Substances 0.000 description 9
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
230000001143 conditioned effect Effects 0.000 description 8
229910052725 zinc Inorganic materials 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
239000011734 sodium Substances 0.000 description 7
229910052708 sodium Inorganic materials 0.000 description 7
229910052742 iron Inorganic materials 0.000 description 6
239000012989 trithiocarbonate Substances 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
229920001451 polypropylene glycol Polymers 0.000 description 5
-1 dithiophosphates Chemical class 0.000 description 4
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
VLDHWMAJBNWALQ-UHFFFAOYSA-M sodium;1,3-benzothiazol-3-ide-2-thione Chemical compound [Na+].C1=CC=C2SC([S-])=NC2=C1 VLDHWMAJBNWALQ-UHFFFAOYSA-M 0.000 description 3
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
229910052932 antlerite Inorganic materials 0.000 description 2
229910052972 bournonite Inorganic materials 0.000 description 2
229910052951 chalcopyrite Inorganic materials 0.000 description 2
DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 2
229910000365 copper sulfate Inorganic materials 0.000 description 2
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
229910052949 galena Inorganic materials 0.000 description 2
239000000463 material Substances 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
229910052976 metal sulfide Inorganic materials 0.000 description 2
229910052961 molybdenite Inorganic materials 0.000 description 2
CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
239000010944 silver (metal) Substances 0.000 description 2
229910052950 sphalerite Inorganic materials 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
HIZCIEIDIFGZSS-UHFFFAOYSA-L trithiocarbonate Chemical compound [S-]C([S-])=S HIZCIEIDIFGZSS-UHFFFAOYSA-L 0.000 description 2
229910000442 triuranium octoxide Inorganic materials 0.000 description 2
241001120493 Arene Species 0.000 description 1
229910015369 AuTe Inorganic materials 0.000 description 1
108091005950 Azurite Proteins 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229920002907 Guar gum Polymers 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
241000907663 Siproeta stelenes Species 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
229910052948 bornite Inorganic materials 0.000 description 1
229910052933 brochantite Inorganic materials 0.000 description 1
229910052947 chalcocite Inorganic materials 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
PTVDYARBVCBHSL-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu] PTVDYARBVCBHSL-UHFFFAOYSA-N 0.000 description 1
LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 1
239000012990 dithiocarbamate Substances 0.000 description 1
150000004659 dithiocarbamates Chemical class 0.000 description 1
229910052971 enargite Inorganic materials 0.000 description 1
239000008394 flocculating agent Substances 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
239000000665 guar gum Substances 0.000 description 1
229960002154 guar gum Drugs 0.000 description 1
235000010417 guar gum Nutrition 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000009533 lab test Methods 0.000 description 1
XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005065 mining Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
229910052903 pyrophyllite Inorganic materials 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
SRYYCRXKYKWXDQ-PTGKCMAJSA-N success Chemical compound O([C@H]1CCC[C@@H](OC(=O)C[C@H]2[C@@H]3C=C[C@@H]4C[C@H](C[C@H]4[C@@H]3C=C2C(=O)[C@@H]1C)O[C@H]1[C@@H]([C@H](OC)[C@@H](OC)[C@H](C)C1)OC)CC)[C@H]1CC[C@H](N(C)C)[C@@H](C)O1 SRYYCRXKYKWXDQ-PTGKCMAJSA-N 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229910052969 tetrahedrite Inorganic materials 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
GWBUNZLLLLDXMD-UHFFFAOYSA-H tricopper;dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[O-]C([O-])=O.[O-]C([O-])=O GWBUNZLLLLDXMD-UHFFFAOYSA-H 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical group [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000012991 xanthate Substances 0.000 description 1
229910000010 zinc carbonate Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/025—Precious metal ores

Landscapes

Manufacture And Refinement Of Metals (AREA)

CA000606500A 1988-12-19 1989-07-24 Flottation de minerais et agents de flottation de mineraux utilises a cette fin Expired - Lifetime CA1310145C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/286,343		1988-12-19
US07/286,343 US4857179A (en)	1988-12-19	1988-12-19	Ore flotation and mineral flotation agents for use therein

Publications (1)

Publication Number	Publication Date
CA1310145C true CA1310145C (fr)	1992-11-10

Family

ID=23098172

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000606500A Expired - Lifetime CA1310145C (fr)	1988-12-19	1989-07-24	Flottation de minerais et agents de flottation de mineraux utilises a cette fin

Country Status (2)

Country	Link
US (1)	US4857179A (fr)
CA (1)	CA1310145C (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4966688A (en) *	1988-06-23	1990-10-30	Phillips Petroleum Company	Ore flotation employing amino mercaptothiadiazoles
US7757864B2 (en) *	2004-06-15	2010-07-20	M-I L.L.C.	Screen assembly designed to conform to the radius of vibrating shakers with crowned decks
US9447481B1 (en)	2015-10-07	2016-09-20	Chevron Phillips Chemical Company Lp	Dipentene dimercaptan compositions and use thereof as a mining chemical collector
US20170282193A1 (en) *	2016-04-05	2017-10-05	Chevron Phillips Chemical Company Lp	Mercaptanized Dicyclopentadiene Compositions and Use Thereof as a Mining Chemical Collector
US9539587B1 (en) *	2016-04-05	2017-01-10	Chevron Phillips Chemical Company Lp	Mercaptanized dicyclopentadiene compositions and use thereof as a mining chemical collector
WO2025144839A1 (fr)	2023-12-27	2025-07-03	Arkema Inc.	Compositions de polysulfure et procédés de séparation de minerais

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3025327A (en) *	1959-03-30	1962-03-13	Standard Oil Co	Mercapto-7, 3alpha, 4, 7, 7alpha-pentahydro-4, 7-methanoindenes
US3538044A (en) *	1967-08-11	1970-11-03	Pennwalt Corp	Dimercaptan derivatives as synergists for polyolefin stabilization
SU1068173A1 (ru) *	1982-08-03	1984-01-23	Yakimenko Petr M	Собиратель дл флотации полиметаллических руд
US4601818A (en) *	1983-03-30	1986-07-22	Phillips Petroleum Company	Ore flotation
US4622131A (en) *	1985-04-30	1986-11-11	Phillips Petroleum Company	Ore flotation

1988
- 1988-12-19 US US07/286,343 patent/US4857179A/en not_active Expired - Fee Related
1989
- 1989-07-24 CA CA000606500A patent/CA1310145C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
US4857179A (en)	1989-08-15

Legal Events

Date	Code	Title	Description
1997-11-10	MKLA	Lapsed
2023-05-26	MKLA	Lapsed	Effective date: 19971110

Publication	Publication Date	Title
CA1270076A (fr)	1990-06-05	Capteurs pour la flottation selective sur mousse de minerais sulfures
US5074994A (en)	1991-12-24	Sequential and selective flotation of sulfide ores
US4022686A (en)	1977-05-10	Flotation process for copper ores and copper smelter slags
US4684459A (en)	1987-08-04	Collector compositions for the froth flotation of mineral values
US4582596A (en)	1986-04-15	Frothers demonstrating enhanced recovery of coarse particles in froth floatation
US5074993A (en)	1991-12-24	Flotation process
EP0174866A2 (fr)	1986-03-19	Collecteurs pour la flottation à mousse de minérais enrichis
US4554108A (en)	1985-11-19	Alkali carboxyalkyl dithiocarbamates and use as ore flotation reagents
US3464551A (en)	1969-09-02	Dialkyl dithiocarbamates as collectors in froth flotation
US4439314A (en)	1984-03-27	Flotation reagents
US5126038A (en)	1992-06-30	Process for improved precious metals recovery from ores with the use of alkylhydroxamate collectors
US4514293A (en)	1985-04-30	Ore flotation and flotation agents for use therein
US4601818A (en)	1986-07-22	Ore flotation
US2310240A (en)	1943-02-09	Flotation of ores
CA1310145C (fr)	1992-11-10	Flottation de minerais et agents de flottation de mineraux utilises a cette fin
US4702821A (en)	1987-10-27	Ore flotation and di-alkali metal-di(carboxyalkyl)dithiocarbamate and diammonium-di(carboxyalkyl)dithiocarbamate flotation agents for use therein
US4295962A (en)	1981-10-20	Recovering copper by flotation using N-mercaptoalkyl amide depressant
US4793852A (en)	1988-12-27	Process for the recovery of non-ferrous metal sulfides
CA2428121C (fr)	2010-05-04	Collecteur pour la precession de sulfures de metaux non-ferreux
US4595538A (en)	1986-06-17	Tri-alkali metal-di(carboxyalkyl)dithiocarbamate and triammonium-di(carboxyalkyl)dithiocarbamate flotation agents
US4676890A (en)	1987-06-30	Collector compositions for the froth flotation of mineral values
US3827557A (en)	1974-08-06	Method of copper sulfide ore flotation
CA2066426A1 (fr)	1991-12-16	Procede de flottation utilisant des carbamates
US4533467A (en)	1985-08-06	Ore flotation and flotation agents for use therein
US4702822A (en)	1987-10-27	Novel collector composition for froth flotation