CA1312842C - Extraction par champ alternatif du metal noble contenu dans de la boue de minerais - Google Patents
Extraction par champ alternatif du metal noble contenu dans de la boue de mineraisInfo
- Publication number
- CA1312842C CA1312842C CA000517940A CA517940A CA1312842C CA 1312842 C CA1312842 C CA 1312842C CA 000517940 A CA000517940 A CA 000517940A CA 517940 A CA517940 A CA 517940A CA 1312842 C CA1312842 C CA 1312842C
- Authority
- CA
- Canada
- Prior art keywords
- gold
- noble metal
- ore
- dissolution
- lixiviant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 17
- 239000002002 slurry Substances 0.000 title claims abstract description 13
- 238000000605 extraction Methods 0.000 title description 8
- 239000010931 gold Substances 0.000 claims abstract description 60
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 53
- 229910052737 gold Inorganic materials 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000007800 oxidant agent Substances 0.000 claims abstract description 34
- 230000001590 oxidative effect Effects 0.000 claims abstract description 21
- 230000005684 electric field Effects 0.000 claims abstract description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 48
- 239000011780 sodium chloride Substances 0.000 claims description 24
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea group Chemical group NC(=S)N UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 20
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical group [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 abstract description 36
- 238000002386 leaching Methods 0.000 abstract description 19
- 239000000243 solution Substances 0.000 description 32
- 230000003647 oxidation Effects 0.000 description 25
- 238000007254 oxidation reaction Methods 0.000 description 25
- 238000013019 agitation Methods 0.000 description 21
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 20
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 17
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 9
- 235000019270 ammonium chloride Nutrition 0.000 description 9
- 239000011324 bead Substances 0.000 description 8
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 8
- 238000011084 recovery Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 229910015400 FeC13 Inorganic materials 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- MNWBNISUBARLIT-UHFFFAOYSA-N sodium cyanide Chemical compound [Na+].N#[C-] MNWBNISUBARLIT-UHFFFAOYSA-N 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 241000487918 Acacia argyrodendron Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000011222 chang cao shi Nutrition 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001527806 Iti Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- FRHBOQMZUOWXQL-UHFFFAOYSA-L ammonium ferric citrate Chemical compound [NH4+].[Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FRHBOQMZUOWXQL-UHFFFAOYSA-L 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229960004642 ferric ammonium citrate Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000000011 iron ammonium citrate Nutrition 0.000 description 1
- 239000004313 iron ammonium citrate Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/045—Leaching using electrochemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPH02367 | 1985-09-10 | ||
| AUPH236785 | 1985-09-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1312842C true CA1312842C (fr) | 1993-01-19 |
Family
ID=3771269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000517940A Expired - Fee Related CA1312842C (fr) | 1985-09-10 | 1986-09-10 | Extraction par champ alternatif du metal noble contenu dans de la boue de minerais |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4980134A (fr) |
| CN (1) | CN1008446B (fr) |
| AU (1) | AU585390B2 (fr) |
| BR (1) | BR8604310A (fr) |
| CA (1) | CA1312842C (fr) |
| GB (1) | GB2181452B (fr) |
| MY (1) | MY101543A (fr) |
| NZ (1) | NZ217504A (fr) |
| PH (1) | PH21188A (fr) |
| ZA (1) | ZA866798B (fr) |
| ZW (1) | ZW18286A1 (fr) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH672925A5 (fr) * | 1988-09-19 | 1990-01-15 | Hana Dr Sc Nat Frauenknecht | |
| MY105658A (en) * | 1989-03-07 | 1994-11-30 | Butler Dean R | Noble metal recovery |
| GB8914037D0 (en) * | 1989-06-19 | 1989-08-09 | Univ Cardiff | Dissolving values of platinum group metals from ores and concentrates |
| NZ237011A (en) * | 1990-02-23 | 1992-06-25 | Cra Services | Extraction and recovery of gold by treatment with an acidic lixiviant solution |
| US5114687A (en) * | 1990-12-14 | 1992-05-19 | South Dakota School Of Mines & Technology | Ammonia extraction of gold and silver from ores and other materials |
| US5328669A (en) * | 1993-01-26 | 1994-07-12 | South Dakota School Of Mines And Technology | Extraction of precious metals from ores and other precious metal containing materials using halogen salts |
| US5308381A (en) * | 1993-04-15 | 1994-05-03 | South Dakota School Of Mines & Techology | Ammonia extraction of gold and silver from ores and other materials |
| US5542957A (en) * | 1995-01-27 | 1996-08-06 | South Dakota School Of Mines And Technology | Recovery of platinum group metals and rhenium from materials using halogen reagents |
| RU2121517C1 (ru) * | 1998-01-29 | 1998-11-10 | Карманников Владимир Павлович | Способ извлечения и разделения платины и палладия |
| GB2349876B (en) * | 1999-05-10 | 2003-03-05 | Rio Tinto Technology Dev Ltd | Process for the Recovery of Noble Metals |
| US6660059B2 (en) * | 2000-05-19 | 2003-12-09 | Placer Dome Technical Services Limited | Method for thiosulfate leaching of precious metal-containing materials |
| US7722840B2 (en) | 2002-11-15 | 2010-05-25 | Placer Dome Technical Services Limited | Method for thiosulfate leaching of precious metal-containing materials |
| US20040237721A1 (en) * | 2003-05-29 | 2004-12-02 | Morteza Baghalha | Anoxic leaching of precious metals with thiosulfate and precious metal oxidants |
| WO2006113284A2 (fr) * | 2005-04-13 | 2006-10-26 | Metals Recovery Technology Inc. | Processus de recuperation de metaux du groupe des platineux, de rhenium et d'or |
| US7964015B2 (en) * | 2007-05-23 | 2011-06-21 | Contact Marketing Solutions, Llc | Metal extraction without cyanide |
| RU2394109C1 (ru) * | 2009-01-11 | 2010-07-10 | Закрытое Акционерное Общество "Уралкалий-Технология" | Способ сорбционного извлечения благородных металлов |
| CN101818258B (zh) * | 2010-05-10 | 2011-07-06 | 梁伟基 | 一种混合浸出剂快速浸出金银的方法 |
| EP2576850B1 (fr) * | 2010-06-01 | 2015-03-04 | Voldemars Belakovs | Procédé de récupération de métaux nobles et d'autres sous-produits à partir d'un minerai |
| WO2012076981A1 (fr) | 2010-12-07 | 2012-06-14 | Barrick Gold Corporation | Résine en lixiviation à co-courant et à contre-courant dans des procédés de lixiviation d'or |
| AR086933A1 (es) | 2011-06-15 | 2014-01-29 | Barrick Gold Corp | Metodo para recuperar metales preciosos y cobre de soluciones de lixiviado |
| CN103103348B (zh) * | 2012-12-31 | 2014-10-29 | 长沙铂鲨环保设备有限公司 | 一种类卤化合物的应用 |
| US8931642B2 (en) | 2013-01-14 | 2015-01-13 | William D. Simmons | Activated flotation circuit for processing combined oxide and sulfide ores |
| RU2540236C2 (ru) * | 2013-05-07 | 2015-02-10 | Федеральное государственное бюджетное учреждение науки Институт химии Дальневосточного отделения Российской академии наук (ИХ ДВО РАН) | Способ переработки высокоуглеродистых золотоносных пород |
| US10161016B2 (en) | 2013-05-29 | 2018-12-25 | Barrick Gold Corporation | Method for pre-treatment of gold-bearing oxide ores |
| CN103937975B (zh) * | 2014-03-25 | 2016-09-14 | 陕西锌业有限公司 | 从湿法炼锌浮选银精矿中直接提取银的方法 |
| WO2015175251A1 (fr) | 2014-05-12 | 2015-11-19 | Summit Mining International Inc. | Procédé de lixiviation de saumure pour la récupération de métaux de valeur à partir de matériaux oxydés |
| US11993826B2 (en) | 2018-05-15 | 2024-05-28 | Hycroft Mining Holding Corporation | Alkaline oxidation methods and systems for recovery of metals from ores |
| PE20211512A1 (es) | 2019-01-21 | 2021-08-11 | Barrick Gold Corp | Metodo para la lixiviacion con tiosulfato catalizado con carbon de materiales que contienen oro |
| CN111809063B (zh) | 2019-04-12 | 2021-10-22 | 上海师范大学 | 一种光催化金属溶解方法 |
| EP3967661B1 (fr) * | 2020-09-09 | 2023-07-26 | Northvolt AB | Procédé de préparation de solutions de sulfate de métal de qualité de batterie |
| CN118028904B (zh) * | 2024-01-12 | 2024-10-18 | 武汉理工大学 | 一种硫代硫酸盐电化学氧化浸出贵金属的方法 |
| CN117887977B (zh) * | 2024-01-12 | 2024-10-18 | 武汉理工大学 | 一种电化学氧化选择性分步浸出电子废弃物中Au、Ag的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2761829A (en) * | 1951-06-29 | 1956-09-04 | Norman H Dolloff | Polarization prevention in electrolysis of sulfide ores |
| US3957601A (en) * | 1974-05-17 | 1976-05-18 | Mineral Research & Development Corporation | Electrochemical mining |
| US4071278A (en) * | 1975-01-27 | 1978-01-31 | Carpenter Neil L | Leaching methods and apparatus |
| US4206024A (en) * | 1975-01-27 | 1980-06-03 | Darrell G. Lochte | Electrochemical leaching methods |
| US4139432A (en) * | 1976-08-16 | 1979-02-13 | Ghiringhelli Hugh A | Process for electrochemically recovering precious metals from ores |
| US4128462A (en) * | 1976-08-16 | 1978-12-05 | Ghiringhelli Hugh A | Electrochemical process for recovering precious metals from their ores |
| US4204922A (en) * | 1977-12-06 | 1980-05-27 | The Broken Hill Propietary Company Limited | Simultaneous electrodissolution and electrowinning of metals from simple sulphides |
| IT1228590B (it) * | 1982-08-05 | 1991-06-24 | Dextec Metallurg | Procedimento per il recupero di argento e oro dai minerali e dai loro concentrati |
| ZA84929B (en) * | 1983-02-22 | 1984-09-26 | Sueddeutsche Kalkstickstoff | Hydrometallurgical recovery of noble metals using thiourea |
| AU2534984A (en) * | 1983-03-02 | 1984-09-06 | Shepherdson Building Pty. Ltd. | Recovery of gold electrolytically from pulp |
-
1986
- 1986-09-03 PH PH34212A patent/PH21188A/en unknown
- 1986-09-03 ZW ZW182/86A patent/ZW18286A1/xx unknown
- 1986-09-03 GB GB8621306A patent/GB2181452B/en not_active Expired
- 1986-09-08 ZA ZA866798A patent/ZA866798B/xx unknown
- 1986-09-09 BR BR8604310A patent/BR8604310A/pt unknown
- 1986-09-09 CN CN86106986A patent/CN1008446B/zh not_active Expired
- 1986-09-09 NZ NZ217504A patent/NZ217504A/xx unknown
- 1986-09-09 AU AU62523/86A patent/AU585390B2/en not_active Ceased
- 1986-09-09 US US06/905,690 patent/US4980134A/en not_active Expired - Fee Related
- 1986-09-10 CA CA000517940A patent/CA1312842C/fr not_active Expired - Fee Related
-
1987
- 1987-02-04 MY MYPI87000089A patent/MY101543A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NZ217504A (en) | 1988-08-30 |
| CN86106986A (zh) | 1987-08-05 |
| GB8621306D0 (en) | 1986-10-15 |
| CN1008446B (zh) | 1990-06-20 |
| AU585390B2 (en) | 1989-06-15 |
| US4980134A (en) | 1990-12-25 |
| PH21188A (en) | 1987-08-12 |
| GB2181452A (en) | 1987-04-23 |
| GB2181452B (en) | 1989-06-07 |
| MY101543A (en) | 1991-12-17 |
| ZW18286A1 (en) | 1987-05-27 |
| BR8604310A (pt) | 1987-05-05 |
| AU6252386A (en) | 1987-03-12 |
| ZA866798B (en) | 1987-05-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |