CA1312986C - Thermoformable vinylidene chloride resin composition and resin laminate comprising this resin composition - Google Patents

Thermoformable vinylidene chloride resin composition and resin laminate comprising this resin composition

Info

Publication number: CA1312986C
Authority: CA; Canada
Prior art keywords: weight; resin; vinylidene chloride; chloride resin; resin composition
Prior art date: 1986-09-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000546132A

Other languages

English (en)

French (fr)

Inventor

Muneki Yamada

Fumio Kano

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Toyo Seikan Group Holdings Ltd

Original Assignee

Toyo Seikan Kaisha Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-09-05

Filing date

1987-09-04

Publication date

1993-01-19

1987-09-04 Application filed by Toyo Seikan Kaisha Ltd filed Critical Toyo Seikan Kaisha Ltd

1993-01-19 Application granted granted Critical

1993-01-19 Publication of CA1312986C publication Critical patent/CA1312986C/en

2010-01-19 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229920005989 resin Polymers 0.000 title claims abstract description 132
239000011347 resin Substances 0.000 title claims abstract description 132
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 title claims abstract description 69
239000011342 resin composition Substances 0.000 title claims abstract description 50
239000004014 plasticizer Substances 0.000 claims abstract description 49
150000003016 phosphoric acids Chemical class 0.000 claims abstract description 33
239000000178 monomer Substances 0.000 claims abstract description 21
238000003856 thermoforming Methods 0.000 claims abstract description 17
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
125000005395 methacrylic acid group Chemical group 0.000 claims abstract description 10
229920005992 thermoplastic resin Polymers 0.000 claims abstract description 10
239000010410 layer Substances 0.000 claims description 53
229920001577 copolymer Polymers 0.000 claims description 25
-1 fatty acid ester Chemical class 0.000 claims description 20
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 18
239000005977 Ethylene Substances 0.000 claims description 18
229910052783 alkali metal Inorganic materials 0.000 claims description 9
239000004593 Epoxy Substances 0.000 claims description 8
HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 claims description 8
239000002253 acid Substances 0.000 claims description 8
238000000034 method Methods 0.000 claims description 8
229920001155 polypropylene Polymers 0.000 claims description 7
125000005396 acrylic acid ester group Chemical group 0.000 claims description 6
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
239000000155 melt Substances 0.000 claims description 6
239000002245 particle Substances 0.000 claims description 6
229920000728 polyester Polymers 0.000 claims description 6
230000008569 process Effects 0.000 claims description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 5
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
239000012790 adhesive layer Substances 0.000 claims description 5
235000014113 dietary fatty acids Nutrition 0.000 claims description 5
239000000194 fatty acid Substances 0.000 claims description 5
229930195729 fatty acid Natural products 0.000 claims description 5
125000005397 methacrylic acid ester group Chemical group 0.000 claims description 5
239000000843 powder Substances 0.000 claims description 5
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
239000003549 soybean oil Substances 0.000 claims description 5
235000012424 soybean oil Nutrition 0.000 claims description 5
240000006240 Linum usitatissimum Species 0.000 claims description 4
235000004431 Linum usitatissimum Nutrition 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 4
239000004359 castor oil Substances 0.000 claims description 4
235000019438 castor oil Nutrition 0.000 claims description 4
CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 claims description 4
235000004426 flaxseed Nutrition 0.000 claims description 4
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
IIGMITQLXAGZTL-UHFFFAOYSA-N octyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCC IIGMITQLXAGZTL-UHFFFAOYSA-N 0.000 claims description 4
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 claims description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
239000004698 Polyethylene Substances 0.000 claims description 3
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
125000004122 cyclic group Chemical group 0.000 claims description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
229920000573 polyethylene Polymers 0.000 claims description 3
229920001634 Copolyester Polymers 0.000 claims description 2
239000004822 Hot adhesive Substances 0.000 claims description 2
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 2
229910019142 PO4 Inorganic materials 0.000 claims description 2
239000004952 Polyamide Substances 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 claims description 2
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
229920000554 ionomer Polymers 0.000 claims description 2
125000002560 nitrile group Chemical group 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims description 2
229920002647 polyamide Polymers 0.000 claims description 2
229920000515 polycarbonate Polymers 0.000 claims description 2
239000004417 polycarbonate Substances 0.000 claims description 2
229920005672 polyolefin resin Polymers 0.000 claims description 2
QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims 3
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims 2
235000011180 diphosphates Nutrition 0.000 claims 2
235000019832 sodium triphosphate Nutrition 0.000 claims 2
229920001169 thermoplastic Polymers 0.000 claims 2
239000004416 thermosoftening plastic Substances 0.000 claims 2
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 2
GIXFALHDORQSOQ-UHFFFAOYSA-J 2,4,6,8-tetraoxido-1,3,5,7,2$l^{5},4$l^{5},6$l^{5},8$l^{5}-tetraoxatetraphosphocane 2,4,6,8-tetraoxide Chemical compound [O-]P1(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])(=O)O1 GIXFALHDORQSOQ-UHFFFAOYSA-J 0.000 claims 1
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims 1
AZSFNUJOCKMOGB-UHFFFAOYSA-K cyclotriphosphate(3-) Chemical group [O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 AZSFNUJOCKMOGB-UHFFFAOYSA-K 0.000 claims 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
229940005740 hexametaphosphate Drugs 0.000 claims 1
238000005979 thermal decomposition reaction Methods 0.000 abstract description 11
238000004806 packaging method and process Methods 0.000 abstract description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 42
239000000853 adhesive Substances 0.000 description 13
230000001070 adhesive effect Effects 0.000 description 13
229920001328 Polyvinylidene chloride Polymers 0.000 description 11
239000005033 polyvinylidene chloride Substances 0.000 description 11
150000003839 salts Chemical class 0.000 description 10
238000005187 foaming Methods 0.000 description 9
239000005022 packaging material Substances 0.000 description 8
239000000203 mixture Substances 0.000 description 7
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
239000004743 Polypropylene Substances 0.000 description 6
238000002845 discoloration Methods 0.000 description 6
238000001125 extrusion Methods 0.000 description 6
238000000465 moulding Methods 0.000 description 5
230000009467 reduction Effects 0.000 description 5
238000000354 decomposition reaction Methods 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000004816 latex Substances 0.000 description 4
229920000126 latex Polymers 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
238000011282 treatment Methods 0.000 description 4
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
238000000071 blow moulding Methods 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
230000006866 deterioration Effects 0.000 description 3
229910001882 dioxygen Inorganic materials 0.000 description 3
239000007789 gas Substances 0.000 description 3
230000035699 permeability Effects 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
230000001954 sterilising effect Effects 0.000 description 3
238000004383 yellowing Methods 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
230000004888 barrier function Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
229920006026 co-polymeric resin Polymers 0.000 description 2
238000007033 dehydrochlorination reaction Methods 0.000 description 2
239000012760 heat stabilizer Substances 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
229910000041 hydrogen chloride Inorganic materials 0.000 description 2
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
238000004898 kneading Methods 0.000 description 2
238000003475 lamination Methods 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N n-Decanedioic acid Natural products OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000006722 reduction reaction Methods 0.000 description 2
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
238000004659 sterilization and disinfection Methods 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
GIXFALHDORQSOQ-UHFFFAOYSA-N 2,4,6,8-tetrahydroxy-1,3,5,7,2$l^{5},4$l^{5},6$l^{5},8$l^{5}-tetraoxatetraphosphocane 2,4,6,8-tetraoxide Chemical class OP1(=O)OP(O)(=O)OP(O)(=O)OP(O)(=O)O1 GIXFALHDORQSOQ-UHFFFAOYSA-N 0.000 description 1
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
ZJZJKRFYHSRMNR-UHFFFAOYSA-N Cl[C]=C Chemical compound Cl[C]=C ZJZJKRFYHSRMNR-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
BDJRBEYXGGNYIS-UHFFFAOYSA-N Nonanedioid acid Natural products OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
235000019485 Safflower oil Nutrition 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000004840 adhesive resin Substances 0.000 description 1
229920006223 adhesive resin Polymers 0.000 description 1
230000002411 adverse Effects 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
AZSFNUJOCKMOGB-UHFFFAOYSA-N cyclotriphosphoric acid Chemical class OP1(=O)OP(O)(=O)OP(O)(=O)O1 AZSFNUJOCKMOGB-UHFFFAOYSA-N 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000002156 mixing Methods 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
229920000137 polyphosphoric acid Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
229940099402 potassium metaphosphate Drugs 0.000 description 1
229940005657 pyrophosphoric acid Drugs 0.000 description 1
239000003813 safflower oil Substances 0.000 description 1
235000005713 safflower oil Nutrition 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
235000019983 sodium metaphosphate Nutrition 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
241000894007 species Species 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2327/00—Polyvinylhalogenides
- B32B2327/06—PVC, i.e. polyvinylchloride
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/008—Additives improving gas barrier properties

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Laminated Bodies (AREA)
Compositions Of Macromolecular Compounds (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CA000546132A 1986-09-05 1987-09-04 Thermoformable vinylidene chloride resin composition and resin laminate comprising this resin composition Expired - Fee Related CA1312986C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP61208005A JPS6363738A (ja)	1986-09-05	1986-09-05	熱成形性塩化ビニリデン樹脂組成物
JP208005/86		1986-09-05

Publications (1)

Publication Number	Publication Date
CA1312986C true CA1312986C (en)	1993-01-19

Family

ID=16549093

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000546132A Expired - Fee Related CA1312986C (en)	1986-09-05	1987-09-04	Thermoformable vinylidene chloride resin composition and resin laminate comprising this resin composition

Country Status (7)

Country	Link
US (1)	US5084500A (de)
EP (1)	EP0281634B1 (de)
JP (2)	JPS6363738A (de)
AU (1)	AU600977B2 (de)
CA (1)	CA1312986C (de)
DE (1)	DE3786455T2 (de)
WO (1)	WO1988001632A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0403542B1 (de) *	1988-03-07	1996-10-16	The Dow Chemical Company	Formulierungspaket zur extrusion von vinylidenchloridinterpolymerisaten und dieses paket enthaltende polyvinylidenchloridzusammensetzung
ATE115985T1 (de) *	1988-10-07	1995-01-15	Atochem North America	Stabilisierungsmittel für halogenhaltige polymere.
US5030511A (en) *	1989-06-09	1991-07-09	W. R. Grace & Co.-Conn.	Extruded vinylidene chloride copolymer flexible packaging film
US5002989A (en) *	1989-09-01	1991-03-26	The Dow Chemical Company	Formulation for extrudable vinylidene chloride copolymers having high barrier properties
US5187369A (en) *	1990-10-01	1993-02-16	General Electric Company	High sensitivity, high resolution, solid state x-ray imaging device with barrier layer
NZ244002A (en) *	1991-08-23	1996-03-26	Grace W R & Co	Extrudable composition containing plasticiser, acrylate/styrene polymer and vinylidene chloride copolymer; multilayer polymeric films
US5202188A (en) *	1991-08-23	1993-04-13	W. R. Grace & Co.-Conn.	Vinylidene chloride film
CA2104625A1 (en) *	1992-12-17	1994-06-18	Cryovac, Inc.	Extrudable vinylidene chloride polymeric film
US5342910A (en) *	1992-12-18	1994-08-30	The Dow Chemical Company	Process for preparing vinylidene chloride or vinyl chloride polymer by suspension polymerization
US5538770A (en) *	1994-11-18	1996-07-23	W. R. Grace & Co. -Conn.	Vinylidene chloride film with controlled gas permeability
US5679465A (en) *	1995-10-03	1997-10-21	W. R. Grace & Co.-Conn.	Vinylidene chloride composition and film with high thermal stability
JP5356785B2 (ja) *	2008-11-19	2013-12-04	旭化成ケミカルズ株式会社	多層フィルム、シート及びバッグ
FR2957351B1 (fr) *	2010-03-10	2013-06-28	Solvay	Composition a base de copolymere du chlorure de vinylidene
CN103590577B (zh) *	2013-11-21	2015-10-21	无锡合众信息科技有限公司	一种复合地坪材料
AU2017215884B2 (en) *	2016-02-05	2019-04-18	Asahi Kasei Kabushiki Kaisha	Cylindrical molded article, barrier plug, and container with barrier plug
WO2017135450A1 (ja) *	2016-02-05	2017-08-10	株式会社細川洋行	バリア口栓及びバリア口栓付容器
JP6999384B2 (ja) *	2017-11-30	2022-01-18	株式会社クレハ	塩化ビニリデン系樹脂フィルム、それを用いた充填包装体、及びその製造方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2477612A (en) *	1948-06-28	1949-08-02	Dow Chemical Co	Vinylidene chloride-vinyl chloride copolymer composition for making shrinkable, translucent films
NL129981C (de) *	1966-03-26
DE1794175A1 (de) *	1967-09-21	1971-10-21	Dow Chemical Co	Polyvinylidenchloridmasse
US3908070A (en) *	1972-04-24	1975-09-23	Dow Chemical Co	Multilayer thermoplastic barrier structure
JPS5222676B2 (de) *	1973-08-28	1977-06-18
JPS5120212B2 (de) *	1973-10-09	1976-06-23
JPS584736B2 (ja) *	1975-12-22	1983-01-27	旭化成株式会社	エンカビニリデンケイキヨウジユウゴウタイジユシノアンテイカソセイブツ
US4127633A (en) *	1976-04-21	1978-11-28	Imperial Chemical Industries Limited	Process for fabricating biaxially oriented container of polyethylene terephthalate coated with a copolymer of vinylidene chloride
US4132691A (en) *	1977-04-06	1979-01-02	M&T Chemical Inc.	Lubricant composition for vinyl chloride polymers
JPS586699B2 (ja) *	1978-10-06	1983-02-05	出光興産株式会社	セツコウ成形体
JPS55127454A (en) *	1979-03-27	1980-10-02	Asahi Chem Ind Co Ltd	Stabilization of vinylidene chloride resin
JPS58116149A (ja) *	1981-12-29	1983-07-11	呉羽化学工業株式会社	熱収縮性積層フイルム
US4418168A (en) *	1982-03-18	1983-11-29	The Dow Chemical Company	Process for imparting stability to particulate vinylidene chloride polymer resins
JPS59190845A (ja) *	1983-04-13	1984-10-29	呉羽化学工業株式会社	耐熱性塩化ビニリデン樹脂積層体
JPS61120719A (ja) *	1984-11-16	1986-06-07	Asahi Chem Ind Co Ltd	溶融押出法を用いた塩化ビニリデン−メチルアクリレ−ト系共重合体の成形加工方法

1986
- 1986-09-05 JP JP61208005A patent/JPS6363738A/ja active Granted
1987
- 1987-09-04 CA CA000546132A patent/CA1312986C/en not_active Expired - Fee Related
- 1987-09-04 US US07/210,583 patent/US5084500A/en not_active Expired - Fee Related
- 1987-09-04 EP EP87905790A patent/EP0281634B1/de not_active Expired - Lifetime
- 1987-09-04 WO PCT/JP1987/000659 patent/WO1988001632A1/ja not_active Ceased
- 1987-09-04 DE DE87905790T patent/DE3786455T2/de not_active Expired - Fee Related
- 1987-09-04 AU AU79112/87A patent/AU600977B2/en not_active Ceased
1989
- 1989-12-21 JP JP1329606A patent/JPH02212142A/ja active Granted

Also Published As

Publication number	Publication date
AU7911287A (en)	1988-03-24
WO1988001632A1 (fr)	1988-03-10
JPS6363738A (ja)	1988-03-22
JPH031341B2 (de)	1991-01-10
EP0281634A4 (de)	1990-03-12
DE3786455D1 (de)	1993-08-12
US5084500A (en)	1992-01-28
DE3786455T2 (de)	1993-12-16
AU600977B2 (en)	1990-08-30
EP0281634B1 (de)	1993-07-07
EP0281634A1 (de)	1988-09-14
JPH02212142A (ja)	1990-08-23
JPH053980B2 (de)	1993-01-19

Legal Events

Date	Code	Title	Description
2004-01-19	MKLA	Lapsed

Publication	Publication Date	Title
EP0281634B1 (de)	1993-07-07	Durch wärme formbare vinylidenchlorid harzzusammensetzung und daraus erzeugtes laminat
US4244914A (en)	1981-01-13	Process for preparing gas-, vapor- and odor-proof coupled and coextruded multilayer articles of thermoplastic material and closed-surface bodies comprising the same
KR950013364B1 (ko)	1995-11-02	폴리비닐 알코올 제품 및 이를 함유하는 다층 제품
CA2499588C (en)	2010-09-14	Polypropylene containers
JP6602647B2 (ja)	2019-11-06	エチレン−ビニルアルコール共重合体を含む樹脂組成物、積層体及び成形品
JPH04270654A (ja)	1992-09-28	マット状外観を有するプラスチック容器
JPH11106592A (ja)	1999-04-20	樹脂組成物およびその積層体
JPWO2009084391A1 (ja)	2011-05-19	ポリプロピレン樹脂組成物、該樹脂組成物からなる成形体、及び該成形体の製造方法
US4352850A (en)	1982-10-05	Five-layered packaging film
US4921907A (en)	1990-05-01	Resin composition and multilayered structure
US4877662A (en)	1989-10-31	Vessel comprising resin composition
JP3978070B2 (ja)	2007-09-19	多層フィルムまたはシート
US5003002A (en)	1991-03-26	Blends of amorphous nylon and ethylene vinyl alcohol copolymers and laminates and containers made therefrom
EP3412596A1 (de)	2018-12-12	Mundbarrierestopper und behälter mit mundbarrierestopper
JP4082780B2 (ja)	2008-04-30	樹脂組成物の製造法
CA2050156C (en)	2004-07-13	Ma-pvdc formulations, films and structure which maintain high barrier properties after retorting
JP7399759B2 (ja)	2023-12-18	樹脂組成物及び積層フィルム並びに包装材料
JP7521889B2 (ja)	2024-07-24	樹脂組成物、その製造方法及びそれを用いた多層構造体
JP3329875B2 (ja)	2002-09-30	多層構造体
JPH01148551A (ja)	1989-06-09	プラスチックシート成形容器
JP4823405B2 (ja)	2011-11-24	樹脂組成物及びその製造方法、その用途
JPS6268743A (ja)	1987-03-28	多層プラスチツク容器及びその製法
JP2703477B2 (ja)	1998-01-26	有色食品収納用積層容器
JP2007216457A (ja)	2007-08-30	積層フィルム
JPH02299836A (ja)	1990-12-12	積層物