CA1314149C - Methodes de recuperation de valeurs d'arsenic dans des residus - Google Patents

Methodes de recuperation de valeurs d'arsenic dans des residus

Info

Publication number: CA1314149C
Authority: CA; Canada
Prior art keywords: arsenic; arsenic trioxide; particles; trioxide; values
Prior art date: 1987-12-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 554182

Other languages

English (en)

Inventor

Jaroslav R. Derka

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-12-11

Filing date

1987-12-11

Publication date

1993-03-09

1987-12-11 Application filed by Individual filed Critical Individual

1987-12-11 Priority to CA 554182 priority Critical patent/CA1314149C/fr

1993-03-09 Application granted granted Critical

1993-03-09 Publication of CA1314149C publication Critical patent/CA1314149C/fr

2010-03-09 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229910052785 arsenic Inorganic materials 0.000 title claims abstract description 69
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 title claims abstract description 69
238000000034 method Methods 0.000 title claims abstract description 61
239000002699 waste material Substances 0.000 title description 4
GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 claims abstract description 102
HJTAZXHBEBIQQX-UHFFFAOYSA-N 1,5-bis(chloromethyl)naphthalene Chemical compound C1=CC=C2C(CCl)=CC=CC2=C1CCl HJTAZXHBEBIQQX-UHFFFAOYSA-N 0.000 claims abstract description 64
238000001704 evaporation Methods 0.000 claims abstract description 18
239000000463 material Substances 0.000 claims abstract description 18
230000008020 evaporation Effects 0.000 claims abstract description 15
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 7
239000005864 Sulphur Substances 0.000 claims abstract description 7
238000011084 recovery Methods 0.000 claims abstract description 7
238000000926 separation method Methods 0.000 claims abstract description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
239000002245 particle Substances 0.000 claims description 20
239000011362 coarse particle Substances 0.000 claims description 18
238000002485 combustion reaction Methods 0.000 claims description 16
229930195733 hydrocarbon Natural products 0.000 claims description 16
150000002430 hydrocarbons Chemical class 0.000 claims description 16
239000004215 Carbon black (E152) Substances 0.000 claims description 15
238000001556 precipitation Methods 0.000 claims description 15
239000012530 fluid Substances 0.000 claims description 12
238000004519 manufacturing process Methods 0.000 claims description 10
239000007787 solid Substances 0.000 claims description 9
238000009835 boiling Methods 0.000 claims description 3
239000007789 gas Substances 0.000 description 33
239000000047 product Substances 0.000 description 13
239000000243 solution Substances 0.000 description 12
238000013459 approach Methods 0.000 description 10
238000001816 cooling Methods 0.000 description 8
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
238000005201 scrubbing Methods 0.000 description 6
RAHZWNYVWXNFOC-UHFFFAOYSA-N sulfur dioxide Inorganic materials O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
239000010970 precious metal Substances 0.000 description 5
150000004820 halides Chemical class 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 3
229910021529 ammonia Inorganic materials 0.000 description 3
239000000498 cooling water Substances 0.000 description 3
239000000428 dust Substances 0.000 description 3
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
229910052737 gold Inorganic materials 0.000 description 3
239000010931 gold Substances 0.000 description 3
238000002347 injection Methods 0.000 description 3
239000007924 injection Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000007670 refining Methods 0.000 description 3
229910052711 selenium Inorganic materials 0.000 description 3
239000011669 selenium Substances 0.000 description 3
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 3
235000010269 sulphur dioxide Nutrition 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
239000003929 acidic solution Substances 0.000 description 2
229910052787 antimony Inorganic materials 0.000 description 2
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000004140 cleaning Methods 0.000 description 2
239000013078 crystal Substances 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000012535 impurity Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
-1 platinum group metals Chemical class 0.000 description 2
239000002893 slag Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
239000004291 sulphur dioxide Substances 0.000 description 2
238000005406 washing Methods 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
238000003723 Smelting Methods 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
RHQKKJPJCHGKQO-UHFFFAOYSA-N [Cu+2].[O-][Cr]([O-])=O Chemical compound [Cu+2].[O-][Cr]([O-])=O RHQKKJPJCHGKQO-UHFFFAOYSA-N 0.000 description 1
RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical class [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
150000001495 arsenic compounds Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
UDRRLPGVCZOTQW-UHFFFAOYSA-N bismuth lead Chemical compound [Pb].[Bi] UDRRLPGVCZOTQW-UHFFFAOYSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003518 caustics Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000011109 contamination Methods 0.000 description 1
239000013058 crude material Substances 0.000 description 1
238000007599 discharging Methods 0.000 description 1
238000010410 dusting Methods 0.000 description 1
230000005611 electricity Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
229910001447 ferric ion Inorganic materials 0.000 description 1
239000003500 flue dust Substances 0.000 description 1
239000003546 flue gas Substances 0.000 description 1
238000009854 hydrometallurgy Methods 0.000 description 1
239000013072 incoming material Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
238000002386 leaching Methods 0.000 description 1
239000011133 lead Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000011505 plaster Substances 0.000 description 1
230000008092 positive effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
239000012716 precipitator Substances 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
238000012216 screening Methods 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
238000007738 vacuum evaporation Methods 0.000 description 1
239000002023 wood Substances 0.000 description 1
239000003171 wood protecting agent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B30/00—Obtaining antimony, arsenic or bismuth
- C22B30/04—Obtaining arsenic
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/16—Dry methods smelting of sulfides or formation of mattes with volatilisation or condensation of the metal being produced

Landscapes

Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Treating Waste Gases (AREA)

CA 554182 1987-12-11 1987-12-11 Methodes de recuperation de valeurs d'arsenic dans des residus Expired - Fee Related CA1314149C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA 554182 CA1314149C (fr)	1987-12-11	1987-12-11	Methodes de recuperation de valeurs d'arsenic dans des residus

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA 554182 CA1314149C (fr)	1987-12-11	1987-12-11	Methodes de recuperation de valeurs d'arsenic dans des residus

Publications (1)

Publication Number	Publication Date
CA1314149C true CA1314149C (fr)	1993-03-09

Family

ID=4137061

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 554182 Expired - Fee Related CA1314149C (fr)	1987-12-11	1987-12-11	Methodes de recuperation de valeurs d'arsenic dans des residus

Country Status (1)

Country	Link
CA (1)	CA1314149C (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2006042898A1 (fr) *	2004-10-22	2006-04-27	Outokumpu Technology Oyj	Procédé de retraitement de sous-produits oxydants contenant de l’arsenic
CN101587064B (zh) *	2009-06-09	2010-09-29	扬州高能新材料有限公司	高纯三氧化二砷含硫检测中的二氧化硫浓度检测方法
WO2018120406A1 (fr) *	2016-12-30	2018-07-05	焱鑫环保科技有限公司	Four de purification par sublimation de trioxyde d'arsenic à commande précise utilisant un alliage à bas point de fusion comme corps de flottaison
CN109502874A (zh) *	2018-11-16	2019-03-22	西北矿冶研究院	一种强化三氧化二砷蒸发结晶的装置及方法
CN111569903A (zh) *	2020-05-29	2020-08-25	常熟理工学院	一种直接利用砷钌矿制备钌基催化剂的方法及其产品和应用
CN114314657A (zh) *	2022-02-18	2022-04-12	郑州德凯科技有限公司	一种连续制备三氧化二砷的生产装置及方法

1987
- 1987-12-11 CA CA 554182 patent/CA1314149C/fr not_active Expired - Fee Related

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2006042898A1 (fr) *	2004-10-22	2006-04-27	Outokumpu Technology Oyj	Procédé de retraitement de sous-produits oxydants contenant de l’arsenic
EA011214B1 (ru) *	2004-10-22	2009-02-27	Ототек Оюй	Способ переработки оксидных побочных продуктов, содержащих мышьяк
CN101587064B (zh) *	2009-06-09	2010-09-29	扬州高能新材料有限公司	高纯三氧化二砷含硫检测中的二氧化硫浓度检测方法
WO2018120406A1 (fr) *	2016-12-30	2018-07-05	焱鑫环保科技有限公司	Four de purification par sublimation de trioxyde d'arsenic à commande précise utilisant un alliage à bas point de fusion comme corps de flottaison
CN109502874A (zh) *	2018-11-16	2019-03-22	西北矿冶研究院	一种强化三氧化二砷蒸发结晶的装置及方法
CN109502874B (zh) *	2018-11-16	2021-11-16	西北矿冶研究院	一种强化三氧化二砷蒸发结晶的装置及方法
CN111569903A (zh) *	2020-05-29	2020-08-25	常熟理工学院	一种直接利用砷钌矿制备钌基催化剂的方法及其产品和应用
CN114314657A (zh) *	2022-02-18	2022-04-12	郑州德凯科技有限公司	一种连续制备三氧化二砷的生产装置及方法
CN114314657B (zh) *	2022-02-18	2023-09-22	郑州德凯科技有限公司	一种连续制备三氧化二砷的生产装置及方法

Legal Events

Date	Code	Title	Description
2003-03-10	MKLA	Lapsed

Publication	Publication Date	Title
EP1179605B1 (fr)	2004-11-03	Procédé pour l'extraction du soufre de résidus de la lixiviation de minerais sulfureux par distillation et condensation
US5702500A (en)	1997-12-30	Integrated process for the recovery of metals and fused alumina from spent catalysts
US3677696A (en)	1972-07-18	Process for removal and recovery of mercury from gases
FI68864C (fi)	1985-11-11	Foerfarande foer tillvaratagning av grundaemnessvavel och vaerdemetaller
US3443991A (en)	1969-05-13	Process for pickling metal
US2039256A (en)	1936-04-28	Process of treating refinery sludges or slimes containing selenium and tellurium
US4497780A (en)	1985-02-05	Method and apparatus for removing arsenic from an arsenic-containing material
US5759503A (en)	1998-06-02	Method for the further purification of zinc oxide
CA1314149C (fr)	1993-03-09	Methodes de recuperation de valeurs d'arsenic dans des residus
JP2004523341A (ja)	2004-08-05	酸水溶液からヒ素を回収する方法
CN108179290B (zh)	2019-09-24	一种从酸泥中富集汞的方法
EP0244910B1 (fr)	1989-05-03	Séparation de métaux non ferreux de matières pulvérulentes contenant du fer
US4043822A (en)	1977-08-23	Treatment of water-soluble metal sulfate residues
CA1242864A (fr)	1988-10-11	Methode d'extraction du trioxyde d'arsenic, des gaz d'echappement resultant de la fusion des minerais
CA1177257A (fr)	1984-11-06	Methode de traitement des minerais de zinc sulfureux
Raghavan et al.	1999	Innovative hydrometallurgical processing technique for industrial zinc and manganese process residues
CA1109637A (fr)	1981-09-29	Purification du trichlorure de titanium
US3803288A (en)	1974-04-09	Recovery of sulfur and iron oxide from pyritic materials
CN112267025A (zh)	2021-01-26	一种从低品位失效氧化铝载体催化剂中提取钯的方法
US1916853A (en)	1933-07-04	Process of treating ores
JP4044981B2 (ja)	2008-02-06	廃酸からの不純物除去方法
US1940912A (en)	1933-12-26	Treatment of ores
US2785957A (en)	1957-03-19	Regeneration of pickling liquor
JP2536057B2 (ja)	1996-09-18	脱銅ドロスからのスズの回収方法
US2726140A (en)	1955-12-06	Production of chlorine and metal sulfates