CA1321448C - Assouplisseur en poudre - Google Patents

Assouplisseur en poudre

Info

Publication number: CA1321448C
Authority: CA; Canada
Prior art keywords: fabric softening; quaternary ammonium; clay; water; organic
Prior art date: 1986-04-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000534053A

Other languages

English (en)

Inventor

John A. Hockey

Ralph R. Sepulveda

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-04-11

Filing date

1987-04-07

Publication date

1993-08-24

1987-04-07 Application filed by Unilever PLC filed Critical Unilever PLC

1993-08-24 Application granted granted Critical

1993-08-24 Publication of CA1321448C publication Critical patent/CA1321448C/fr

2010-08-24 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000002245 particle Substances 0.000 title claims abstract description 41
239000004744 fabric Substances 0.000 title claims abstract description 39
239000000203 mixture Substances 0.000 claims abstract description 59
239000004927 clay Substances 0.000 claims abstract description 25
239000003599 detergent Substances 0.000 claims abstract description 23
150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 13
-1 quaternary ammonium ions Chemical class 0.000 claims description 24
239000011230 binding agent Substances 0.000 claims description 12
239000004094 surface-active agent Substances 0.000 claims description 11
150000001875 compounds Chemical class 0.000 claims description 8
235000014113 dietary fatty acids Nutrition 0.000 claims description 8
239000000194 fatty acid Substances 0.000 claims description 8
229930195729 fatty acid Natural products 0.000 claims description 8
150000003839 salts Chemical class 0.000 claims description 8
239000003945 anionic surfactant Substances 0.000 claims description 7
150000001450 anions Chemical class 0.000 claims description 7
125000005037 alkyl phenyl group Chemical group 0.000 claims description 6
150000004665 fatty acids Chemical class 0.000 claims description 6
150000001768 cations Chemical class 0.000 claims description 5
238000005342 ion exchange Methods 0.000 claims description 5
125000000129 anionic group Chemical group 0.000 claims description 4
125000004122 cyclic group Chemical group 0.000 claims description 4
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
229920000140 heteropolymer Polymers 0.000 claims description 3
239000000344 soap Substances 0.000 claims description 3
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
229910052901 montmorillonite Inorganic materials 0.000 claims description 2
OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical group CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 claims 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims 1
239000000843 powder Substances 0.000 abstract description 19
125000001453 quaternary ammonium group Chemical group 0.000 abstract description 8
230000003292 diminished effect Effects 0.000 abstract 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 24
238000009472 formulation Methods 0.000 description 21
REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
239000002585 base Substances 0.000 description 9
229920001223 polyethylene glycol Polymers 0.000 description 8
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical group CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 7
150000003254 radicals Chemical class 0.000 description 7
238000012360 testing method Methods 0.000 description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
239000000654 additive Substances 0.000 description 6
125000002091 cationic group Chemical group 0.000 description 6
239000000047 product Substances 0.000 description 6
239000011734 sodium Substances 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
ZITBHNVGLSVXEF-UHFFFAOYSA-N 2-[2-(16-methylheptadecoxy)ethoxy]ethanol Chemical compound CC(C)CCCCCCCCCCCCCCCOCCOCCO ZITBHNVGLSVXEF-UHFFFAOYSA-N 0.000 description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
229910052500 inorganic mineral Inorganic materials 0.000 description 5
239000000463 material Substances 0.000 description 5
238000000034 method Methods 0.000 description 5
239000011707 mineral Substances 0.000 description 5
125000004432 carbon atom Chemical group C* 0.000 description 4
239000013078 crystal Substances 0.000 description 4
238000004900 laundering Methods 0.000 description 4
229910021647 smectite Inorganic materials 0.000 description 4
239000000243 solution Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
238000005406 washing Methods 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
239000004902 Softening Agent Substances 0.000 description 3
239000002253 acid Substances 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
229910000323 aluminium silicate Inorganic materials 0.000 description 3
239000000440 bentonite Substances 0.000 description 3
229910000278 bentonite Inorganic materials 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
238000004140 cleaning Methods 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
238000009826 distribution Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
238000011156 evaluation Methods 0.000 description 3
239000008187 granular material Substances 0.000 description 3
239000003112 inhibitor Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
229910021645 metal ion Inorganic materials 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000002689 soil Substances 0.000 description 3
239000001993 wax Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
235000013162 Cocos nucifera Nutrition 0.000 description 2
244000060011 Cocos nucifera Species 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
150000001350 alkyl halides Chemical class 0.000 description 2
238000013459 approach Methods 0.000 description 2
239000007844 bleaching agent Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
239000000428 dust Substances 0.000 description 2
239000002979 fabric softener Substances 0.000 description 2
238000000227 grinding Methods 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
239000000391 magnesium silicate Substances 0.000 description 2
235000012243 magnesium silicates Nutrition 0.000 description 2
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
238000003801 milling Methods 0.000 description 2
125000004433 nitrogen atom Chemical group N* 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
159000000001 potassium salts Chemical class 0.000 description 2
230000008569 process Effects 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
238000005507 spraying Methods 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
VSJNUOJSWAEPLD-UHFFFAOYSA-N 2-(carboxymethoxy)-2-sulfobutanedioic acid Chemical compound OC(=O)COC(S(O)(=O)=O)(C(O)=O)CC(O)=O VSJNUOJSWAEPLD-UHFFFAOYSA-N 0.000 description 1
PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical class CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 1
235000018185 Betula X alpestris Nutrition 0.000 description 1
235000018212 Betula X uliginosa Nutrition 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
239000004368 Modified starch Substances 0.000 description 1
229920000881 Modified starch Polymers 0.000 description 1
101100270435 Mus musculus Arhgef12 gene Proteins 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
125000006177 alkyl benzyl group Chemical group 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000003957 anion exchange resin Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000002734 clay mineral Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000005538 encapsulation Methods 0.000 description 1
238000011067 equilibration Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
238000001914 filtration Methods 0.000 description 1
230000008570 general process Effects 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229910000271 hectorite Inorganic materials 0.000 description 1
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
125000001183 hydrocarbyl group Chemical group 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
230000006872 improvement Effects 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000011256 inorganic filler Substances 0.000 description 1
229910003475 inorganic filler Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
238000010412 laundry washing Methods 0.000 description 1
238000011068 loading method Methods 0.000 description 1
150000004668 long chain fatty acids Chemical class 0.000 description 1
230000001050 lubricating effect Effects 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
235000019426 modified starch Nutrition 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
229910000273 nontronite Inorganic materials 0.000 description 1
XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000002304 perfume Substances 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
235000019422 polyvinyl alcohol Nutrition 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000012545 processing Methods 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
230000004044 response Effects 0.000 description 1
238000012552 review Methods 0.000 description 1
229910000275 saponite Inorganic materials 0.000 description 1
229910000276 sauconite Inorganic materials 0.000 description 1
229940071207 sesquicarbonate Drugs 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000001117 sulphuric acid Substances 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
239000003760 tallow Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Landscapes

Detergent Compositions (AREA)

CA000534053A 1986-04-11 1987-04-07 Assouplisseur en poudre Expired - Fee Related CA1321448C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US85102686A	1986-04-11	1986-04-11
US851026		1986-04-11

Publications (1)

Publication Number	Publication Date
CA1321448C true CA1321448C (fr)	1993-08-24

Family

ID=25309760

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000534053A Expired - Fee Related CA1321448C (fr)	1986-04-11	1987-04-07	Assouplisseur en poudre

Country Status (5)

Country	Link
JP (1)	JPS62265400A (fr)
AU (1)	AU7114487A (fr)
BR (1)	BR8701700A (fr)
CA (1)	CA1321448C (fr)
ZA (1)	ZA872599B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3881329T3 (de) †	1987-10-19	2002-05-23	The Procter & Gamble Company, Cincinnati	Reinigungsmittel.
CA2004165C (fr) *	1988-12-21	1997-12-16	The Procter & Gamble Company	Composes de conditionnement de tissus
US5668073A (en) *	1991-11-06	1997-09-16	The Procter & Gamble Company	Detergent compounds with high activity cellulase and quaternary ammonium compounds
JP2974780B2 (ja) *	1992-02-18	1999-11-10	ザ、プロクター、エンド、ギャンブル、カンパニー	高活性セルラーゼと第四級アンモニウム化合物とを有する洗剤組成物

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3862058A (en) *	1972-11-10	1975-01-21	Procter & Gamble	Detergent compositions containing a smectite-type clay softening agent
LU71307A1 (fr) *	1974-11-18	1976-09-06
JPS5833915B2 (ja) *	1978-11-13	1983-07-22	ザ、プロクタ−、エンド、ギヤンブル、カンパニ−	繊維柔軟化作用を有する洗剤組成物
DE3271167D1 (en) *	1981-09-11	1986-06-19	Procter & Gamble	Fabric softening detergent additive products and use thereof in detergent compositions
GB8331823D0 (en) *	1983-11-29	1984-01-04	Procter & Gamble	Laundry compositions

1987
- 1987-04-07 CA CA000534053A patent/CA1321448C/fr not_active Expired - Fee Related
- 1987-04-07 AU AU71144/87A patent/AU7114487A/en not_active Abandoned
- 1987-04-10 BR BR8701700A patent/BR8701700A/pt unknown
- 1987-04-10 JP JP8857987A patent/JPS62265400A/ja active Pending
- 1987-04-10 ZA ZA872599A patent/ZA872599B/xx unknown

Also Published As

Publication number	Publication date
AU7114487A (en)	1987-10-15
BR8701700A (pt)	1988-01-12
JPS62265400A (ja)	1987-11-18
ZA872599B (en)	1988-12-28

Legal Events

Date	Code	Title	Description
1998-08-24	MKLA	Lapsed

Publication	Publication Date	Title
US3936537A (en)	1976-02-03	Detergent-compatible fabric softening and antistatic compositions
US4632768A (en)	1986-12-30	Clay fabric softener agglomerates
CA1130057A (fr)	1982-08-24	Assouplisseurs de tissus
US5019292A (en)	1991-05-28	Detergent compositions
US4536315A (en)	1985-08-20	Perfume-containing carrier having surface-modified particles for laundry composition
CA1137383A (fr)	1982-12-14	Detergent avec assouplisseur de tissus
CA1152263A (fr)	1983-08-23	Agents assouplissants et antistatique compatibles avec des detergents de lessive
US4758378A (en)	1988-07-19	Softening detergent compositions containing amide softening agent
CA1212504A (fr)	1986-10-14	Detergent-assouplisseur granule
CA1217005A (fr)	1987-01-27	Detergent avec agent d'assouplissement de tissus
CA1222356A (fr)	1987-06-02	Composition a l'argile modifiee en surface pour l'assouplissement des tissus
JP2520460B2 (ja)	1996-07-31	アミド成分を含有する洗剤プラス柔軟剤
AU661826B2 (en)	1995-08-10	Laundry detergent compositions containing crystalling/layeredsilicates
EP0297673B1 (fr)	1993-11-24	Compositions détergentes/assouplissantes contenant des argiles d'hectorite
US4764292A (en)	1988-08-16	Fabric-softening particles
US4524012A (en)	1985-06-18	Fabric softening and fluffing detergent composition
GB2170236A (en)	1986-07-30	Particulate fabric softening and antistatic built detergent composition and particulate agglomerate for use in manufacture thereof
CA1321448C (fr)	1993-08-24	Assouplisseur en poudre
EP0387426B1 (fr)	1996-10-02	Composition adoucissante textile contenant une argile hectorite naturelle
US5062972A (en)	1991-11-05	Fabric conditioning compositions: natural hectorite clay and binding and dispersing agent
IE60065B1 (en)	1994-06-01	Softening and bleaching detergent compositions containing amide softening agent
US4806253A (en)	1989-02-21	Laundry compositions
GB2207144A (en)	1989-01-25	Detergent compositions comprising a softening clay and an amphoteric material
NZ222531A (en)	1990-11-27	Detergent compositions with amides/sulphonamides
NZ212083A (en)	1988-01-08	Built synthetic anionic detergent composition containing polyacetal carboxylate