CA1322703C - Detergent pour laveuse automatique a haute teneur en carbonate et inhibant les depots de sels de calcium - Google Patents

Detergent pour laveuse automatique a haute teneur en carbonate et inhibant les depots de sels de calcium

Info

Publication number: CA1322703C
Authority: CA; Canada
Prior art keywords: acid; alkali; composition; group; sodium
Prior art date: 1988-10-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000600710A

Other languages

English (en)

Inventor

William L. Smith

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Clorox Co

Original Assignee

Clorox Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-10-12

Filing date

1989-05-25

Publication date

1993-10-05

1989-05-25 Application filed by Clorox Co filed Critical Clorox Co

1993-10-05 Application granted granted Critical

1993-10-05 Publication of CA1322703C publication Critical patent/CA1322703C/fr

2010-10-05 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 23
238000004851 dishwashing Methods 0.000 title claims abstract description 9
159000000007 calcium salts Chemical class 0.000 title description 7
230000008021 deposition Effects 0.000 title description 5
230000003247 decreasing effect Effects 0.000 title description 2
239000000203 mixture Substances 0.000 claims abstract description 44
239000002253 acid Substances 0.000 claims abstract description 28
239000011575 calcium Substances 0.000 claims abstract description 28
239000004094 surface-active agent Substances 0.000 claims abstract description 28
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 23
229910052791 calcium Inorganic materials 0.000 claims abstract description 23
238000005187 foaming Methods 0.000 claims abstract description 21
239000003112 inhibitor Substances 0.000 claims abstract description 17
239000003795 chemical substances by application Substances 0.000 claims abstract description 15
229910000288 alkali metal carbonate Inorganic materials 0.000 claims abstract description 14
150000008041 alkali metal carbonates Chemical class 0.000 claims abstract description 14
238000004061 bleaching Methods 0.000 claims abstract description 12
229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 11
238000004140 cleaning Methods 0.000 claims abstract description 4
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 43
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 28
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
-1 aliphatic alcohols Chemical class 0.000 claims description 16
229910019142 PO4 Inorganic materials 0.000 claims description 14
235000021317 phosphate Nutrition 0.000 claims description 13
229910000029 sodium carbonate Inorganic materials 0.000 claims description 13
238000005406 washing Methods 0.000 claims description 13
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 12
239000000377 silicon dioxide Substances 0.000 claims description 12
239000004115 Sodium Silicate Substances 0.000 claims description 11
YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 11
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 11
235000012239 silicon dioxide Nutrition 0.000 claims description 11
229920002125 Sokalan® Polymers 0.000 claims description 10
229910052681 coesite Inorganic materials 0.000 claims description 10
229920001577 copolymer Polymers 0.000 claims description 10
229910052906 cristobalite Inorganic materials 0.000 claims description 10
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 10
229910052682 stishovite Inorganic materials 0.000 claims description 10
229910052905 tridymite Inorganic materials 0.000 claims description 10
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
229910052911 sodium silicate Inorganic materials 0.000 claims description 9
238000000034 method Methods 0.000 claims description 8
239000007844 bleaching agent Substances 0.000 claims description 7
230000002401 inhibitory effect Effects 0.000 claims description 7
150000007942 carboxylates Chemical class 0.000 claims description 5
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 5
235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 5
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 4
125000002947 alkylene group Chemical group 0.000 claims description 4
150000002894 organic compounds Chemical class 0.000 claims description 4
239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 4
125000005270 trialkylamine group Chemical group 0.000 claims description 4
239000004584 polyacrylic acid Substances 0.000 claims description 3
SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 claims description 2
229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 2
239000007864 aqueous solution Substances 0.000 claims description 2
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims 4
UTCHNZLBVKHYKC-UHFFFAOYSA-N 2-hydroxy-2-phosphonoacetic acid Chemical compound OC(=O)C(O)P(O)(O)=O UTCHNZLBVKHYKC-UHFFFAOYSA-N 0.000 claims 3
239000013078 crystal Substances 0.000 claims 1
229910052816 inorganic phosphate Inorganic materials 0.000 claims 1
239000002736 nonionic surfactant Substances 0.000 claims 1
239000002689 soil Substances 0.000 abstract description 31
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 31
239000002244 precipitate Substances 0.000 abstract description 14
230000005764 inhibitory process Effects 0.000 abstract description 9
238000001556 precipitation Methods 0.000 abstract description 7
150000004965 peroxy acids Chemical class 0.000 abstract description 6
229910052736 halogen Inorganic materials 0.000 abstract description 5
150000002367 halogens Chemical class 0.000 abstract description 5
108090000790 Enzymes Proteins 0.000 abstract description 2
102000004190 Enzymes Human genes 0.000 abstract description 2
239000000975 dye Substances 0.000 abstract description 2
239000003205 fragrance Substances 0.000 abstract 1
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 19
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
239000011734 sodium Substances 0.000 description 19
229910052708 sodium Inorganic materials 0.000 description 19
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 14
230000000694 effects Effects 0.000 description 14
229920000642 polymer Polymers 0.000 description 13
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 11
235000017550 sodium carbonate Nutrition 0.000 description 11
235000019589 hardness Nutrition 0.000 description 10
150000003839 salts Chemical class 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
229920000058 polyacrylate Polymers 0.000 description 9
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
239000011574 phosphorus Substances 0.000 description 8
229910052698 phosphorus Inorganic materials 0.000 description 8
150000004760 silicates Chemical class 0.000 description 8
239000000243 solution Substances 0.000 description 8
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
239000011521 glass Substances 0.000 description 7
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
230000008901 benefit Effects 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
239000006260 foam Substances 0.000 description 6
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 6
239000000463 material Substances 0.000 description 6
239000000047 product Substances 0.000 description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
150000007513 acids Chemical class 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
229910000019 calcium carbonate Inorganic materials 0.000 description 5
150000004649 carbonic acid derivatives Chemical class 0.000 description 5
239000000945 filler Substances 0.000 description 5
239000011591 potassium Substances 0.000 description 5
229910052700 potassium Inorganic materials 0.000 description 5
241000894007 species Species 0.000 description 5
230000000007 visual effect Effects 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
229920002472 Starch Polymers 0.000 description 4
238000007792 addition Methods 0.000 description 4
238000005054 agglomeration Methods 0.000 description 4
230000002776 aggregation Effects 0.000 description 4
238000001035 drying Methods 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
235000013336 milk Nutrition 0.000 description 4
239000008267 milk Substances 0.000 description 4
210000004080 milk Anatomy 0.000 description 4
229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 4
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
239000003352 sequestering agent Substances 0.000 description 4
235000011152 sodium sulphate Nutrition 0.000 description 4
235000019832 sodium triphosphate Nutrition 0.000 description 4
239000008107 starch Substances 0.000 description 4
235000019698 starch Nutrition 0.000 description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
101710194948 Protein phosphatase PhpP Proteins 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
235000010216 calcium carbonate Nutrition 0.000 description 3
238000005260 corrosion Methods 0.000 description 3
230000007797 corrosion Effects 0.000 description 3
239000003792 electrolyte Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000011976 maleic acid Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
235000011962 puddings Nutrition 0.000 description 3
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 3
229910052938 sodium sulfate Inorganic materials 0.000 description 3
239000007787 solid Substances 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
240000001987 Pyrus communis Species 0.000 description 2
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
230000009471 action Effects 0.000 description 2
239000012190 activator Substances 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910000272 alkali metal oxide Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
230000004075 alteration Effects 0.000 description 2
239000008139 complexing agent Substances 0.000 description 2
CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 2
WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
239000012530 fluid Substances 0.000 description 2
125000001145 hydrido group Chemical class *[H] 0.000 description 2
JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000011368 organic material Substances 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
229920005646 polycarboxylate Polymers 0.000 description 2
235000011181 potassium carbonates Nutrition 0.000 description 2
235000011182 sodium carbonates Nutrition 0.000 description 2
229960001922 sodium perborate Drugs 0.000 description 2
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235000019351 sodium silicates Nutrition 0.000 description 2
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
239000007921 spray Substances 0.000 description 2
230000003068 static effect Effects 0.000 description 2
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
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VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
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BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
150000003949 imides Chemical class 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
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ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
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235000013310 margarine Nutrition 0.000 description 1
239000003264 margarine Substances 0.000 description 1
150000004972 metal peroxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000005395 methacrylic acid group Chemical class 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
LIQLLUGYBKEWRJ-UHFFFAOYSA-I pentasodium;2-phosphonatobutane-1,2,4-tricarboxylate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CCC(P([O-])([O-])=O)(C([O-])=O)CC([O-])=O LIQLLUGYBKEWRJ-UHFFFAOYSA-I 0.000 description 1
ZJAOAACCNHFJAH-UHFFFAOYSA-N phosphonoformic acid Chemical class OC(=O)P(O)(O)=O ZJAOAACCNHFJAH-UHFFFAOYSA-N 0.000 description 1
XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920001444 polymaleic acid Polymers 0.000 description 1
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical class [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
239000002243 precursor Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000010453 quartz Substances 0.000 description 1
238000009991 scouring Methods 0.000 description 1
208000022417 sinus histiocytosis with massive lymphadenopathy Diseases 0.000 description 1
229940047670 sodium acrylate Drugs 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
229910000162 sodium phosphate Inorganic materials 0.000 description 1
229960003339 sodium phosphate Drugs 0.000 description 1
235000011008 sodium phosphates Nutrition 0.000 description 1
SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical class [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
239000003643 water by type Substances 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

CA000600710A 1988-10-12 1989-05-25 Detergent pour laveuse automatique a haute teneur en carbonate et inhibant les depots de sels de calcium Expired - Fee Related CA1322703C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US25687588A	1988-10-12	1988-10-12
US256,875		1988-10-12

Publications (1)

Publication Number	Publication Date
CA1322703C true CA1322703C (fr)	1993-10-05

Family

ID=22973957

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000600710A Expired - Fee Related CA1322703C (fr)	1988-10-12	1989-05-25	Detergent pour laveuse automatique a haute teneur en carbonate et inhibant les depots de sels de calcium

Country Status (5)

Country	Link
EP (1)	EP0364067B1 (fr)
AT (1)	ATE133446T1 (fr)
CA (1)	CA1322703C (fr)
DE (1)	DE68925509T2 (fr)
ES (1)	ES2082776T3 (fr)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0598817B1 (fr) *	1991-08-13	1995-12-20	The Procter & Gamble Company	Procede de production d'un detergent granulaire de lavage automatique de vaiselle
US5281351A (en) *	1991-12-06	1994-01-25	Lever Brothers Company, Division Of Conopco, Inc.	Processes for incorporating anti-scalants in powdered detergent compositions
CA2161085C (fr) *	1993-04-27	2000-10-24	Eugene Steven Sadlowski	Detergent liquide ou en granules pour laveuses automatiques
WO1994025556A1 (fr) *	1993-04-27	1994-11-10	The Procter & Gamble Company	Compositions de detergent liquide ou granulaire pour lave-vaisselle
DE69413055T2 (de) *	1993-11-03	1999-05-06	The Procter & Gamble Co., Cincinnati, Ohio	Kalziumkarbonatabsetzungskontrolle in geschirrspuelmaschinen
EP0726935B1 (fr) *	1993-11-03	2000-08-30	The Procter & Gamble Company	Limitation de la precipitation de carbonate de calcium dans les lave-vaisselle
GB2285051A (en) *	1993-12-23	1995-06-28	Procter & Gamble	Rinse aid composition
GB2285052A (en) *	1993-12-23	1995-06-28	Procter & Gamble	Detergent composition
GB2285053A (en) *	1993-12-23	1995-06-28	Procter & Gamble	Rinse aid composition
FR2726002B1 (fr) *	1994-10-21	1997-01-17	Rhone Poulenc Chimie	Composition de builder sans zeolithes ni phostates comprenant un systeme diminuant les incrustations calciques, son utilisation dans des compositions detergentes et ces compositions detergentes
FR2732032B1 (fr) *	1995-03-20	1997-06-13	Rhone Poulenc Chimie	Composition d'adjuvant de detergence diminuant les incrustations calciques, son utilisation dans des compositions detergentes et ces compositions detergentes
FR2732033B1 (fr) *	1995-03-20	1997-04-30	Rhone Poulenc Chimie	Composition d'adjuvant de detergence diminuant les incrustations calciques, son utilisation dans des compositions detergentes et ces compositions detergentes
US6156715A (en) *	1997-01-13	2000-12-05	Ecolab Inc.	Stable solid block metal protecting warewashing detergent composition
US6177392B1 (en) *	1997-01-13	2001-01-23	Ecolab Inc.	Stable solid block detergent composition
AU1273601A (en) *	1999-11-12	2001-05-30	Unilever Plc	Machine dish wash compositions
GB0502056D0 (en) *	2005-02-01	2005-03-09	Unilever Plc	Modified sodium carbonate carrier meterial
US20100197545A1 (en)	2009-01-30	2010-08-05	Ecolab USA	High alkaline detergent composition with enhanced scale control
FR3009831B1 (fr) *	2013-08-23	2015-09-04	Hlg Man	Composition plastique chargee en sulfate de sodium et carbonate de sodium
ES3058141T3 (en)	2017-06-26	2026-03-09	Ecolab Usa Inc	Method of warewashing comprising detergent compositions substantially free of polycarboxylic acid polymers
US20230106979A1 (en)	2020-02-28	2023-04-06	Conopco Inc., D/B/A Unilever	Dishwash detergent product
DE102022131906A1 (de)	2022-12-01	2024-06-06	Henkel Ag & Co. Kgaa	Geschirrspülmaschinenreiniger mit verbesserter Fettentfernung und zusätzlicher Kalkentfernung

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3579455A (en) *	1968-08-02	1971-05-18	Grace W R & Co	Machine dishwashing compositions containing sodium polyacrylate
US3627686A (en) *	1968-09-30	1971-12-14	Chemed Corp	Machine dishwashing compositions containing sodium polyacrylate and nta
US3925228A (en) *	1973-01-11	1975-12-09	Colgate Palmolive Co	Carbonate built detergents
GB1575094A (en) *	1977-03-24	1980-09-17	Pennwalt Corp	Detergent compositions
US4298493A (en) *	1979-10-04	1981-11-03	Colgate-Palmolive Company	Method for retarding gelation of bicarbonate-carbonate-silicate crutcher slurries
DE3447291A1 (de) *	1984-12-24	1986-06-26	Henkel KGaA, 4000 Düsseldorf	Phosphatfreies mittel fuer das maschinelle geschirrspuelen
US4608188A (en) *	1985-04-12	1986-08-26	Basf Corporation	Dishwashing composition
DE3644808A1 (de) *	1986-12-31	1988-07-14	Henkel Kgaa	Phosphatfreies waschmittel mit verringerter schaumneigung
GB8710290D0 (en) *	1987-04-30	1987-06-03	Unilever Plc	Preparation of granular detergent composition
GB8710291D0 (en) *	1987-04-30	1987-06-03	Unilever Plc	Preparation of granular detergent composition
DE3825858A1 (de) *	1988-07-29	1990-02-01	Henkel Kgaa	Phosphatarme buildersalzkombination

1989
- 1989-05-25 CA CA000600710A patent/CA1322703C/fr not_active Expired - Fee Related
- 1989-06-02 EP EP89305572A patent/EP0364067B1/fr not_active Expired - Lifetime
- 1989-06-02 DE DE68925509T patent/DE68925509T2/de not_active Expired - Fee Related
- 1989-06-02 ES ES89305572T patent/ES2082776T3/es not_active Expired - Lifetime
- 1989-06-02 AT AT89305572T patent/ATE133446T1/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
ATE133446T1 (de)	1996-02-15
DE68925509D1 (de)	1996-03-07
EP0364067A2 (fr)	1990-04-18
ES2082776T3 (es)	1996-04-01
EP0364067B1 (fr)	1996-01-24
EP0364067A3 (fr)	1991-01-30
DE68925509T2 (de)	1996-05-30

Legal Events

Date	Code	Title	Description
2000-10-05	MKLA	Lapsed

Publication	Publication Date	Title
CA1322703C (fr)	1993-10-05	Detergent pour laveuse automatique a haute teneur en carbonate et inhibant les depots de sels de calcium
EP0068721B1 (fr)	1986-08-20	Procédé pour laver les matières textiles et composition détergente à cet usage
US4203858A (en)	1980-05-20	Phosphate-free machine dishwashing composition
US5279756A (en)	1994-01-18	Non-phosphate machine dishwashing detergents
US3701735A (en)	1972-10-31	Automatic dishwashing compositions
US5152910A (en)	1992-10-06	Low-phosphate machine dishwashing detergents
US3764559A (en)	1973-10-09	Detergent compositions
CA2084172A1 (fr)	1993-06-07	Procede de preparation de compositions pour detergent en poudre
US5232622A (en)	1993-08-03	Chlorine-free machine dishwashing
US5205954A (en)	1993-04-27	Automatic dishwasher powder detergent composition
JPS6348399A (ja)	1988-03-01	ビルダ−としての珪酸ナトリウム並びにコ−ビルダ−及び活性塩素支持剤を含む食器具用洗剤
US4539144A (en)	1985-09-03	Dishwashing compositions with an anti-filming polymer
GB2234980A (en)	1991-02-20	Detergent composition for machine dishwashers
US5545348A (en)	1996-08-13	Non-Phosphate high carbonate machine dishwashing detergents containing maleic acid homopolymer
EP0423014B1 (fr)	1995-03-29	Composition détergente liquide non-aqueuse pour le lavage automatique de la vaisselle contenant deux systèmes de blanchiment
US5281352A (en)	1994-01-25	Low-phosphate machine dishwashing detergents
GB2149418A (en)	1985-06-12	Detergent bleaching composition
JP3383669B2 (ja)	2003-03-04	食器洗い機用無塩素洗剤組成物
EP0463802B1 (fr)	1998-09-09	Procédé pour prévention de l'incrustation sur le tissu
WO2000046329A1 (fr)	2000-08-10	Procede utilise pour laver la vaisselle et compositions connexes
EP0395186A2 (fr)	1990-10-31	Composition détergente pour machines à laver la vaisselle automatiques contenant un double système de blanchiment
JPH05132696A (ja)	1993-05-28	織物付着防止のための組成物及び方法
CA2031289A1 (fr)	1991-06-02	Composition de detergent en poudre pour lave-vaisselle
WO2001036576A1 (fr)	2001-05-25	Compositions pour machine lave-vaisselle
JPH11172281A (ja)	1999-06-29	硬表面用洗浄剤組成物