CA1323501C - Procede d'elimination des contaminants organiques presents dans un materiau solide - Google Patents

Procede d'elimination des contaminants organiques presents dans un materiau solide

Info

Publication number: CA1323501C
Authority: CA; Canada
Prior art keywords: solvent; contaminant; water; solids; hydrophobic
Prior art date: 1988-04-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 595425

Other languages

English (en)

Inventor

Werner Steiner

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-04-15

Filing date

1989-03-31

Publication date

1993-10-26

1988-04-15 Priority claimed from US07/181,943 external-priority patent/US4869825A/en

1989-03-31 Application filed by Individual filed Critical Individual

1993-10-26 Application granted granted Critical

1993-10-26 Publication of CA1323501C publication Critical patent/CA1323501C/fr

2010-10-26 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000007787 solid Substances 0.000 title claims abstract description 90
238000000034 method Methods 0.000 title claims abstract description 82
239000000356 contaminant Substances 0.000 title claims abstract description 71
230000008569 process Effects 0.000 title claims abstract description 66
239000002904 solvent Substances 0.000 claims abstract description 225
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 99
239000000203 mixture Substances 0.000 claims abstract description 45
238000002386 leaching Methods 0.000 claims abstract description 34
238000005202 decontamination Methods 0.000 claims abstract description 8
230000003588 decontaminative effect Effects 0.000 claims abstract description 8
230000002209 hydrophobic effect Effects 0.000 claims description 51
239000007788 liquid Substances 0.000 claims description 45
150000002894 organic compounds Chemical class 0.000 claims description 7
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 6
229910052939 potassium sulfate Inorganic materials 0.000 claims description 6
238000009835 boiling Methods 0.000 claims description 4
235000011151 potassium sulphates Nutrition 0.000 claims description 3
238000004064 recycling Methods 0.000 claims description 3
239000007864 aqueous solution Substances 0.000 claims description 2
FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims 1
239000011343 solid material Substances 0.000 claims 1
239000013049 sediment Substances 0.000 abstract description 97
239000002689 soil Substances 0.000 abstract description 48
150000003071 polychlorinated biphenyls Chemical class 0.000 abstract description 28
239000000463 material Substances 0.000 abstract description 5
239000012141 concentrate Substances 0.000 abstract description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 55
-1 Benzanthracene Nitropropane Chloronaphthalene o-Chlorophenol Cresols Chemical class 0.000 description 31
239000003350 kerosene Substances 0.000 description 22
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 21
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
238000005192 partition Methods 0.000 description 18
238000000605 extraction Methods 0.000 description 13
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
239000003208 petroleum Substances 0.000 description 12
238000011084 recovery Methods 0.000 description 12
239000000126 substance Substances 0.000 description 10
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
239000012266 salt solution Substances 0.000 description 9
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
150000003839 salts Chemical class 0.000 description 8
238000000926 separation method Methods 0.000 description 8
239000012223 aqueous fraction Substances 0.000 description 7
238000001179 sorption measurement Methods 0.000 description 7
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
230000008901 benefit Effects 0.000 description 6
238000011109 contamination Methods 0.000 description 6
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
239000008096 xylene Substances 0.000 description 6
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
230000006378 damage Effects 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
239000000575 pesticide Substances 0.000 description 5
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
238000013459 approach Methods 0.000 description 4
150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
238000004821 distillation Methods 0.000 description 4
239000012530 fluid Substances 0.000 description 4
229960004592 isopropanol Drugs 0.000 description 4
238000012545 processing Methods 0.000 description 4
OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 4
239000010802 sludge Substances 0.000 description 4
238000000638 solvent extraction Methods 0.000 description 4
150000003738 xylenes Chemical class 0.000 description 4
150000001335 aliphatic alkanes Chemical class 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
150000001348 alkyl chlorides Chemical class 0.000 description 3
230000007613 environmental effect Effects 0.000 description 3
235000019441 ethanol Nutrition 0.000 description 3
GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 3
XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
238000004817 gas chromatography Methods 0.000 description 3
239000003921 oil Substances 0.000 description 3
239000011877 solvent mixture Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
241001120493 Arene Species 0.000 description 2
FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 2
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
239000004606 Fillers/Extenders Substances 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
150000001500 aryl chlorides Chemical class 0.000 description 2
150000001555 benzenes Chemical class 0.000 description 2
KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
239000002894 chemical waste Substances 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
238000004140 cleaning Methods 0.000 description 2
SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
150000002013 dioxins Chemical class 0.000 description 2
238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
239000003344 environmental pollutant Substances 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000004009 herbicide Substances 0.000 description 2
CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
238000002955 isolation Methods 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
229940073584 methylene chloride Drugs 0.000 description 2
239000011707 mineral Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000002957 persistent organic pollutant Substances 0.000 description 2
150000002989 phenols Chemical class 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
229920005547 polycyclic aromatic hydrocarbon Chemical class 0.000 description 2
BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
239000013557 residual solvent Substances 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
229950011008 tetrachloroethylene Drugs 0.000 description 2
238000012546 transfer Methods 0.000 description 2
IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 2
239000002699 waste material Substances 0.000 description 2
239000002023 wood Substances 0.000 description 2
QMMOXUPEWRXHJS-HYXAFXHYSA-N (z)-pent-2-ene Chemical compound CC\C=C/C QMMOXUPEWRXHJS-HYXAFXHYSA-N 0.000 description 1
LHMBDJPDVRXCAH-UHFFFAOYSA-N 1,1-dichloroethane dichloromethane tetrachloromethane Chemical compound C(Cl)(Cl)(Cl)Cl.C(Cl)Cl.ClC(C)Cl LHMBDJPDVRXCAH-UHFFFAOYSA-N 0.000 description 1
BTAGRXWGMYTPBY-UHFFFAOYSA-N 1,2,3-trichloro-4-(2,3,4-trichlorophenyl)benzene Chemical compound ClC1=C(Cl)C(Cl)=CC=C1C1=CC=C(Cl)C(Cl)=C1Cl BTAGRXWGMYTPBY-UHFFFAOYSA-N 0.000 description 1
DXBHBZVCASKNBY-UHFFFAOYSA-N 1,2-Benz(a)anthracene Chemical compound C1=CC=C2C3=CC4=CC=CC=C4C=C3C=CC2=C1 DXBHBZVCASKNBY-UHFFFAOYSA-N 0.000 description 1
KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 1
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
FGTSJNHUENLOIR-UHFFFAOYSA-N 1,4-dioxane 2-hydroxyethyl acetate Chemical compound O1CCOCC1.C(C)(=O)OCCO FGTSJNHUENLOIR-UHFFFAOYSA-N 0.000 description 1
JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 1
OIAZSXOCVDLMPM-UHFFFAOYSA-N 1-chloronaphthalene;phenol Chemical compound OC1=CC=CC=C1.C1=CC=C2C(Cl)=CC=CC2=C1 OIAZSXOCVDLMPM-UHFFFAOYSA-N 0.000 description 1
JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 1
KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 1
OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
XXXFZKQPYACQLD-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl acetate Chemical compound CC(=O)OCCOCCO XXXFZKQPYACQLD-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 description 1
TXVHTIQJNYSSKO-UHFFFAOYSA-N BeP Natural products C1=CC=C2C3=CC=CC=C3C3=CC=CC4=CC=C1C2=C34 TXVHTIQJNYSSKO-UHFFFAOYSA-N 0.000 description 1
WUUIFKDEONKOJZ-UHFFFAOYSA-N C1(=CC=CC=C1)Cl.ClCCCCC Chemical compound C1(=CC=CC=C1)Cl.ClCCCCC WUUIFKDEONKOJZ-UHFFFAOYSA-N 0.000 description 1
POZDYQHFAKWGIJ-UHFFFAOYSA-N C1=CC=CC=C1.CCCCCCCCCCCCCCC Chemical compound C1=CC=CC=C1.CCCCCCCCCCCCCCC POZDYQHFAKWGIJ-UHFFFAOYSA-N 0.000 description 1
MPTDGOIIKMBPIW-UHFFFAOYSA-N C1CCCCCCC1.CCCCCCCCCCC Chemical compound C1CCCCCCC1.CCCCCCCCCCC MPTDGOIIKMBPIW-UHFFFAOYSA-N 0.000 description 1
SAMYWHPDHUIKOU-UHFFFAOYSA-N CC1=CC=CC=C1.O1CCOCC1.ClC(=C(Cl)Cl)Cl Chemical compound CC1=CC=CC=C1.O1CCOCC1.ClC(=C(Cl)Cl)Cl SAMYWHPDHUIKOU-UHFFFAOYSA-N 0.000 description 1
RDXJKTZSJDKGQJ-UHFFFAOYSA-N CC1CCCC1.C1CCCCCCC1.C1CCCCCC1.C1CCCCC1.C1CCCC1 Chemical compound CC1CCCC1.C1CCCCCCC1.C1CCCCCC1.C1CCCCC1.C1CCCC1 RDXJKTZSJDKGQJ-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
SSFMHFTZTHUYHQ-UHFFFAOYSA-N FC1=CC=CC=C1.C(CCC)Cl Chemical compound FC1=CC=CC=C1.C(CCC)Cl SSFMHFTZTHUYHQ-UHFFFAOYSA-N 0.000 description 1
239000004348 Glyceryl diacetate Substances 0.000 description 1
235000006173 Larrea tridentata Nutrition 0.000 description 1
244000073231 Larrea tridentata Species 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
QHCMKDJNWTVNTE-UHFFFAOYSA-N O1CCCC1.C(C(C)O)Cl.C(CO)Cl.C(C)(=O)OCCOCCO Chemical compound O1CCCC1.C(C(C)O)Cl.C(CO)Cl.C(C)(=O)OCCOCCO QHCMKDJNWTVNTE-UHFFFAOYSA-N 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
CRPUJAZIXJMDBK-UHFFFAOYSA-N Toxaphene Natural products C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000001502 aryl halides Chemical class 0.000 description 1
150000004074 biphenyls Chemical class 0.000 description 1
239000003990 capacitor Substances 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 1
239000000470 constituent Substances 0.000 description 1
239000006184 cosolvent Substances 0.000 description 1
229960002126 creosote Drugs 0.000 description 1
150000001896 cresols Chemical class 0.000 description 1
239000010730 cutting oil Substances 0.000 description 1
150000001924 cycloalkanes Chemical class 0.000 description 1
150000001925 cycloalkenes Chemical class 0.000 description 1
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
UQVAKAZDYWTNHO-UHFFFAOYSA-N decane dec-1-ene Chemical compound CCCCCCCCCC.CCCCCCCCC=C UQVAKAZDYWTNHO-UHFFFAOYSA-N 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000001784 detoxification Methods 0.000 description 1
150000004826 dibenzofurans Chemical class 0.000 description 1
229940117389 dichlorobenzene Drugs 0.000 description 1
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
229940043237 diethanolamine Drugs 0.000 description 1
UBPGILLNMDGSDS-UHFFFAOYSA-N diethylene glycol diacetate Chemical compound CC(=O)OCCOCCOC(C)=O UBPGILLNMDGSDS-UHFFFAOYSA-N 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
238000004710 electron pair approximation Methods 0.000 description 1
DFBKLUNHFCTMDC-GKRDHZSOSA-N endrin Chemical compound C([C@@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@@H]2[C@H]2[C@@H]1O2 DFBKLUNHFCTMDC-GKRDHZSOSA-N 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
LJWKFGGDMBPPAZ-UHFFFAOYSA-N ethoxyethane;toluene Chemical compound CCOCC.CC1=CC=CC=C1 LJWKFGGDMBPPAZ-UHFFFAOYSA-N 0.000 description 1
GFUIDHWFLMPAGY-UHFFFAOYSA-N ethyl 2-hydroxy-2-methylpropanoate Chemical compound CCOC(=O)C(C)(C)O GFUIDHWFLMPAGY-UHFFFAOYSA-N 0.000 description 1
VDONOVZEYUHCKE-UHFFFAOYSA-N ethyl 2-hydroxypropanoate;propan-2-yl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O.CC(C)OC(=O)C(C)O VDONOVZEYUHCKE-UHFFFAOYSA-N 0.000 description 1
239000000284 extract Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
JLYXXMFPNIAWKQ-UHFFFAOYSA-N gamma-hexachlorocyclohexane Natural products ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
235000019443 glyceryl diacetate Nutrition 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000000976 ink Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229960002809 lindane Drugs 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
KWKAKUADMBZCLK-UHFFFAOYSA-N methyl heptene Natural products CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
239000012046 mixed solvent Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
KJZCBDFGSHKRAR-UHFFFAOYSA-N naphthalene phenanthrene Chemical compound C1=CC=CC2=CC=CC=C21.C1=CC=C2C3=CC=CC=C3C=CC2=C1 KJZCBDFGSHKRAR-UHFFFAOYSA-N 0.000 description 1
OPJCFBWDYOBKSZ-UHFFFAOYSA-N octane 1,3-xylene Chemical compound CCCCCCCC.CC1=CC=CC(C)=C1 OPJCFBWDYOBKSZ-UHFFFAOYSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
XRWGUIJCLKVUML-UHFFFAOYSA-N pentane undecane Chemical compound CCCCC.CCCCCCCCCCC XRWGUIJCLKVUML-UHFFFAOYSA-N 0.000 description 1
239000012071 phase Substances 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
GWHJZXXIDMPWGX-UHFFFAOYSA-N pseudo-cymene Natural products CC1=CC=C(C)C(C)=C1 GWHJZXXIDMPWGX-UHFFFAOYSA-N 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000005060 rubber Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
239000011550 stock solution Substances 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000000057 synthetic resin Substances 0.000 description 1
OEJNXTAZZBRGDN-UHFFFAOYSA-N toxaphene Chemical compound ClC1C(Cl)C2(Cl)C(CCl)(CCl)C(=C)C1(Cl)C2(Cl)Cl OEJNXTAZZBRGDN-UHFFFAOYSA-N 0.000 description 1
238000003828 vacuum filtration Methods 0.000 description 1
210000000707 wrist Anatomy 0.000 description 1

Landscapes

Processing Of Solid Wastes (AREA)
Treatment Of Sludge (AREA)

CA 595425 1988-04-15 1989-03-31 Procede d'elimination des contaminants organiques presents dans un materiau solide Expired - Fee Related CA1323501C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/181,943 US4869825A (en)	1987-05-26	1988-04-15	Process for the removal of organic contaminants from solids
US181,943		1988-04-15

Publications (1)

Publication Number	Publication Date
CA1323501C true CA1323501C (fr)	1993-10-26

Family

ID=22666464

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 595425 Expired - Fee Related CA1323501C (fr)	1988-04-15	1989-03-31	Procede d'elimination des contaminants organiques presents dans un materiau solide

Country Status (1)

Country	Link
CA (1)	CA1323501C (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN116410720A (zh) *	2021-12-29	2023-07-11	中国石油天然气股份有限公司	一种低沸点高闪点无表面活性剂微乳液及其清洗油基岩屑的方法

1989
- 1989-03-31 CA CA 595425 patent/CA1323501C/fr not_active Expired - Fee Related

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN116410720A (zh) *	2021-12-29	2023-07-11	中国石油天然气股份有限公司	一种低沸点高闪点无表面活性剂微乳液及其清洗油基岩屑的方法

Legal Events

Date	Code	Title	Description
2003-10-27	MKLA	Lapsed

Publication	Publication Date	Title
US4869825A (en)	1989-09-26	Process for the removal of organic contaminants from solids
US4801384A (en)	1989-01-31	Process for the removal of organic contaminants from soils and sedimenta
US5055196A (en)	1991-10-08	Extraction process to remove pcbs from soil and sludge
AU610929B2 (en)	1991-05-30	Process for treatment of organic contaminants in solid or liquid phase waste
US4405448A (en)	1983-09-20	Process for removing halogenated aliphatic and aromatic compounds from petroleum products
US4662948A (en)	1987-05-05	On-site removal of PCB and dioxins from soils
Sikdar et al.	1998	Membrane technologies for remediating contaminated soils: a critical review
JPS6372391A (ja)	1988-04-02	浄化処理方法
Hall et al.	1990	An overview of solvent extraction treatment technologies
WO1989004221A1 (fr)	1989-05-18	Procede de decontamination de la terre
WO1995006527A1 (fr)	1995-03-09	Procede d'assechement et d'extraction par solvant de sols humides, de sediments et de boues contamines
US6207073B1 (en)	2001-03-27	Remediation of environmental contaminants using a metal and a sulfur-containing compound
Kilbane	1998	Extractability and subsequent biodegradation of PAHs from contaminated soil
US5242598A (en)	1993-09-07	Solid phase extraction
AU8003700A (en)	2001-04-23	A method to remediate soil using a surfactant of an alkenylsuccinic anhydride or acid reacted with an amine acid or salt of an amine acid
WO2007096891A1 (fr)	2007-08-30	Séparation simultanée de métaux lourds et de matières organiques présents dans le sol, dans de la boue ou dans des sédiments
US4975198A (en)	1990-12-04	Process for the removal of organic contaminants from soils and sediment
AU1190701A (en)	2001-04-23	A method to remediate soil using a surfactant of a salt of an acrylamidoalkanesulfonic acid-amine reaction product
CA1323501C (fr)	1993-10-26	Procede d'elimination des contaminants organiques presents dans un materiau solide
US5427688A (en)	1995-06-27	Decontamination of soil and other particulate matter
Sahle‐Demessie et al.	2000	Solvent extraction and soil washing treatment of contaminated soils from wood preserving sites: Bench‐scale studies
Meckes et al.	1992	Solvent extraction processes: a survey of systems in the SITE program
Martins et al.	1992	Hydrophobic expanded vermiculite as a cleaning agent for contaminated waters
Jackson	1999	Anticipating ground-water contamination by new technologies and chemicals: The case of chlorinated solvents in California
Jones	1992	The BEST® solvent extraction process treatment of soil, sediment, and sludges

CA1323501C - Procede d'elimination des contaminants organiques presents dans un materiau solide - Google Patents

Info

Links

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=22666464

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

Similar Documents

Legal Events