CA1325311C - Adjuvant du ciment - Google Patents

Adjuvant du ciment

Info

Publication number: CA1325311C
Authority: CA; Canada
Prior art keywords: cement; superplasticizer; cement composition; composition; copolymer
Prior art date: 1986-07-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000539923A

Other languages

English (en)

Inventor

Joseph Michael Daly

James Michael Gaidis

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co Conn

Original Assignee

WR Grace and Co Conn

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-07-01

Filing date

1987-06-17

Publication date

1993-12-14

1987-06-17 Application filed by WR Grace and Co Conn filed Critical WR Grace and Co Conn

1993-12-14 Application granted granted Critical

1993-12-14 Publication of CA1325311C publication Critical patent/CA1325311C/fr

2010-12-14 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000004568 cement Substances 0.000 title claims abstract description 127
239000000203 mixture Substances 0.000 claims abstract description 114
229920001577 copolymer Polymers 0.000 claims abstract description 44
229920000642 polymer Polymers 0.000 claims abstract description 26
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 21
-1 hydroxyalkyl acrylate Chemical compound 0.000 claims abstract description 14
239000002253 acid Substances 0.000 claims abstract description 11
229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 11
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 10
239000003513 alkali Substances 0.000 claims abstract description 6
229910052783 alkali metal Inorganic materials 0.000 claims abstract 3
239000008030 superplasticizer Substances 0.000 claims description 40
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 20
239000000463 material Substances 0.000 claims description 17
239000007787 solid Substances 0.000 claims description 16
GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims description 10
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 10
238000000034 method Methods 0.000 claims description 9
238000002156 mixing Methods 0.000 claims description 8
125000005907 alkyl ester group Chemical group 0.000 claims description 3
150000001340 alkali metals Chemical class 0.000 claims 2
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims 1
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims 1
QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims 1
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims 1
150000002148 esters Chemical class 0.000 claims 1
239000011396 hydraulic cement Substances 0.000 abstract description 4
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract description 3
239000000047 product Substances 0.000 description 13
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
230000003111 delayed effect Effects 0.000 description 9
239000000178 monomer Substances 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
238000006116 polymerization reaction Methods 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
239000004567 concrete Substances 0.000 description 6
239000002904 solvent Substances 0.000 description 6
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 5
239000011398 Portland cement Substances 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
230000001965 increasing effect Effects 0.000 description 5
239000000243 solution Substances 0.000 description 5
239000010874 unset cement Substances 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
239000003638 chemical reducing agent Substances 0.000 description 4
PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 3
VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
230000003993 interaction Effects 0.000 description 3
239000006072 paste Substances 0.000 description 3
239000004576 sand Substances 0.000 description 3
229940047670 sodium acrylate Drugs 0.000 description 3
238000012360 testing method Methods 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
SQAINHDHICKHLX-UHFFFAOYSA-N 1-naphthaldehyde Chemical compound C1=CC=C2C(C=O)=CC=CC2=C1 SQAINHDHICKHLX-UHFFFAOYSA-N 0.000 description 2
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
229920001732 Lignosulfonate Polymers 0.000 description 2
239000004793 Polystyrene Substances 0.000 description 2
239000012615 aggregate Substances 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000007859 condensation product Substances 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
150000004292 cyclic ethers Chemical class 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000005189 flocculation Methods 0.000 description 2
230000016615 flocculation Effects 0.000 description 2
IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 2
238000005227 gel permeation chromatography Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000004570 mortar (masonry) Substances 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
229920002223 polystyrene Polymers 0.000 description 2
239000011734 sodium Substances 0.000 description 2
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
235000019738 Limestone Nutrition 0.000 description 1
229920000877 Melamine resin Polymers 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
LDKDGDIWEUUXSH-UHFFFAOYSA-N Thymophthalein Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C LDKDGDIWEUUXSH-UHFFFAOYSA-N 0.000 description 1
238000002479 acid--base titration Methods 0.000 description 1
229940048053 acrylate Drugs 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
AGWMJKGGLUJAPB-UHFFFAOYSA-N aluminum;dicalcium;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Ca+2].[Ca+2].[Fe+3] AGWMJKGGLUJAPB-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 1
238000001354 calcination Methods 0.000 description 1
JHLNERQLKQQLRZ-UHFFFAOYSA-N calcium silicate Chemical compound [Ca+2].[Ca+2].[O-][Si]([O-])([O-])[O-] JHLNERQLKQQLRZ-UHFFFAOYSA-N 0.000 description 1
229910052918 calcium silicate Inorganic materials 0.000 description 1
235000012241 calcium silicate Nutrition 0.000 description 1
238000007707 calorimetry Methods 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
HOOWDPSAHIOHCC-UHFFFAOYSA-N dialuminum tricalcium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[Al+3].[Al+3].[Ca++].[Ca++].[Ca++] HOOWDPSAHIOHCC-UHFFFAOYSA-N 0.000 description 1
238000000502 dialysis Methods 0.000 description 1
BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
238000000227 grinding Methods 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
239000003999 initiator Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000006028 limestone Substances 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000000465 moulding Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
239000011970 polystyrene sulfonate Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000007870 radical polymerization initiator Substances 0.000 description 1
238000010526 radical polymerization reaction Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000000376 reactant Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
238000004448 titration Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
229910021534 tricalcium silicate Inorganic materials 0.000 description 1
235000019976 tricalcium silicate Nutrition 0.000 description 1
238000000108 ultra-filtration Methods 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
239000011800 void material Substances 0.000 description 1
239000003643 water by type Substances 0.000 description 1

Landscapes

Curing Cements, Concrete, And Artificial Stone (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA000539923A 1986-07-01 1987-06-17 Adjuvant du ciment Expired - Fee Related CA1325311C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US88084886A	1986-07-01	1986-07-01
US880,848		1986-07-01

Publications (1)

Publication Number	Publication Date
CA1325311C true CA1325311C (fr)	1993-12-14

Family

ID=25377251

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000539923A Expired - Fee Related CA1325311C (fr)	1986-07-01	1987-06-17	Adjuvant du ciment

Country Status (2)

Country	Link
JP (2)	JPS6339906A (fr)
CA (1)	CA1325311C (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1325311C (fr) *	1986-07-01	1993-12-14	W.R. Grace & Co.-Conn.	Adjuvant du ciment
JP5249138B2 (ja) *	2008-06-17	2013-07-31	花王株式会社	水硬性組成物用分散剤
JP5311910B2 (ja) *	2008-07-25	2013-10-09	花王株式会社	コンクリート製品の製造方法
JP5536387B2 (ja) *	2008-07-25	2014-07-02	花王株式会社	遠心成形コンクリート製品の製造方法
JP5122501B2 (ja) *	2009-01-30	2013-01-16	花王株式会社	水硬性組成物
JP5350135B2 (ja) *	2009-08-21	2013-11-27	花王株式会社	水硬性組成物用分散剤
CN103274703B (zh) *	2013-05-08	2014-08-20	中科院广州化学有限公司	一种节水型减水剂及其制备方法和应用
JP6239355B2 (ja) *	2013-11-27	2017-11-29	花王株式会社	水硬性組成物用添加剤
KR102853123B1 (ko) *	2018-09-07	2025-09-03	하이드로-퀘벡	규소 또는 규소-흑연 복합 전극용 폴리머 결합제 및 전기화학적 전지에서의 이들의 용도

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5918338B2 (ja) *	1981-10-30	1984-04-26	株式会社日本触媒	セメント分散剤
JPS58190851A (ja) *	1982-04-28	1983-11-07	上武産業株式会社	水中施工用コンクリ−ト
US4473406A (en) *	1982-06-21	1984-09-25	National Starch And Chemical Corporation	Cementiferous compositions
IE55483B1 (en) *	1982-06-21	1990-09-26	Nat Starch Chem Corp	Cementiferous compositions
JPS619473A (ja) *	1984-06-26	1986-01-17	Nippon Junyaku Kk	粘着剤組成物
JPS6270250A (ja) *	1985-09-24	1987-03-31	株式会社日本触媒	セメント配合物用スランプロス防止剤
GB8527661D0 (en) *	1985-11-08	1985-12-11	Ici Plc	Catalyst supports & precursors
CA1325311C (fr) *	1986-07-01	1993-12-14	W.R. Grace & Co.-Conn.	Adjuvant du ciment

1987
- 1987-06-17 CA CA000539923A patent/CA1325311C/fr not_active Expired - Fee Related
- 1987-07-01 JP JP16250887A patent/JPS6339906A/ja active Pending
1995
- 1995-08-31 JP JP7245077A patent/JPH08113613A/ja active Pending

Also Published As

Publication number	Publication date
JPS6339906A (ja)	1988-02-20
JPH08113613A (ja)	1996-05-07

Legal Events

Date	Code	Title	Description
1997-12-15	MKLA	Lapsed

Publication	Publication Date	Title
US4968734A (en)	1990-11-06	Cement admixture
US4460720A (en)	1984-07-17	Multicomponent concrete superplasticizer
US5100984A (en)	1992-03-31	Water-soluble copolymers, a process for their preparation and their use as fluidizers in suspensions of solid matter
US5798425A (en)	1998-08-25	Co-polymers based on oxyalkyleneglycol alkenyl ethers and unsaturated dicarboxylic acid derivatives
CA2107267C (fr)	1999-12-28	Agents de dispersion de ciment
KR910006893B1 (ko)	1991-09-10	시멘트용 분산제 및 그 제조방법 및 이 시멘트용 분산제를 사용하는 수경성 시멘트 조성물에의 유동성 부여방법
JP5479478B2 (ja)	2014-04-23	セメント状組成物のワーカビリティ保持のためのダイナミックコポリマー
US5290869A (en)	1994-03-01	Cement dispersion agents
BRPI0915306B1 (pt)	2022-01-25	Processo de síntese de copolímero
US6043329A (en)	2000-03-28	Acrylic copolymers
DE69217071T2 (de)	1997-05-07	Wasserlösliche Vinylacetat/Maleinsäurehalbamid-Copolymere und ihre Verwendung als Verflüssiger oder Wasserreduziermittel für wässrige Dispersionen
EP0537870A1 (fr)	1993-04-21	Copolymères d'ethers insaturés éthyléniquement utilisables comme superplastifiants pour ciment hydraulique
CA2550967A1 (fr)	2005-07-14	Superplastifiant a resistance initiale elevee
CA2231641A1 (fr)	1997-04-17	Melanges pour betons a base de lignines
JPS6339906A (ja)	1988-02-20	セメント添加剤
JP4291922B2 (ja)	2009-07-08	セメント組成物用材料分離低減剤
EP2292567A1 (fr)	2011-03-09	Dispersant pour un composite hydraulique
CN108025971B (zh)	2021-04-02	作为碱活化粘结剂的分散剂的嵌段共聚物
US20090018240A1 (en)	2009-01-15	Use of Water-Soluble or Water-Dispersible Polymers as Additives in Mineral Building Materials
CA1162951A (fr)	1984-02-28	Superplasticiseur pour ciment
JPS6230648A (ja)	1987-02-09	セメント用分散剤
JPS62212252A (ja)	1987-09-18	セメント用分散剤
WO2025207324A1 (fr)	2025-10-02	Adjuvant de rétention d'eau
JPS62212253A (ja)	1987-09-18	セメント用分散剤
HK1096079B (en)	2009-07-24	High early strength superplasticizer