CA1326571C - Valorisation des metaux presents dans les residus des sables bitumineux - Google Patents
Valorisation des metaux presents dans les residus des sables bitumineuxInfo
- Publication number
- CA1326571C CA1326571C CA000527560A CA527560A CA1326571C CA 1326571 C CA1326571 C CA 1326571C CA 000527560 A CA000527560 A CA 000527560A CA 527560 A CA527560 A CA 527560A CA 1326571 C CA1326571 C CA 1326571C
- Authority
- CA
- Canada
- Prior art keywords
- slurry
- solids
- bitumen
- metal values
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002002 slurry Substances 0.000 title claims abstract description 36
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 23
- 239000002184 metal Substances 0.000 title claims abstract description 23
- 238000011084 recovery Methods 0.000 title description 13
- 239000007787 solid Substances 0.000 claims abstract description 34
- 238000005188 flotation Methods 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 28
- 230000008569 process Effects 0.000 claims abstract description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000010936 titanium Substances 0.000 claims abstract description 22
- 239000010426 asphalt Substances 0.000 claims abstract description 19
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 16
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004576 sand Substances 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 6
- 238000003809 water extraction Methods 0.000 claims abstract description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 23
- 239000010665 pine oil Substances 0.000 claims description 9
- -1 alkyl aryl sulphonate Chemical compound 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000007885 magnetic separation Methods 0.000 claims description 4
- 238000012216 screening Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- 229910052500 inorganic mineral Inorganic materials 0.000 description 21
- 239000011707 mineral Substances 0.000 description 21
- 235000010755 mineral Nutrition 0.000 description 21
- 239000012141 concentrate Substances 0.000 description 15
- 235000008504 concentrate Nutrition 0.000 description 14
- 238000000926 separation method Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 229910052779 Neodymium Inorganic materials 0.000 description 5
- 229910052746 lanthanum Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229910052684 Cerium Inorganic materials 0.000 description 4
- 229910052776 Thorium Inorganic materials 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000000921 elemental analysis Methods 0.000 description 4
- 229910052727 yttrium Inorganic materials 0.000 description 4
- 229910052688 Gadolinium Inorganic materials 0.000 description 3
- 229910052772 Samarium Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- IXQWNVPHFNLUGD-UHFFFAOYSA-N iron titanium Chemical compound [Ti].[Fe] IXQWNVPHFNLUGD-UHFFFAOYSA-N 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910052845 zircon Inorganic materials 0.000 description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 2
- GRYSXUXXBDSYRT-WOUKDFQISA-N (2r,3r,4r,5r)-2-(hydroxymethyl)-4-methoxy-5-[6-(methylamino)purin-9-yl]oxolan-3-ol Chemical compound C1=NC=2C(NC)=NC=NC=2N1[C@@H]1O[C@H](CO)[C@@H](O)[C@H]1OC GRYSXUXXBDSYRT-WOUKDFQISA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- LENJPRSQISBMDN-UHFFFAOYSA-N [Y].[Ce] Chemical compound [Y].[Ce] LENJPRSQISBMDN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000008396 flotation agent Substances 0.000 description 1
- 239000000727 fraction Substances 0.000 description 1
- 238000009291 froth flotation Methods 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 229910001608 iron mineral Inorganic materials 0.000 description 1
- 239000001034 iron oxide pigment Substances 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000006148 magnetic separator Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052590 monazite Inorganic materials 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 239000003027 oil sand Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000011275 tar sand Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
- B03B9/02—General arrangement of separating plant, e.g. flow sheets specially adapted for oil-sand, oil-chalk, oil-shales, ozokerite, bitumen, or the like
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Geology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000527560A CA1326571C (fr) | 1987-01-16 | 1987-01-16 | Valorisation des metaux presents dans les residus des sables bitumineux |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000527560A CA1326571C (fr) | 1987-01-16 | 1987-01-16 | Valorisation des metaux presents dans les residus des sables bitumineux |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1326571C true CA1326571C (fr) | 1994-01-25 |
Family
ID=4134778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000527560A Expired - Lifetime CA1326571C (fr) | 1987-01-16 | 1987-01-16 | Valorisation des metaux presents dans les residus des sables bitumineux |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1326571C (fr) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7341658B2 (en) | 2002-04-18 | 2008-03-11 | Tatanium Corporation Inc. | Recovery of heavy minerals from a tar sand |
| US7695612B2 (en) | 2006-05-25 | 2010-04-13 | Titanium Corporation Inc. | Process for recovering heavy minerals from oil sand tailings |
| CN103272685A (zh) * | 2013-05-15 | 2013-09-04 | 包钢集团矿山研究院(有限责任公司) | 包头矿氧化矿浮选尾矿中回收铁和稀土的选矿工艺 |
| US8852429B2 (en) | 2010-02-22 | 2014-10-07 | Titanium Corporation Inc. | Method for processing froth treatment tailings |
| WO2015051435A1 (fr) * | 2013-10-10 | 2015-04-16 | Titanium Corporation Inc. | Procédé de production d'un produit concentré de zirconium à partir de résidus provenant du traitement de mousses |
| CN106362858A (zh) * | 2016-10-14 | 2017-02-01 | 鞍钢集团矿业有限公司 | 从铁尾矿中提取替代水泥的超细铁尾粉的工艺 |
| US10087372B2 (en) | 2009-04-09 | 2018-10-02 | Titanium Corporation Inc. | Methods for separating a feed material derived from a process for recovering bitumen from oil sands |
| CN109013047A (zh) * | 2018-09-25 | 2018-12-18 | 李梅 | 一种分选稀有金属精矿和石英长石精矿的选矿方法 |
| CN113443798A (zh) * | 2020-03-27 | 2021-09-28 | 宝峨资源有限公司 | 用于清洁污染材料的方法和处理设备 |
-
1987
- 1987-01-16 CA CA000527560A patent/CA1326571C/fr not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7341658B2 (en) | 2002-04-18 | 2008-03-11 | Tatanium Corporation Inc. | Recovery of heavy minerals from a tar sand |
| US7695612B2 (en) | 2006-05-25 | 2010-04-13 | Titanium Corporation Inc. | Process for recovering heavy minerals from oil sand tailings |
| US10087372B2 (en) | 2009-04-09 | 2018-10-02 | Titanium Corporation Inc. | Methods for separating a feed material derived from a process for recovering bitumen from oil sands |
| US8852429B2 (en) | 2010-02-22 | 2014-10-07 | Titanium Corporation Inc. | Method for processing froth treatment tailings |
| CN103272685A (zh) * | 2013-05-15 | 2013-09-04 | 包钢集团矿山研究院(有限责任公司) | 包头矿氧化矿浮选尾矿中回收铁和稀土的选矿工艺 |
| CN103272685B (zh) * | 2013-05-15 | 2015-09-30 | 包钢集团矿山研究院(有限责任公司) | 包头矿氧化矿浮选尾矿中回收铁和稀土的选矿工艺 |
| WO2015051435A1 (fr) * | 2013-10-10 | 2015-04-16 | Titanium Corporation Inc. | Procédé de production d'un produit concentré de zirconium à partir de résidus provenant du traitement de mousses |
| US9694367B2 (en) | 2013-10-10 | 2017-07-04 | Titanium Corporation, Inc. | Method for producing a zirconium concentrated product from froth treatment tailings |
| CN106362858A (zh) * | 2016-10-14 | 2017-02-01 | 鞍钢集团矿业有限公司 | 从铁尾矿中提取替代水泥的超细铁尾粉的工艺 |
| CN109013047A (zh) * | 2018-09-25 | 2018-12-18 | 李梅 | 一种分选稀有金属精矿和石英长石精矿的选矿方法 |
| CN113443798A (zh) * | 2020-03-27 | 2021-09-28 | 宝峨资源有限公司 | 用于清洁污染材料的方法和处理设备 |
| EP3885021A1 (fr) * | 2020-03-27 | 2021-09-29 | Bauer Resources GmbH | Procédé et installation de traitement de nettoyage d'un matériaux contaminés |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |
Effective date: 20110125 |