CA1327258C - Procede pour l'obtention de fibres de carbone pre-etirees - Google Patents

Procede pour l'obtention de fibres de carbone pre-etirees

Info

Publication number: CA1327258C
Authority: CA; Canada
Prior art keywords: precursor; stretching; temperature; tow; precursor tow
Prior art date: 1988-02-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000590558A

Other languages

English (en)

Inventor

James Toner Paul Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hercules LLC

Original Assignee

Hercules LLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-02-16

Filing date

1989-02-09

Publication date

1994-03-01

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22559371&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1327258(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1989-02-09 Application filed by Hercules LLC filed Critical Hercules LLC

1994-03-01 Application granted granted Critical

1994-03-01 Publication of CA1327258C publication Critical patent/CA1327258C/fr

2011-03-01 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000004519 manufacturing process Methods 0.000 title claims abstract description 20
229920000049 Carbon (fiber) Polymers 0.000 title abstract description 43
239000004917 carbon fiber Substances 0.000 title abstract description 43
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract description 41
239000002243 precursor Substances 0.000 claims abstract description 120
229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 34
238000000034 method Methods 0.000 claims abstract description 29
230000003647 oxidation Effects 0.000 claims abstract description 20
238000007254 oxidation reaction Methods 0.000 claims abstract description 20
239000000835 fiber Substances 0.000 claims description 23
238000010438 heat treatment Methods 0.000 claims description 16
229920000642 polymer Polymers 0.000 claims description 16
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 13
239000000178 monomer Substances 0.000 claims description 13
239000000463 material Substances 0.000 claims description 12
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
229910052799 carbon Inorganic materials 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 9
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
239000002904 solvent Substances 0.000 claims description 8
238000010000 carbonizing Methods 0.000 claims description 5
230000001590 oxidative effect Effects 0.000 claims description 5
230000000379 polymerizing effect Effects 0.000 claims description 2
238000003763 carbonization Methods 0.000 abstract description 7
239000000243 solution Substances 0.000 description 11
238000009987 spinning Methods 0.000 description 8
230000001965 increasing effect Effects 0.000 description 7
229940063559 methacrylic acid Drugs 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
239000000701 coagulant Substances 0.000 description 4
238000004381 surface treatment Methods 0.000 description 4
238000012360 testing method Methods 0.000 description 4
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
239000007789 gas Substances 0.000 description 3
238000004886 process control Methods 0.000 description 3
230000009467 reduction Effects 0.000 description 3
238000002166 wet spinning Methods 0.000 description 3
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
239000004593 Epoxy Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000013461 design Methods 0.000 description 2
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
238000012545 processing Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
238000012546 transfer Methods 0.000 description 2
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
101100481176 Bacillus subtilis (strain 168) thiE gene Proteins 0.000 description 1
241000905957 Channa melasoma Species 0.000 description 1
101100494344 Desulfobacterium autotrophicum (strain ATCC 43914 / DSM 3382 / HRM2) bzaF gene Proteins 0.000 description 1
108700040458 Drosophila Strn-Mlck Proteins 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
241000353097 Molva molva Species 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
238000012644 addition polymerization Methods 0.000 description 1
235000012538 ammonium bicarbonate Nutrition 0.000 description 1
239000001099 ammonium carbonate Substances 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
230000000332 continued effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
-1 di~ethylsul~oxide Substances 0.000 description 1
238000000578 dry spinning Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910001867 inorganic solvent Inorganic materials 0.000 description 1
239000003049 inorganic solvent Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
125000005395 methacrylic acid group Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000013557 residual solvent Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
238000004513 sizing Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
101150029215 thiC gene Proteins 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
238000011282 treatment Methods 0.000 description 1
235000005074 zinc chloride Nutrition 0.000 description 1
239000011592 zinc chloride Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
- D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
- D01F9/225—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles from stabilised polyacrylonitriles
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods

Landscapes

Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Mechanical Engineering (AREA)
Physics & Mathematics (AREA)
Thermal Sciences (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Inorganic Fibers (AREA)
Artificial Filaments (AREA)
Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

CA000590558A 1988-02-16 1989-02-09 Procede pour l'obtention de fibres de carbone pre-etirees Expired - Fee Related CA1327258C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US15638988A	1988-02-16	1988-02-16
US156,389		1988-02-16

Publications (1)

Publication Number	Publication Date
CA1327258C true CA1327258C (fr)	1994-03-01

Family

ID=22559371

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000590558A Expired - Fee Related CA1327258C (fr)	1988-02-16	1989-02-09	Procede pour l'obtention de fibres de carbone pre-etirees

Country Status (7)

Country	Link
EP (1)	EP0329128B1 (fr)
JP (1)	JP3033960B2 (fr)
AT (1)	ATE176012T1 (fr)
CA (1)	CA1327258C (fr)
DE (1)	DE68928911T2 (fr)
ES (1)	ES2128296T3 (fr)
IL (1)	IL89271A (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2770233B1 (fr) *	1997-10-27	2000-01-14	Messier Bugatti	Procede de fabrication de preformes en fibres de carbone
BR112013011517A2 (pt)	2010-11-30	2016-08-09	Toray Industries	''método para a fabricação de uma fibra de poliacrilonitrila e de carbono''
WO2017117544A1 (fr)	2015-12-31	2017-07-06	Ut-Battelle, Llc	Procédé de production de fibres de carbone à partir de fibres commerciales polyvalentes

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1324041A (en) *	1969-10-31	1973-07-18	Nippon Carbon Co Ltd	Method of producing carbon fibres
DE2211639C3 (de) *	1972-03-10	1978-12-14	Bayer Ag, 5090 Leverkusen	Verfahren zur Herstellung von Kohlenstoff-Fäden
JPS6039763A (ja) *	1983-08-11	1985-03-01	Japan Storage Battery Co Ltd	電解液循環装置を備える鉛蓄電池
JPS6156327A (ja) *	1984-08-28	1986-03-22	Canon Inc	表示パネルの駆動法
JPH0742605B2 (ja) *	1987-09-16	1995-05-10	日機装株式会社	アクリル系繊維の製造方法

1989
- 1989-02-09 CA CA000590558A patent/CA1327258C/fr not_active Expired - Fee Related
- 1989-02-13 IL IL89271A patent/IL89271A/xx not_active IP Right Cessation
- 1989-02-16 JP JP1037316A patent/JP3033960B2/ja not_active Expired - Lifetime
- 1989-02-16 ES ES89102638T patent/ES2128296T3/es not_active Expired - Lifetime
- 1989-02-16 AT AT89102638T patent/ATE176012T1/de not_active IP Right Cessation
- 1989-02-16 DE DE68928911T patent/DE68928911T2/de not_active Expired - Fee Related
- 1989-02-16 EP EP89102638A patent/EP0329128B1/fr not_active Revoked

Also Published As

Publication number	Publication date
ES2128296T3 (es)	1999-05-16
EP0329128A2 (fr)	1989-08-23
EP0329128B1 (fr)	1999-01-20
EP0329128A3 (fr)	1991-03-13
DE68928911T2 (de)	1999-05-27
ATE176012T1 (de)	1999-02-15
JP3033960B2 (ja)	2000-04-17
JPH026627A (ja)	1990-01-10
IL89271A0 (en)	1989-09-10
IL89271A (en)	1992-12-01
DE68928911D1 (de)	1999-03-04

Legal Events

Date	Code	Title	Description
2001-03-01	MKLA	Lapsed

Publication	Publication Date	Title
CA1095206A (fr)	1981-02-10	Procede de production de fibres de carbone
US3529934A (en)	1970-09-22	Process for the preparation of carbon fibers
EP1130140B1 (fr)	2005-11-16	Fibre precurseur a base d'acrylonitrile destinee a former une fibre de carbone et procede de production
EP0159365B1 (fr)	1991-09-04	Fibres de carbone a haute resistance et module d'elasticite eleve et leur procede de production
US4917836A (en)	1990-04-17	Process for producing high-strength, high-modulus carbon fibers
US5066433A (en)	1991-11-19	Method of manufacturing carbon fiber using preliminary stretch
US4452860A (en)	1984-06-05	Carbon fibers and process for producing the same
US4186179A (en)	1980-01-29	Process for producing oxidized or carbon fibers
US3867499A (en)	1975-02-18	Process for wet-spinning fibers derived from acrylic polymers
US4397831A (en)	1983-08-09	Production of carbon fibers from acrylonitrile based fibers
US4869856A (en)	1989-09-26	Method for producing carbon fibers from acrylonitrile fiber strands
EP0329128B1 (fr)	1999-01-20	Méthode pour la fabrication de fibres de carbone, ou ses fibres précurseures, en utilisant un étirage préliminaire
JP7655307B2 (ja)	2025-04-02	炭素繊維とその製造方法および炭素繊維複合材料
CA1199763A (fr)	1986-01-28	Methode de production de filaments extra-solides a partir de polyacrylonitrile file a sec
JPH01306619A (ja)	1989-12-11	高強度高弾性率炭素繊維
US3838562A (en)	1974-10-01	Acrylonitrile yarn
EP0378381A2 (fr)	1990-07-18	Fibres de carbone chargées de métaux
US5413858A (en)	1995-05-09	Acrylic fiber and process for production thereof
US4237109A (en)	1980-12-02	Process for producing carbon fabric
CN112708969B (zh)	2022-10-11	一种聚丙烯腈预氧化纤维的制备方法
JP2002003081A (ja)	2002-01-09	炭素繊維前駆体アクリル系太物糸条パッケージおよびその製造方法
JP3562115B2 (ja)	2004-09-08	炭素繊維前駆体アクリル系糸条パッケージおよび炭素繊維前駆体アクリル系糸条の巻き取り方法
JP3964011B2 (ja)	2007-08-22	炭素繊維用アクリロニトリル系前駆体繊維およびその製造方法
JP3002614B2 (ja)	2000-01-24	アクリロニトリル系繊維及びその製法
GB1578492A (en)	1980-11-05	Production of carbon fibres