CA1330476C - Methodes et compositions servant a ameliorer la resistance aux taches des fibres de tapis - Google Patents

Methodes et compositions servant a ameliorer la resistance aux taches des fibres de tapis

Info

Publication number: CA1330476C
Authority: CA; Canada
Prior art keywords: carpet; fiber; effective amount; fabric; sulfonated aromatic
Prior art date: 1987-09-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000578108A

Other languages

English (en)

Inventor

Michael Philip Friedberger

Dale Alan Hangey

Roger Neil Spitz

Paul Wesley Harris

Charles Jayroe Cole

William Alexander Archie

Daniel Joseph Corcoran, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Honeywell International Inc

Original Assignee

AlliedSignal Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-09-28

Filing date

1988-09-22

Publication date

1994-07-05

1988-09-22 Application filed by AlliedSignal Inc filed Critical AlliedSignal Inc

1994-07-05 Application granted granted Critical

1994-07-05 Publication of CA1330476C publication Critical patent/CA1330476C/fr

2011-07-05 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 146
239000000835 fiber Substances 0.000 title claims abstract description 130
239000000203 mixture Substances 0.000 title claims abstract description 126
239000004744 fabric Substances 0.000 claims abstract description 130
125000003118 aryl group Chemical group 0.000 claims abstract description 97
238000004383 yellowing Methods 0.000 claims abstract description 50
150000003839 salts Chemical class 0.000 claims abstract description 31
239000002270 dispersing agent Substances 0.000 claims abstract description 28
239000003352 sequestering agent Substances 0.000 claims abstract description 27
150000001768 cations Chemical class 0.000 claims abstract description 18
239000002253 acid Substances 0.000 claims abstract description 15
230000003647 oxidation Effects 0.000 claims abstract description 6
238000007254 oxidation reaction Methods 0.000 claims abstract description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 103
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 69
SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical group [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 claims description 54
ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 44
ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 44
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 44
239000007864 aqueous solution Substances 0.000 claims description 40
-1 fluorocarbon compound Chemical class 0.000 claims description 40
229920001778 nylon Polymers 0.000 claims description 38
239000004342 Benzoyl peroxide Substances 0.000 claims description 35
238000004043 dyeing Methods 0.000 claims description 35
235000019400 benzoyl peroxide Nutrition 0.000 claims description 33
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 32
239000004677 Nylon Substances 0.000 claims description 25
238000010186 staining Methods 0.000 claims description 25
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 18
229910052783 alkali metal Inorganic materials 0.000 claims description 11
238000013020 steam cleaning Methods 0.000 claims description 8
239000007800 oxidant agent Substances 0.000 claims description 7
229920000642 polymer Polymers 0.000 claims description 7
239000007787 solid Substances 0.000 claims description 7
FEPBITJSIHRMRT-UHFFFAOYSA-N 4-hydroxybenzenesulfonic acid Chemical compound OC1=CC=C(S(O)(=O)=O)C=C1 FEPBITJSIHRMRT-UHFFFAOYSA-N 0.000 claims description 6
239000013078 crystal Substances 0.000 claims description 4
210000002268 wool Anatomy 0.000 claims description 3
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract description 85
230000008569 process Effects 0.000 abstract description 82
229910052943 magnesium sulfate Inorganic materials 0.000 abstract description 47
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical class FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract description 43
235000019341 magnesium sulphate Nutrition 0.000 abstract description 42
150000003567 thiocyanates Chemical class 0.000 abstract description 9
239000002689 soil Substances 0.000 abstract description 8
230000003139 buffering effect Effects 0.000 abstract description 3
150000007513 acids Chemical class 0.000 abstract description 2
238000004140 cleaning Methods 0.000 abstract 1
238000011282 treatment Methods 0.000 description 36
239000000975 dye Substances 0.000 description 30
239000000243 solution Substances 0.000 description 22
239000000758 substrate Substances 0.000 description 19
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 18
238000004458 analytical method Methods 0.000 description 16
230000000694 effects Effects 0.000 description 16
230000008859 change Effects 0.000 description 15
238000009472 formulation Methods 0.000 description 15
230000006872 improvement Effects 0.000 description 15
238000006243 chemical reaction Methods 0.000 description 14
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
239000004784 Superba Substances 0.000 description 13
241000324401 Superba Species 0.000 description 13
230000008901 benefit Effects 0.000 description 13
239000000126 substance Substances 0.000 description 13
239000003795 chemical substances by application Substances 0.000 description 12
239000007921 spray Substances 0.000 description 11
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
150000001875 compounds Chemical class 0.000 description 10
150000002989 phenols Chemical class 0.000 description 10
239000007795 chemical reaction product Substances 0.000 description 9
125000001153 fluoro group Chemical group F* 0.000 description 9
230000009467 reduction Effects 0.000 description 9
239000011734 sodium Substances 0.000 description 9
229910052708 sodium Inorganic materials 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
230000035515 penetration Effects 0.000 description 8
159000000000 sodium salts Chemical class 0.000 description 8
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
239000010949 copper Substances 0.000 description 7
229910052802 copper Inorganic materials 0.000 description 7
238000011156 evaluation Methods 0.000 description 7
238000005562 fading Methods 0.000 description 7
238000005406 washing Methods 0.000 description 7
239000011701 zinc Substances 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000013530 defoamer Substances 0.000 description 6
239000003599 detergent Substances 0.000 description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
239000011591 potassium Substances 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 6
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 6
229910052725 zinc Inorganic materials 0.000 description 6
NNARPPSIYMCXMB-UHFFFAOYSA-N 1,4-bis(2-methylpropoxy)-1,4-dioxobutane-2-sulfonic acid Chemical compound CC(C)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(C)C NNARPPSIYMCXMB-UHFFFAOYSA-N 0.000 description 5
VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 5
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
229910019142 PO4 Inorganic materials 0.000 description 5
230000002411 adverse Effects 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 5
125000004429 atom Chemical group 0.000 description 5
239000012141 concentrate Substances 0.000 description 5
238000009833 condensation Methods 0.000 description 5
230000005494 condensation Effects 0.000 description 5
238000010924 continuous production Methods 0.000 description 5
239000003921 oil Substances 0.000 description 5
238000010979 pH adjustment Methods 0.000 description 5
235000021317 phosphate Nutrition 0.000 description 5
235000019982 sodium hexametaphosphate Nutrition 0.000 description 5
WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 4
LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 4
MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 4
239000011575 calcium Substances 0.000 description 4
235000001465 calcium Nutrition 0.000 description 4
238000010014 continuous dyeing Methods 0.000 description 4
229960002089 ferrous chloride Drugs 0.000 description 4
239000011777 magnesium Substances 0.000 description 4
229910052749 magnesium Inorganic materials 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 4
229940044654 phenolsulfonic acid Drugs 0.000 description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
239000010452 phosphate Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
238000009736 wetting Methods 0.000 description 4
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
239000000980 acid dye Substances 0.000 description 3
229910021529 ammonia Inorganic materials 0.000 description 3
239000003963 antioxidant agent Substances 0.000 description 3
238000010923 batch production Methods 0.000 description 3
230000000903 blocking effect Effects 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
238000001035 drying Methods 0.000 description 3
229960001484 edetic acid Drugs 0.000 description 3
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 3
SUBFIBLJQMMKBK-UHFFFAOYSA-K iron(3+);trithiocyanate Chemical compound [Fe+3].[S-]C#N.[S-]C#N.[S-]C#N SUBFIBLJQMMKBK-UHFFFAOYSA-K 0.000 description 3
230000014759 maintenance of location Effects 0.000 description 3
239000000463 material Substances 0.000 description 3
230000000149 penetrating effect Effects 0.000 description 3
150000002978 peroxides Chemical class 0.000 description 3
YXCDJKQYFBEAOU-UHFFFAOYSA-N phenyl thiocyanate Chemical compound N#CSC1=CC=CC=C1 YXCDJKQYFBEAOU-UHFFFAOYSA-N 0.000 description 3
229920005594 polymer fiber Polymers 0.000 description 3
238000001179 sorption measurement Methods 0.000 description 3
238000010025 steaming Methods 0.000 description 3
150000003457 sulfones Chemical class 0.000 description 3
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 3
229910052724 xenon Inorganic materials 0.000 description 3
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
208000002874 Acne Vulgaris Diseases 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
241000167854 Bourreria succulenta Species 0.000 description 2
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
239000004952 Polyamide Substances 0.000 description 2
229920000388 Polyphosphate Polymers 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
206010000496 acne Diseases 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
150000001414 amino alcohols Chemical class 0.000 description 2
150000008064 anhydrides Chemical class 0.000 description 2
230000003078 antioxidant effect Effects 0.000 description 2
238000009978 beck dyeing Methods 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
239000002738 chelating agent Substances 0.000 description 2
230000009920 chelation Effects 0.000 description 2
235000019693 cherries Nutrition 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
238000010276 construction Methods 0.000 description 2
PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 description 2
230000006378 damage Effects 0.000 description 2
230000007423 decrease Effects 0.000 description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 2
230000008030 elimination Effects 0.000 description 2
238000003379 elimination reaction Methods 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
238000005187 foaming Methods 0.000 description 2
239000012948 isocyanate Substances 0.000 description 2
150000002513 isocyanates Chemical class 0.000 description 2
230000007774 longterm Effects 0.000 description 2
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 2
229920002647 polyamide Polymers 0.000 description 2
239000001205 polyphosphate Substances 0.000 description 2
235000011176 polyphosphates Nutrition 0.000 description 2
ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000009919 sequestration Effects 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
101000652359 Homo sapiens Spermatogenesis-associated protein 2 Proteins 0.000 description 1
101000642464 Homo sapiens Spermatogenesis-associated protein 2-like protein Proteins 0.000 description 1
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical class CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
229910017621 MgSO4-7H2O Inorganic materials 0.000 description 1
229920000299 Nylon 12 Polymers 0.000 description 1
229920001007 Nylon 4 Polymers 0.000 description 1
229920002292 Nylon 6 Polymers 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
102100030254 Spermatogenesis-associated protein 2 Human genes 0.000 description 1
102220609490 UPF0489 protein C5orf22_I60F_mutation Human genes 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
229940031012 anti-acne preparations Drugs 0.000 description 1
239000013011 aqueous formulation Substances 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
239000002585 base Substances 0.000 description 1
150000001565 benzotriazoles Chemical class 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
239000003086 colorant Substances 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
239000000986 disperse dye Substances 0.000 description 1
229940079593 drug Drugs 0.000 description 1
239000003814 drug Substances 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
229940116007 ferrous phosphate Drugs 0.000 description 1
239000011790 ferrous sulphate Substances 0.000 description 1
235000003891 ferrous sulphate Nutrition 0.000 description 1
239000012530 fluid Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
239000000576 food coloring agent Substances 0.000 description 1
235000002864 food coloring agent Nutrition 0.000 description 1
239000000989 food dye Substances 0.000 description 1
235000021384 green leafy vegetables Nutrition 0.000 description 1
238000009998 heat setting Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000004128 high performance liquid chromatography Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
238000002483 medication Methods 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
JWZXKXIUSSIAMR-UHFFFAOYSA-N methylene bis(thiocyanate) Chemical compound N#CSCSC#N JWZXKXIUSSIAMR-UHFFFAOYSA-N 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000010791 quenching Methods 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
NTWXWSVUSTYPJH-UHFFFAOYSA-M sodium;1,4-bis(2-methylpropoxy)-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].CC(C)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(C)C NTWXWSVUSTYPJH-UHFFFAOYSA-M 0.000 description 1
230000001629 suppression Effects 0.000 description 1
238000004347 surface barrier Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
235000016804 zinc Nutrition 0.000 description 1
229910000368 zinc sulfate Inorganic materials 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
- D06M15/412—Phenol-aldehyde or phenol-ketone resins sulfonated
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Coloring (AREA)
Chemical Or Physical Treatment Of Fibers (AREA)
Carpets (AREA)

CA000578108A 1987-09-28 1988-09-22 Methodes et compositions servant a ameliorer la resistance aux taches des fibres de tapis Expired - Fee Related CA1330476C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US10165287A	1987-09-28	1987-09-28
US101,652		1987-09-28

Publications (1)

Publication Number	Publication Date
CA1330476C true CA1330476C (fr)	1994-07-05

Family

ID=22285740

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000578108A Expired - Fee Related CA1330476C (fr)	1987-09-28	1988-09-22	Methodes et compositions servant a ameliorer la resistance aux taches des fibres de tapis

Country Status (6)

Country	Link
EP (1)	EP0382724B1 (fr)
JP (1)	JPH03500307A (fr)
AT (1)	ATE118837T1 (fr)
CA (1)	CA1330476C (fr)
DE (1)	DE3853165T2 (fr)
WO (1)	WO1989002949A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5135774A (en) *	1990-03-27	1992-08-04	Allied-Signal Inc.	Method to impart coffee stain resistance to polyamide fibers
US5118551A (en) *	1990-03-27	1992-06-02	Allied-Signal Inc.	Method to impart stain resistance to polyamide textile substrates
US5670246A (en) *	1995-09-22	1997-09-23	E. I. Du Pont De Nemours And Company	Treatment of polyamide materials with partial fluoroesters or fluorothioesters of maleic acid polymers and sulfonated aromatic condensates
US6852134B2 (en)	1999-07-08	2005-02-08	Invista North America S.A.R.L.	Method of imparting stain resistance to a differentially dyeable textile surface and the article produced thereby
US7491805B2 (en)	2001-05-18	2009-02-17	Sirna Therapeutics, Inc.	Conjugates and compositions for cellular delivery
US6811574B2 (en)	2000-07-03	2004-11-02	Dupont Textiles & Interiors, Inc.	Method of after-treatment of a dyeable nylon textile surface with a stain resist and the article produced thereby
US6814758B1 (en) *	2001-04-26	2004-11-09	Simco Holding Corporation	Process for protecting dyed nylon fibers from colorants and chemical agents

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3039981A (en) *	1955-12-27	1962-06-19	Owens Corning Fiberglass Corp	Aqueous binder composition of phenolformaldehyde condensate, aluminum sulfate and mineral oil, and glass fiber coated therewith
BE759823A (fr) *	1969-12-03	1971-05-17	Bayer Ag	Agents ameliorant la solidite au mouille
CA1264505A (fr) *	1986-02-14	1990-01-23	E.I. Du Pont De Nemours And Company	Procede de fabrication de polyamides resistant aux taches
DE3683151D1 (de) *	1986-03-06	1992-02-06	Monsanto Co	Fleckenabweisende nylonfasern.

1988
- 1988-04-06 AT AT88904055T patent/ATE118837T1/de not_active IP Right Cessation
- 1988-04-06 DE DE3853165T patent/DE3853165T2/de not_active Expired - Fee Related
- 1988-04-06 EP EP88904055A patent/EP0382724B1/fr not_active Expired - Lifetime
- 1988-04-06 WO PCT/US1988/001112 patent/WO1989002949A1/fr not_active Ceased
- 1988-04-06 JP JP63503627A patent/JPH03500307A/ja active Pending
- 1988-09-22 CA CA000578108A patent/CA1330476C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
EP0382724A1 (fr)	1990-08-22
DE3853165D1 (de)	1995-03-30
EP0382724B1 (fr)	1995-02-22
DE3853165T2 (de)	1995-07-27
ATE118837T1 (de)	1995-03-15
JPH03500307A (ja)	1991-01-24
WO1989002949A1 (fr)	1989-04-06

Legal Events

Date	Code	Title	Description
1998-07-06	MKLA	Lapsed

Publication	Publication Date	Title
US5110317A (en)	1992-05-05	Methods and compositions to enhance stain resistance of dyed nylon carpet fibers: thiocyanate to reduce yellowing
CA2037930C (fr)	2001-09-11	Procede d'application d'agents antitaches
AU735478B2 (en)	2001-07-12	Tandem application of soil and stain resists to carpeting
US5230708A (en)	1993-07-27	Methods and compositions to enhance stain resistance of nylon carpet fibers: thlocyanate to reduce yellowing
US4865885A (en)	1989-09-12	Food color stain blocking fiber agents
US20140033451A1 (en)	2014-02-06	Aqueous dispersion of dye, stain-blocker, and fluorochemical and its use in the manufacture of carpet
CA1330476C (fr)	1994-07-05	Methodes et compositions servant a ameliorer la resistance aux taches des fibres de tapis
US5145487A (en)	1992-09-08	Methods and compositions to enhance stain resistance of carpet fibers using sulfonated aromatic condensates
US5152803A (en)	1992-10-06	Methods and compositions to enhance stain resistance of carpet fibers with water-soluble thiocyanate
JP2014501806A (ja)	2014-01-23	染料、汚染ブロッカーおよびフルオロケミカルの水性分散液並びにカーペットの製造におけるその使用
EP0267681B1 (fr)	1993-03-10	Traiter des articles en polyamides fibreux
AU618533B2 (en)	1992-01-02	Method to enhance stain resistance of carpet fibers
EP0268368B1 (fr)	1995-12-13	Traitement de textile
US7037441B2 (en)	2006-05-02	Durable press cellulosic fibrous substrates with improved physical properties
US5482764A (en)	1996-01-09	Method for improving the bleach resistance of dyed textile fiber and product made thereby
CA2378676C (fr)	2010-10-19	Procede permettant de conferer une resistance aux taches a une surface de textile presentant une aptitude a etre teinte differentiellement, et article produit par ce procede
EP0612880A1 (fr)	1994-08-31	Procédé pour améliorer la résistance au blanchiment de fibres textiles teintes et produit réalisé à partir de ces fibres
US4985040A (en)	1991-01-15	Treatment of woollen textile material
US4448817A (en)	1984-05-15	Textile finishing of keratinous articles
EP1069233B1 (fr)	2008-12-17	Procédé pour rendre résistantes aux tâches des surfaces textiles susceptibles d'être teintes par un procédé de teinture différentiel et surface textile ainsi obtenue
EP1730346B1 (fr)	2013-06-26	Compositions resistant aux taches