CA1333306C - Compositions de copolymeres de styrene-diene bloques - Google Patents

Compositions de copolymeres de styrene-diene bloques

Info

Publication number: CA1333306C
Authority: CA; Canada
Prior art keywords: styrene; ratio; copolymer; blocks; oil
Prior art date: 1985-11-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000616482A

Other languages

English (en)

Inventor

Jose P. Gamarra

C. John Swinmurn

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-11-22

Filing date

1992-08-31

Publication date

1994-11-29

1985-11-22 Priority claimed from US06/801,018 external-priority patent/US4716183A/en

1992-08-31 Application filed by Individual filed Critical Individual

1994-11-29 Application granted granted Critical

1994-11-29 Publication of CA1333306C publication Critical patent/CA1333306C/fr

2006-11-21 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 72
229920001400 block copolymer Polymers 0.000 title abstract description 10
229920000428 triblock copolymer Polymers 0.000 claims abstract description 34
-1 poly(styrene-ethylenebutylene-styrene) Polymers 0.000 claims abstract description 25
239000003921 oil Substances 0.000 claims description 42
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 40
229920001577 copolymer Polymers 0.000 claims description 14
239000004215 Carbon black (E152) Substances 0.000 claims description 10
229930195733 hydrocarbon Natural products 0.000 claims description 10
150000002430 hydrocarbons Chemical class 0.000 claims description 10
239000003963 antioxidant agent Substances 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 3
230000003078 antioxidant effect Effects 0.000 claims description 2
239000003063 flame retardant Substances 0.000 claims description 2
239000003381 stabilizer Substances 0.000 claims description 2
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
239000010690 paraffinic oil Substances 0.000 claims 1
230000005855 radiation Effects 0.000 abstract description 21
239000007822 coupling agent Substances 0.000 abstract description 6
238000004132 cross linking Methods 0.000 description 9
229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 9
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 7
230000035515 penetration Effects 0.000 description 6
230000001070 adhesive effect Effects 0.000 description 5
239000000463 material Substances 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
239000000853 adhesive Substances 0.000 description 4
229920001971 elastomer Polymers 0.000 description 4
238000010894 electron beam technology Methods 0.000 description 4
238000002156 mixing Methods 0.000 description 4
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
239000000806 elastomer Substances 0.000 description 3
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
229920002633 Kraton (polymer) Polymers 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000003999 initiator Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000003847 radiation curing Methods 0.000 description 2
239000003566 sealing material Substances 0.000 description 2
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
GDOBGDUGIFUCJV-UHFFFAOYSA-N 2,2-dimethylbutane;2-methylprop-2-enoic acid Chemical compound CCC(C)(C)C.CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O GDOBGDUGIFUCJV-UHFFFAOYSA-N 0.000 description 1
MRDMGGOYEBRLPD-UHFFFAOYSA-N 2-ethoxy-1-(2-ethoxyphenyl)ethanone Chemical compound CCOCC(=O)C1=CC=CC=C1OCC MRDMGGOYEBRLPD-UHFFFAOYSA-N 0.000 description 1
FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
241000736032 Sabia <angiosperm> Species 0.000 description 1
WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
125000004386 diacrylate group Chemical group 0.000 description 1
239000013536 elastomeric material Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
238000000034 method Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000005060 rubber Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
229920002725 thermoplastic elastomer Polymers 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA000616482A 1985-11-22 1992-08-31 Compositions de copolymeres de styrene-diene bloques Expired - Fee Related CA1333306C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US06/801,018 US4716183A (en)	1985-11-22	1985-11-22	Styrene-diene block copolymer compositions
US801,018		1985-11-22
CA000523583A CA1310151C (fr)	1985-11-22	1986-11-21	Copolymere bloque styrene-diene, et ses compositions

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000523583A Division CA1310151C (fr)	1985-11-22	1986-11-21	Copolymere bloque styrene-diene, et ses compositions

Publications (1)

Publication Number	Publication Date
CA1333306C true CA1333306C (fr)	1994-11-29

Family

ID=25671164

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000616482A Expired - Fee Related CA1333306C (fr)	1985-11-22	1992-08-31	Compositions de copolymeres de styrene-diene bloques

Country Status (1)

Country	Link
CA (1)	CA1333306C (fr)

1992
- 1992-08-31 CA CA000616482A patent/CA1333306C/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1999-11-29	MKLA	Lapsed

Publication	Publication Date	Title
US4716183A (en)	1987-12-29	Styrene-diene block copolymer compositions
US5149736A (en)	1992-09-22	Heat resistant gel compositions
JP2716711B2 (ja)	1998-02-18	ポリマー組成物およびその製法
EP0602130B1 (fr)	1998-05-13	Gels
US5777031A (en)	1998-07-07	High 1,2 content thermoplastic elastomer/oil/polyolefin composition
US5705556A (en)	1998-01-06	Modified styrenic block copolymer compounds having improved elastic performance
US6797765B2 (en)	2004-09-28	Gelatinous elastomer
US3993613A (en)	1976-11-23	Adhesive composition
CA2152823C (fr)	2004-04-06	Gels supportant les basses temperatures
EP0822227B1 (fr)	2005-01-19	Compositions de gel d'huile contenant des copolymères séquencés de styrène-butadiène-styrène hydrogenés à haute teneur en vinyle
US20060194925A1 (en)	2006-08-31	Gel with wide distribution of Mw in mid-block
KR100620633B1 (ko)	2006-09-13	신규의 테트라블록 공중합체 및 이것을 함유한 조성물
JPH0198656A (ja)	1989-04-17	耐熱性組成物及びその製法と用途
EP0938524B1 (fr)	2001-09-05	Composes modifies de copolymere styrenique sequence ayant des proprietes elastiques ameliorees
JP2004131707A (ja)	2004-04-30	３元ブロック共重合体及び製造方法
CA1333306C (fr)	1994-11-29	Compositions de copolymeres de styrene-diene bloques
EP1442079A1 (fr)	2004-08-04	Composition polymere solide durcissable
CA1100669A (fr)	1981-05-05	Traduction non-disponible
WO2002062891A1 (fr)	2002-08-15	Elastomere gelatineux ameliore
EP0910610B1 (fr)	2000-03-15	Composition elastomere/huile/polyolefine thermoplastique a faible teneur d'arene
KR100490290B1 (ko)	2005-11-08	고1,2-함량열가소성엘라스토머오일폴리올레핀조성물
KR20000022419A (ko)	2000-04-25	낮은 아렌 함량의 열가소성 엘라스토머/오일/폴리올레핀 조성물
WO2001014472A1 (fr)	2001-03-01	Gels thermoplastiques a peau formee d'un seul tenant