CA1334324C - Procede de fabrication de papier - Google Patents
Procede de fabrication de papierInfo
- Publication number
- CA1334324C CA1334324C CA000609515A CA609515A CA1334324C CA 1334324 C CA1334324 C CA 1334324C CA 000609515 A CA000609515 A CA 000609515A CA 609515 A CA609515 A CA 609515A CA 1334324 C CA1334324 C CA 1334324C
- Authority
- CA
- Canada
- Prior art keywords
- process according
- colloid
- aluminate
- synthetic polymer
- anionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000000084 colloidal system Substances 0.000 claims abstract description 47
- 125000000129 anionic group Chemical group 0.000 claims abstract description 35
- 125000002091 cationic group Chemical group 0.000 claims abstract description 32
- 150000004645 aluminates Chemical class 0.000 claims abstract description 26
- 229920001059 synthetic polymer Polymers 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 17
- 239000000725 suspension Substances 0.000 claims abstract description 7
- 239000001913 cellulose Substances 0.000 claims abstract description 5
- 229920002678 cellulose Polymers 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- 239000002245 particle Substances 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229920002873 Polyethylenimine Polymers 0.000 claims description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 2
- -1 aluminum modified silica sol Chemical class 0.000 claims description 2
- 229920000962 poly(amidoamine) Polymers 0.000 claims description 2
- 239000002344 surface layer Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 abstract description 8
- 238000007792 addition Methods 0.000 description 14
- 239000000123 paper Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229920006317 cationic polymer Polymers 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229910001388 sodium aluminate Inorganic materials 0.000 description 5
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 4
- 239000008119 colloidal silica Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 239000012764 mineral filler Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- 229910020284 Na2SO4.10H2O Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 235000012216 bentonite Nutrition 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 229940092782 bentonite Drugs 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000518994 Conta Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910003202 NH4 Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- ZEMWIYASLJTEHQ-UHFFFAOYSA-J aluminum;sodium;disulfate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZEMWIYASLJTEHQ-UHFFFAOYSA-J 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
- D21H17/45—Nitrogen-containing groups
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Making Paper Articles (AREA)
- Polarising Elements (AREA)
- Electronic Switches (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8803065-5 | 1988-09-01 | ||
| SE8803065A SE467627B (sv) | 1988-09-01 | 1988-09-01 | Saett vid framstaellning av papper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1334324C true CA1334324C (fr) | 1995-02-14 |
Family
ID=20373187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000609515A Expired - Lifetime CA1334324C (fr) | 1988-09-01 | 1989-08-28 | Procede de fabrication de papier |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0357574B1 (fr) |
| JP (1) | JP2521539B2 (fr) |
| AT (1) | ATE99010T1 (fr) |
| AU (1) | AU605997B2 (fr) |
| BR (1) | BR8904283A (fr) |
| CA (1) | CA1334324C (fr) |
| DE (1) | DE68911626T2 (fr) |
| ES (1) | ES2048323T3 (fr) |
| FI (1) | FI90448C (fr) |
| NO (1) | NO171567C (fr) |
| NZ (1) | NZ230427A (fr) |
| PT (1) | PT91611B (fr) |
| SE (1) | SE467627B (fr) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4795531A (en) * | 1987-09-22 | 1989-01-03 | Nalco Chemical Company | Method for dewatering paper |
| US4927498A (en) * | 1988-01-13 | 1990-05-22 | E. I. Du Pont De Nemours And Company | Retention and drainage aid for papermaking |
| SE500367C2 (sv) * | 1989-11-09 | 1994-06-13 | Eka Nobel Ab | Silikasoler och förfarande för framställning av papper |
| JP2521651B2 (ja) * | 1991-07-02 | 1996-08-07 | エカ ノーベル アクチェボラーグ | 紙の製造方法 |
| DE4437118A1 (de) * | 1994-10-05 | 1996-04-11 | Technocell Dekor Gmbh & Co Kg | Basispapier für dekorative Beschichtungssysteme |
| US5846384A (en) * | 1995-06-15 | 1998-12-08 | Eka Chemicals Ab | Process for the production of paper |
| SE9502184D0 (sv) * | 1995-06-15 | 1995-06-15 | Eka Nobel Ab | A process for the production of paper |
| US5595630A (en) * | 1995-08-31 | 1997-01-21 | E. I. Du Pont De Nemours And Company | Process for the manufacture of paper |
| SE9504081D0 (sv) * | 1995-11-15 | 1995-11-15 | Eka Nobel Ab | A process for the production of paper |
| US7169261B2 (en) | 1999-05-04 | 2007-01-30 | Akzo Nobel N.V. | Silica-based sols |
| WO2000066492A1 (fr) | 1999-05-04 | 2000-11-09 | Akzo Nobel N.V. | Sols a base de silice |
| US6379501B1 (en) | 1999-12-14 | 2002-04-30 | Hercules Incorporated | Cellulose products and processes for preparing the same |
| JP4206344B2 (ja) * | 2002-04-03 | 2009-01-07 | 星光Pmc株式会社 | 紙の製造方法及び歩留り向上剤 |
| FI121119B (fi) † | 2003-04-15 | 2010-07-15 | Kemira Oyj | Menetelmä paperin valmistamiseksi |
| US8245359B2 (en) | 2006-12-28 | 2012-08-21 | Tokyo Kinzoku Industry Co., Ltd. | Clip |
| CN103556532B (zh) * | 2013-10-31 | 2016-01-20 | 东莞理文造纸厂有限公司 | 一种造纸用助留剂及其制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE8403062L (sv) * | 1984-06-07 | 1985-12-08 | Eka Ab | Forfarande vid papperstillverkning |
| SE451739B (sv) * | 1985-04-03 | 1987-10-26 | Eka Nobel Ab | Papperstillverkningsforfarande och pappersprodukt varvid som avvattnings- och retentionsforbettrande kemikalie anvends katjonisk polyakrylamid och en speciell oorganisk kolloid |
| SE8701252D0 (sv) * | 1987-03-03 | 1987-03-25 | Eka Nobel Ab | Sett vid framstellning av papper |
| US4795531A (en) * | 1987-09-22 | 1989-01-03 | Nalco Chemical Company | Method for dewatering paper |
| US4927498A (en) * | 1988-01-13 | 1990-05-22 | E. I. Du Pont De Nemours And Company | Retention and drainage aid for papermaking |
| SE461156B (sv) * | 1988-05-25 | 1990-01-15 | Eka Nobel Ab | Saett foer framstaellning av papper varvid formning och avvattning aeger rum i naervaro av en aluminiumfoerening, ett katjoniskt retentionsmedel och en polymer kiselsyra |
-
1988
- 1988-09-01 SE SE8803065A patent/SE467627B/sv not_active IP Right Cessation
-
1989
- 1989-08-09 EP EP89850252A patent/EP0357574B1/fr not_active Expired - Lifetime
- 1989-08-09 DE DE89850252T patent/DE68911626T2/de not_active Expired - Lifetime
- 1989-08-09 AT AT89850252T patent/ATE99010T1/de not_active IP Right Cessation
- 1989-08-09 ES ES89850252T patent/ES2048323T3/es not_active Expired - Lifetime
- 1989-08-25 BR BR898904283A patent/BR8904283A/pt not_active IP Right Cessation
- 1989-08-25 NZ NZ230427A patent/NZ230427A/en unknown
- 1989-08-28 AU AU40840/89A patent/AU605997B2/en not_active Expired
- 1989-08-28 CA CA000609515A patent/CA1334324C/fr not_active Expired - Lifetime
- 1989-08-29 JP JP1220495A patent/JP2521539B2/ja not_active Expired - Lifetime
- 1989-08-30 FI FI894075A patent/FI90448C/fi active IP Right Grant
- 1989-08-31 NO NO893500A patent/NO171567C/no not_active IP Right Cessation
- 1989-09-01 PT PT91611A patent/PT91611B/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO171567C (no) | 1993-03-31 |
| BR8904283A (pt) | 1990-04-17 |
| PT91611A (pt) | 1990-03-30 |
| FI90448B (fi) | 1993-10-29 |
| FI894075L (fi) | 1990-03-02 |
| EP0357574A2 (fr) | 1990-03-07 |
| SE8803065D0 (sv) | 1988-09-01 |
| NZ230427A (en) | 1991-06-25 |
| FI894075A0 (fi) | 1989-08-30 |
| NO893500D0 (no) | 1989-08-31 |
| FI90448C (fi) | 1994-02-10 |
| ES2048323T3 (es) | 1994-03-16 |
| AU605997B2 (en) | 1991-01-24 |
| PT91611B (pt) | 1995-05-31 |
| ATE99010T1 (de) | 1994-01-15 |
| SE467627B (sv) | 1992-08-17 |
| DE68911626D1 (de) | 1994-02-03 |
| DE68911626T2 (de) | 1994-04-07 |
| SE8803065L (sv) | 1990-03-02 |
| AU4084089A (en) | 1990-03-29 |
| NO893500L (no) | 1990-03-02 |
| EP0357574A3 (fr) | 1991-10-23 |
| JP2521539B2 (ja) | 1996-08-07 |
| JPH0299692A (ja) | 1990-04-11 |
| EP0357574B1 (fr) | 1993-12-22 |
| NO171567B (no) | 1992-12-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |