CA1335331C - Recuperation de metaux non ferreux dans les scories provenant de l'elaboration metallurgique - Google Patents

Recuperation de metaux non ferreux dans les scories provenant de l'elaboration metallurgique

Info

Publication number: CA1335331C
Authority: CA; Canada
Prior art keywords: matte; slag; process according; furnace; ferrous metal
Prior art date: 1988-06-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA 568710

Other languages

English (en)

Inventor

Gary H. Kaiura

James F. Jackson

Richard O. Laine

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Glencore Canada Corp

Original Assignee

Falconbrige Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-06-06

Filing date

1988-06-06

Publication date

1995-04-25

1988-06-06 Application filed by Falconbrige Ltd filed Critical Falconbrige Ltd

1988-06-06 Priority to CA 568710 priority Critical patent/CA1335331C/fr

1995-04-25 Application granted granted Critical

1995-04-25 Publication of CA1335331C publication Critical patent/CA1335331C/fr

2012-04-25 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000002893 slag Substances 0.000 title claims abstract description 272
229910052751 metal Inorganic materials 0.000 title claims abstract description 101
239000002184 metal Substances 0.000 title claims abstract description 101
238000011084 recovery Methods 0.000 title claims abstract description 41
238000013019 agitation Methods 0.000 claims abstract description 61
238000003756 stirring Methods 0.000 claims abstract description 46
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 22
230000021715 photosynthesis, light harvesting Effects 0.000 claims abstract description 18
230000001590 oxidative effect Effects 0.000 claims abstract description 8
238000000034 method Methods 0.000 claims description 72
230000008569 process Effects 0.000 claims description 72
239000007789 gas Substances 0.000 claims description 60
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 56
239000003638 chemical reducing agent Substances 0.000 claims description 46
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 30
239000007787 solid Substances 0.000 claims description 27
229910052742 iron Inorganic materials 0.000 claims description 26
239000010410 layer Substances 0.000 claims description 17
229910000519 Ferrosilicon Inorganic materials 0.000 claims description 15
239000010941 cobalt Substances 0.000 claims description 15
229910017052 cobalt Inorganic materials 0.000 claims description 15
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 15
229910052759 nickel Inorganic materials 0.000 claims description 15
230000002829 reductive effect Effects 0.000 claims description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
238000002347 injection Methods 0.000 claims description 13
239000007924 injection Substances 0.000 claims description 13
SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 12
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 10
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
239000000839 emulsion Substances 0.000 claims description 10
239000000203 mixture Substances 0.000 claims description 10
239000001301 oxygen Substances 0.000 claims description 10
229910052760 oxygen Inorganic materials 0.000 claims description 10
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
229910052802 copper Inorganic materials 0.000 claims description 9
239000010949 copper Substances 0.000 claims description 9
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 9
229910052757 nitrogen Inorganic materials 0.000 claims description 7
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
229910052710 silicon Inorganic materials 0.000 claims description 6
239000010703 silicon Substances 0.000 claims description 6
229910002092 carbon dioxide Inorganic materials 0.000 claims description 5
239000001569 carbon dioxide Substances 0.000 claims description 5
238000000605 extraction Methods 0.000 claims description 5
230000005484 gravity Effects 0.000 claims description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
230000004907 flux Effects 0.000 claims description 4
229910044991 metal oxide Inorganic materials 0.000 claims description 4
150000004706 metal oxides Chemical class 0.000 claims description 4
229910052717 sulfur Inorganic materials 0.000 claims description 4
239000011593 sulfur Substances 0.000 claims description 4
238000010304 firing Methods 0.000 claims description 3
239000003345 natural gas Substances 0.000 claims description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
229910021529 ammonia Inorganic materials 0.000 claims description 2
229910052786 argon Inorganic materials 0.000 claims description 2
239000011575 calcium Substances 0.000 claims description 2
229910052791 calcium Inorganic materials 0.000 claims description 2
229910021346 calcium silicide Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
230000007935 neutral effect Effects 0.000 claims description 2
239000011241 protective layer Substances 0.000 claims description 2
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
229910010271 silicon carbide Inorganic materials 0.000 claims description 2
238000007599 discharging Methods 0.000 claims 2
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 claims 1
230000003647 oxidation Effects 0.000 abstract description 9
238000007254 oxidation reaction Methods 0.000 abstract description 9
238000001816 cooling Methods 0.000 abstract description 7
230000006735 deficit Effects 0.000 abstract description 3
206010001497 Agitation Diseases 0.000 description 57
238000004140 cleaning Methods 0.000 description 27
239000007788 liquid Substances 0.000 description 14
150000002739 metals Chemical class 0.000 description 13
239000012141 concentrate Substances 0.000 description 9
235000008504 concentrate Nutrition 0.000 description 9
230000009467 reduction Effects 0.000 description 7
238000003723 Smelting Methods 0.000 description 6
229910045601 alloy Inorganic materials 0.000 description 6
239000000956 alloy Substances 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
238000005187 foaming Methods 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
238000011282 treatment Methods 0.000 description 6
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
238000002156 mixing Methods 0.000 description 5
239000011819 refractory material Substances 0.000 description 5
230000000694 effects Effects 0.000 description 4
-1 ferrous metals Chemical class 0.000 description 4
230000002035 prolonged effect Effects 0.000 description 4
238000004458 analytical method Methods 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000011449 brick Substances 0.000 description 3
230000003628 erosive effect Effects 0.000 description 3
239000000463 material Substances 0.000 description 3
239000002245 particle Substances 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
229910000831 Steel Inorganic materials 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
230000009471 action Effects 0.000 description 2
238000007792 addition Methods 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
238000010891 electric arc Methods 0.000 description 2
230000001771 impaired effect Effects 0.000 description 2
239000000155 melt Substances 0.000 description 2
230000002688 persistence Effects 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
239000010959 steel Substances 0.000 description 2
150000003568 thioethers Chemical class 0.000 description 2
238000005406 washing Methods 0.000 description 2
229910001018 Cast iron Inorganic materials 0.000 description 1
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
229910000640 Fe alloy Inorganic materials 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
238000010923 batch production Methods 0.000 description 1
238000004581 coalescence Methods 0.000 description 1
229910000428 cobalt oxide Inorganic materials 0.000 description 1
239000000571 coke Substances 0.000 description 1
150000001875 compounds Chemical group 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
239000006260 foam Substances 0.000 description 1
239000004872 foam stabilizing agent Substances 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910001608 iron mineral Inorganic materials 0.000 description 1
238000000622 liquid--liquid extraction Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052976 metal sulfide Inorganic materials 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
230000002633 protecting effect Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
238000009877 rendering Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
238000010079 rubber tapping Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000002210 silicon-based material Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
238000009628 steelmaking Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0054—Slag, slime, speiss, or dross treating
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/025—Obtaining nickel or cobalt by dry processes with formation of a matte or by matte refining or converting into nickel or cobalt, e.g. by the Oxford process
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/04—Dry methods smelting of sulfides or formation of mattes by aluminium, other metals or silicon
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/06—Dry methods smelting of sulfides or formation of mattes by carbides or the like
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/04—Working-up slag
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Environmental & Geological Engineering (AREA)
General Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Manufacture And Refinement Of Metals (AREA)

CA 568710 1988-06-06 1988-06-06 Recuperation de metaux non ferreux dans les scories provenant de l'elaboration metallurgique Expired - Lifetime CA1335331C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA 568710 CA1335331C (fr)	1988-06-06	1988-06-06	Recuperation de metaux non ferreux dans les scories provenant de l'elaboration metallurgique

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA 568710 CA1335331C (fr)	1988-06-06	1988-06-06	Recuperation de metaux non ferreux dans les scories provenant de l'elaboration metallurgique

Publications (1)

Publication Number	Publication Date
CA1335331C true CA1335331C (fr)	1995-04-25

Family

ID=4138142

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 568710 Expired - Lifetime CA1335331C (fr)	1988-06-06	1988-06-06	Recuperation de metaux non ferreux dans les scories provenant de l'elaboration metallurgique

Country Status (1)

Country	Link
CA (1)	CA1335331C (fr)

1988
- 1988-06-06 CA CA 568710 patent/CA1335331C/fr not_active Expired - Lifetime

Legal Events

Date	Code	Title	Description
2012-04-25	MKEX	Expiry

Publication	Publication Date	Title
RU2476611C2 (ru)	2013-02-27	Извлечение металлов из отходов, содержащих медь и другие ценные металлы
US4085923A (en)	1978-04-25	Apparatus for a metallurgical process using oxygen
CA1088757A (fr)	1980-11-04	Procede d'extraction de nickel, nickel-cuivre, nickel- cobalt et nickel-cuivre-cobalt en presence dans des concentrations ou scories
CA1277840C (fr)	1990-12-18	Methode de reduction continue du laitier en fusion dans un four electrique
CA1159261A (fr)	1983-12-27	Methode et appareillage pour la recuperation pyrometallurique du cuivre
US4615729A (en)	1986-10-07	Flash smelting process
WO1997020954A1 (fr)	1997-06-12	Procede duplex simplifie de traitement de minerais et/ou concentres de nickel en vue de la production de ferronickels, de fers au nickel et d'aciers inoxydables
US4814004A (en)	1989-03-21	Non-ferrous metal recovery
JPH10158712A (ja)	1998-06-16	精製反応器中でニッケル合金化鉄浴を製造する方法
CA2098521C (fr)	1998-04-21	Procede pour la production de matte a haute teneur de nickel et de mattes sulfurees metallisees
US4521245A (en)	1985-06-04	Method of processing sulphide copper- and/or sulphide copper-zinc concentrates
JP2527914B2 (ja)	1996-08-28	非鉄硫化物の製錬
JPH0377857B2 (fr)	1991-12-11
RU2037543C1 (ru)	1995-06-19	Способ получения металлов и сплавов
US3988148A (en)	1976-10-26	Metallurgical process using oxygen
EP0007890B1 (fr)	1982-11-03	Procédé pour la production et le raffinage de plomb brut à partir de matières brutes plombifères contenant de l'arsenic
US3091524A (en)	1963-05-28	Metallurgical process
RU2105073C1 (ru)	1998-02-20	Способ обработки ванадиевого шлака
US3990889A (en)	1976-11-09	Metallurgical process using oxygen
US4108638A (en)	1978-08-22	Process for separating nickel, cobalt and copper
US4514222A (en)	1985-04-30	High intensity lead smelting process
CA2267325A1 (fr)	1998-03-26	Procede servant a raffiner du cuivre brut a teneur elevee en impuretes afin d'obtenir du cuivre anodique
US4334925A (en)	1982-06-15	Combined carburization and sulfurization/desulfurization of molybdenum-rich matte
US4274868A (en)	1981-06-23	Recovery of tin from ores or other materials
US4334924A (en)	1982-06-15	Pyrometallurgical oxidation of molybdenum rich matte