CA1338656C - Inhibiteur de corrosion et de tartre - Google Patents

Inhibiteur de corrosion et de tartre

Info

Publication number: CA1338656C
Authority: CA; Canada
Prior art keywords: parts; inhibitor; water; weight per; per million
Prior art date: 1987-04-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 535978

Other languages

English (en)

Inventor

Edward Samuel Beardwood

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

DREW CHEMICAL Ltd

Original Assignee

DREW CHEMICAL LIMITED

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-04-29

Filing date

1987-04-29

Publication date

1996-10-22

1987-04-29 Application filed by DREW CHEMICAL LIMITED filed Critical DREW CHEMICAL LIMITED

1987-04-29 Priority to CA 535978 priority Critical patent/CA1338656C/fr

1996-10-22 Application granted granted Critical

1996-10-22 Publication of CA1338656C publication Critical patent/CA1338656C/fr

2013-10-22 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000003112 inhibitor Substances 0.000 title claims abstract description 40
230000007797 corrosion Effects 0.000 title claims abstract description 32
238000005260 corrosion Methods 0.000 title claims abstract description 32
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 22
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract description 16
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims abstract description 12
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims abstract description 9
239000002455 scale inhibitor Substances 0.000 claims abstract description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
238000000034 method Methods 0.000 claims description 19
229920001897 terpolymer Polymers 0.000 claims description 19
125000000129 anionic group Chemical group 0.000 claims description 14
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 12
229920000058 polyacrylate Polymers 0.000 claims description 11
229920001577 copolymer Polymers 0.000 claims description 10
229920000642 polymer Polymers 0.000 claims description 10
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 9
230000015572 biosynthetic process Effects 0.000 claims description 8
230000002401 inhibitory effect Effects 0.000 claims description 8
229920000141 poly(maleic anhydride) Polymers 0.000 claims description 7
229920000193 polymethacrylate Polymers 0.000 claims description 6
150000003751 zinc Chemical class 0.000 claims description 6
229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 5
239000002270 dispersing agent Substances 0.000 claims 13
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 4
239000002253 acid Substances 0.000 claims 2
239000000203 mixture Substances 0.000 abstract description 17
239000011701 zinc Substances 0.000 abstract description 15
230000005764 inhibitory process Effects 0.000 abstract description 14
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 5
229910052725 zinc Inorganic materials 0.000 abstract description 5
239000002519 antifouling agent Substances 0.000 abstract 1
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 20
238000012360 testing method Methods 0.000 description 20
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 20
229910000019 calcium carbonate Inorganic materials 0.000 description 11
235000010216 calcium carbonate Nutrition 0.000 description 10
239000011592 zinc chloride Substances 0.000 description 10
235000005074 zinc chloride Nutrition 0.000 description 10
CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 9
229910015667 MoO4 Inorganic materials 0.000 description 9
PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 description 9
239000011684 sodium molybdate Substances 0.000 description 9
235000015393 sodium molybdate Nutrition 0.000 description 9
TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 9
229910052751 metal Inorganic materials 0.000 description 8
239000002184 metal Substances 0.000 description 8
239000003643 water by type Substances 0.000 description 8
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000001506 calcium phosphate Substances 0.000 description 5
229910000389 calcium phosphate Inorganic materials 0.000 description 5
235000011010 calcium phosphates Nutrition 0.000 description 5
238000001556 precipitation Methods 0.000 description 5
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 4
239000010949 copper Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
229910001209 Low-carbon steel Inorganic materials 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 3
229910052802 copper Inorganic materials 0.000 description 3
239000010959 steel Substances 0.000 description 3
239000011550 stock solution Substances 0.000 description 3
238000012546 transfer Methods 0.000 description 3
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
229920000388 Polyphosphate Polymers 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
239000001110 calcium chloride Substances 0.000 description 2
235000011148 calcium chloride Nutrition 0.000 description 2
229910001628 calcium chloride Inorganic materials 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
239000012535 impurity Substances 0.000 description 2
-1 molybdates Chemical class 0.000 description 2
239000001205 polyphosphate Substances 0.000 description 2
235000011176 polyphosphates Nutrition 0.000 description 2
239000000243 solution Substances 0.000 description 2
230000003068 static effect Effects 0.000 description 2
241001550224 Apha Species 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
244000104757 Viola obliqua Species 0.000 description 1
YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000005273 aeration Methods 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229960005070 ascorbic acid Drugs 0.000 description 1
235000010323 ascorbic acid Nutrition 0.000 description 1
239000011668 ascorbic acid Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
150000003851 azoles Chemical class 0.000 description 1
150000001558 benzoic acid derivatives Chemical class 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
229910000397 disodium phosphate Inorganic materials 0.000 description 1
235000019800 disodium phosphate Nutrition 0.000 description 1
NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
230000006698 induction Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
150000001455 metallic ions Chemical class 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
FVZVCSNXTFCBQU-UHFFFAOYSA-N phosphanyl Chemical group [PH2] FVZVCSNXTFCBQU-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
239000000047 product Substances 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
230000009919 sequestration Effects 0.000 description 1
108010080511 serum sodium transport inhibitor Proteins 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
235000017550 sodium carbonate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
238000012956 testing procedure Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
239000004246 zinc acetate Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Life Sciences & Earth Sciences (AREA)
Hydrology & Water Resources (AREA)
Environmental & Geological Engineering (AREA)
Water Supply & Treatment (AREA)
Preventing Corrosion Or Incrustation Of Metals (AREA)

CA 535978 1987-04-29 1987-04-29 Inhibiteur de corrosion et de tartre Expired - Fee Related CA1338656C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA 535978 CA1338656C (fr)	1987-04-29	1987-04-29	Inhibiteur de corrosion et de tartre

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA 535978 CA1338656C (fr)	1987-04-29	1987-04-29	Inhibiteur de corrosion et de tartre

Publications (1)

Publication Number	Publication Date
CA1338656C true CA1338656C (fr)	1996-10-22

Family

ID=4135544

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 535978 Expired - Fee Related CA1338656C (fr)	1987-04-29	1987-04-29	Inhibiteur de corrosion et de tartre

Country Status (1)

Country	Link
CA (1)	CA1338656C (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2331999A (en) *	1997-10-28	1999-06-09	Ibm	Copper preservative treatment using azoles
CN115074091A (zh) *	2022-07-08	2022-09-20	陶普斯化学科技(北京)有限公司	一种长效抗酸化高效能载冷剂及其制备方法
CN117736718A (zh) *	2022-09-22	2024-03-22	中国石油天然气股份有限公司	一种覆膜长效型多孔陶粒阻垢支撑剂、制备方法及应用

1987
- 1987-04-29 CA CA 535978 patent/CA1338656C/fr not_active Expired - Fee Related

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2331999A (en) *	1997-10-28	1999-06-09	Ibm	Copper preservative treatment using azoles
GB2331999B (en) *	1997-10-28	2003-01-22	Ibm	Copper preservative treatment
CN115074091A (zh) *	2022-07-08	2022-09-20	陶普斯化学科技(北京)有限公司	一种长效抗酸化高效能载冷剂及其制备方法
CN117736718A (zh) *	2022-09-22	2024-03-22	中国石油天然气股份有限公司	一种覆膜长效型多孔陶粒阻垢支撑剂、制备方法及应用

Legal Events

Date	Code	Title	Description
1999-10-22	MKLA	Lapsed

Publication	Publication Date	Title
US4303568A (en)	1981-12-01	Corrosion inhibition treatments and method
US4443340A (en)	1984-04-17	Control of iron induced fouling in water systems
TWI274071B (en)	2007-02-21	Scale and/or corrosion inhibiting composition
US4744949A (en)	1988-05-17	Method for preventing corrosion in aqueous systems
EP0077187B1 (fr)	1988-06-22	Procédé pour inhiber la corrosion et pour contrôler le dépôt dans un milieu aqueux
CN108623020A (zh)	2018-10-09	一种新型缓蚀阻垢剂及其制备方法与应用
US5320779A (en)	1994-06-14	Use of molybdate as corrosion inhibitor in a zinc/phosphonate cooling water treatment
KR101137459B1 (ko)	2012-04-20	금속의 부식 및 스케일 형성을 억제하는 수처리 방법
US4298568A (en)	1981-11-03	Method and composition for inhibiting corrosion of nonferrous metals in contact with water
EP0277412B1 (fr)	1992-05-06	Inhibition de la corrosion de métaux ferreux
JPS59193909A (ja)	1984-11-02	デポジツト制御方法およびその組成物
GB2231565A (en)	1990-11-21	The inhibition of corrosion in aqueous systems
CA1338656C (fr)	1996-10-22	Inhibiteur de corrosion et de tartre
KR20040053571A (ko)	2004-06-24	냉각시스템에서 금속 부식 및 스케일 형성을 억제하기위한 수처리 방법
EP0609590A1 (fr)	1994-08-10	Procédé d'inhibition de la corrosion de métaux à l'aide d'acides polytartriques
US3794603A (en)	1974-02-26	Zn++-benzotriazole-h2so4 corrosioninhibitor
KR100949354B1 (ko)	2010-03-26	고 전도도 수질에 적합한 수처리 방법
JPS62256973A (ja)	1987-11-09	金属腐蝕抑制と燐酸カルシウム沈澱防止のためのホスホン酸／燐酸塩混合物
CA1340659C (fr)	1999-07-20	Agent anti-tartre et anticorrosion
JP2003082479A (ja)	2003-03-19	防食剤及び方法
JPS6296683A (ja)	1987-05-06	水系における金属類のスケ−ル抑制を兼ねた腐食防止剤
KR101127157B1 (ko)	2012-03-20	냉각시스템용 스케일 형성 억제 수처리 방법
US4297317A (en)	1981-10-27	Low level chromate-based corrosion inhibition in aqueous mediums
US4329250A (en)	1982-05-11	Low level chromate-based corrosion inhibition in aqueous mediums
CA1339521C (fr)	1997-11-04	Substance et methode pour empecher la corrosion dans les systemes aqueux