CA1340348C - Procede de blanchiment pour la production de pates tres blanches - Google Patents

Procede de blanchiment pour la production de pates tres blanches

Info

Publication number: CA1340348C
Authority: CA; Canada
Prior art keywords: pulp; bleaching; stage; sodium; peroxygen
Prior art date: 1989-03-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000594763A

Other languages

English (en)

Inventor

Michel Barbe

Carole Gagne

Celine Leduc

Claude Daneault

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Voith Patent GmbH

Original Assignee

Kvaerner Canada Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-03-23

Filing date

1989-03-23

Publication date

1999-01-26

1989-03-23 Application filed by Kvaerner Canada Inc filed Critical Kvaerner Canada Inc

1989-03-23 Priority to CA000594763A priority Critical patent/CA1340348C/fr

1990-03-22 Priority to DE69009750T priority patent/DE69009750D1/de

1990-03-22 Priority to EP90905400A priority patent/EP0464110B1/fr

1990-03-22 Priority to AT90905400T priority patent/ATE106961T1/de

1990-03-22 Priority to PCT/CA1990/000097 priority patent/WO1990011403A1/fr

1999-01-26 Application granted granted Critical

1999-01-26 Publication of CA1340348C publication Critical patent/CA1340348C/fr

2016-01-26 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000004061 bleaching Methods 0.000 title claims abstract description 98
238000000034 method Methods 0.000 title claims abstract description 73
238000004519 manufacturing process Methods 0.000 title description 3
150000001875 compounds Chemical class 0.000 claims abstract description 30
239000003638 chemical reducing agent Substances 0.000 claims abstract description 29
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 35
238000006243 chemical reaction Methods 0.000 claims description 30
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 16
239000007844 bleaching agent Substances 0.000 claims description 13
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 12
229910052911 sodium silicate Inorganic materials 0.000 claims description 12
230000014759 maintenance of location Effects 0.000 claims description 11
239000004115 Sodium Silicate Substances 0.000 claims description 10
JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical group [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 10
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
238000005406 washing Methods 0.000 claims description 9
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
229910052943 magnesium sulfate Inorganic materials 0.000 claims description 8
235000019341 magnesium sulphate Nutrition 0.000 claims description 8
230000035484 reaction time Effects 0.000 claims description 8
229910052708 sodium Inorganic materials 0.000 claims description 8
239000011734 sodium Substances 0.000 claims description 8
239000012279 sodium borohydride Substances 0.000 claims description 8
229910000033 sodium borohydride Inorganic materials 0.000 claims description 8
239000002738 chelating agent Substances 0.000 claims description 7
239000000126 substance Substances 0.000 claims description 7
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 6
239000006227 byproduct Substances 0.000 claims description 6
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
-1 compound sodium hydroxide Chemical class 0.000 claims description 4
239000007864 aqueous solution Substances 0.000 claims description 3
KQNZLOUWXSAZGD-UHFFFAOYSA-N benzylperoxymethylbenzene Chemical compound C=1C=CC=CC=1COOCC1=CC=CC=C1 KQNZLOUWXSAZGD-UHFFFAOYSA-N 0.000 claims description 3
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 3
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
XQIMLPCOVYNASM-UHFFFAOYSA-N borole Chemical compound B1C=CC=C1 XQIMLPCOVYNASM-UHFFFAOYSA-N 0.000 claims description 2
LPHFLPKXBKBHRW-UHFFFAOYSA-L magnesium;hydrogen sulfite Chemical compound [Mg+2].OS([O-])=O.OS([O-])=O LPHFLPKXBKBHRW-UHFFFAOYSA-L 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
PENRVBJTRIYHOA-UHFFFAOYSA-L zinc dithionite Chemical compound [Zn+2].[O-]S(=O)S([O-])=O PENRVBJTRIYHOA-UHFFFAOYSA-L 0.000 claims description 2
239000012530 fluid Substances 0.000 claims 6
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims 2
239000000391 magnesium silicate Substances 0.000 claims 2
229910052919 magnesium silicate Inorganic materials 0.000 claims 2
235000019792 magnesium silicate Nutrition 0.000 claims 2
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 claims 1
230000006641 stabilisation Effects 0.000 claims 1
238000011105 stabilization Methods 0.000 claims 1
150000002978 peroxides Chemical class 0.000 description 30
229940124024 weight reducing agent Drugs 0.000 description 20
238000002474 experimental method Methods 0.000 description 11
239000007800 oxidant agent Substances 0.000 description 8
229920001131 Pulp (paper) Polymers 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
235000007173 Abies balsamea Nutrition 0.000 description 6
239000004857 Balsam Substances 0.000 description 6
244000018716 Impatiens biflora Species 0.000 description 6
241000218657 Picea Species 0.000 description 6
238000002156 mixing Methods 0.000 description 5
GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
238000003825 pressing Methods 0.000 description 3
235000019832 sodium triphosphate Nutrition 0.000 description 3
239000000243 solution Substances 0.000 description 3
238000012546 transfer Methods 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 2
238000006073 displacement reaction Methods 0.000 description 2
239000000835 fiber Substances 0.000 description 2
229910021645 metal ion Inorganic materials 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
238000004076 pulp bleaching Methods 0.000 description 2
235000019795 sodium metasilicate Nutrition 0.000 description 2
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
PKPBCVSCCPTDIU-UHFFFAOYSA-N B.P Chemical class B.P PKPBCVSCCPTDIU-UHFFFAOYSA-N 0.000 description 1
101100310928 Caenorhabditis elegans sra-6 gene Proteins 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
101000713585 Homo sapiens Tubulin beta-4A chain Proteins 0.000 description 1
241000243251 Hydra Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
FOQXTRLJMXMESG-UHFFFAOYSA-N OS(=O)S(O)=O.OS(=O)S(O)=O Chemical compound OS(=O)S(O)=O.OS(=O)S(O)=O FOQXTRLJMXMESG-UHFFFAOYSA-N 0.000 description 1
102100036788 Tubulin beta-4A chain Human genes 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
229910000085 borane Inorganic materials 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
238000007865 diluting Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000013505 freshwater Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
238000009897 hydrogen peroxide bleaching Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 description 1
PXUQTDZNOHRWLI-OXUVVOBNSA-O malvidin 3-O-beta-D-glucoside Chemical compound COC1=C(O)C(OC)=CC(C=2C(=CC=3C(O)=CC(O)=CC=3[O+]=2)O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)=C1 PXUQTDZNOHRWLI-OXUVVOBNSA-O 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
238000009896 oxidative bleaching Methods 0.000 description 1
LQPLDXQVILYOOL-UHFFFAOYSA-I pentasodium;2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O LQPLDXQVILYOOL-UHFFFAOYSA-I 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
239000013055 pulp slurry Substances 0.000 description 1
238000004537 pulping Methods 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16

Landscapes

Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Wood Science & Technology (AREA)
Paper (AREA)
Detergent Compositions (AREA)
Treatment Of Fiber Materials (AREA)

CA000594763A 1989-03-23 1989-03-23 Procede de blanchiment pour la production de pates tres blanches Expired - Fee Related CA1340348C (fr)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
CA000594763A CA1340348C (fr)	1989-03-23	1989-03-23	Procede de blanchiment pour la production de pates tres blanches
DE69009750T DE69009750D1 (de)	1989-03-23	1990-03-22	Bleichverfahren zur herstellung von hochweissem zellstoff.
EP90905400A EP0464110B1 (fr)	1989-03-23	1990-03-22	Procede de blanchiment servant a la production de pulpes tres claires
AT90905400T ATE106961T1 (de)	1989-03-23	1990-03-22	Bleichverfahren zur herstellung von hochweissem zellstoff.
PCT/CA1990/000097 WO1990011403A1 (fr)	1989-03-23	1990-03-22	Procede de blanchiment servant a la production de pulpes tres claires

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000594763A CA1340348C (fr)	1989-03-23	1989-03-23	Procede de blanchiment pour la production de pates tres blanches

Publications (1)

Publication Number	Publication Date
CA1340348C true CA1340348C (fr)	1999-01-26

Family

ID=4139806

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000594763A Expired - Fee Related CA1340348C (fr)	1989-03-23	1989-03-23	Procede de blanchiment pour la production de pates tres blanches

Country Status (5)

Country	Link
EP (1)	EP0464110B1 (fr)
AT (1)	ATE106961T1 (fr)
CA (1)	CA1340348C (fr)
DE (1)	DE69009750D1 (fr)
WO (1)	WO1990011403A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
USH1690H (en) *	1995-07-20	1997-11-04	Nye; Jeffrey	Process for bleaching kraft pulp
FI105932B (fi) *	1996-05-30	2000-10-31	Kemira Chemicals Oy	Menetelmä korkeasaanto- tai kierrätysmassan valkaisemiseksi
US20030062138A1 (en) *	2001-05-09	2003-04-03	Hache Maurice Joseph Albert	Method for brightening mechanical pulps
EP1418269B1 (fr) *	2002-11-05	2009-02-11	Rohm And Haas Company	Procédé de blanchiment des pates mecaniques
FI122239B (fi)	2004-02-25	2011-10-31	Kemira Oyj	Menetelmä kuitumateriaalin käsittelemiseksi ja uusi koostumus
FI120201B (fi)	2004-05-12	2009-07-31	Kemira Oyj	Uusi koostumus ja menetelmä kuitumateriaalin käsittelemiseksi
US7967948B2 (en)	2006-06-02	2011-06-28	International Paper Company	Process for non-chlorine oxidative bleaching of mechanical pulp in the presence of optical brightening agents
US20100224333A1 (en)	2009-03-09	2010-09-09	Prasad Duggirala	Method and chemical composition to improve efficiency of mechanical pulp
US9932709B2 (en)	2013-03-15	2018-04-03	Ecolab Usa Inc.	Processes and compositions for brightness improvement in paper production
CN104237211B (zh) *	2014-09-23	2016-09-28	中国科学院长春应用化学研究所	一种鲁米诺化学发光体系和鲁米诺、二氧化硫脲、钴离子浓度的测定方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1249402A (fr) *	1984-12-21	1989-01-31	Pulp And Paper Research Institute Of Canada	Avivage multi-etage des pates a fort et tres fort rendement
SE8600615L (sv) *	1985-02-15	1986-08-16	Kamyr Ab	Hog ljushet astadkommes genom blekning av mekanisk massa, sasom kemisk-mekanisk massa (cmp), kemisk-termisk-mekanisk massa (ctmp) och liknande

1989
- 1989-03-23 CA CA000594763A patent/CA1340348C/fr not_active Expired - Fee Related
1990
- 1990-03-22 DE DE69009750T patent/DE69009750D1/de not_active Expired - Lifetime
- 1990-03-22 EP EP90905400A patent/EP0464110B1/fr not_active Expired - Lifetime
- 1990-03-22 AT AT90905400T patent/ATE106961T1/de not_active IP Right Cessation
- 1990-03-22 WO PCT/CA1990/000097 patent/WO1990011403A1/fr not_active Ceased

Also Published As

Publication number	Publication date
EP0464110B1 (fr)	1994-06-08
DE69009750D1 (de)	1994-07-14
WO1990011403A1 (fr)	1990-10-04
EP0464110A1 (fr)	1992-01-08
ATE106961T1 (de)	1994-06-15

Legal Events

Date	Code	Title	Description
2008-01-28	MKLA	Lapsed

Publication	Publication Date	Title
US5785812A (en)	1998-07-28	Process for treating oxygen delignified pulp using an organic peracid or salt, complexing agent and peroxide bleach sequence
US4804440A (en)	1989-02-14	Multistage brightening of high yield and ultra high-yield wood pulps
CA1137257A (fr)	1982-12-14	Blanchiment a l'ozone
CA1340348C (fr)	1999-01-26	Procede de blanchiment pour la production de pates tres blanches
CN101443514A (zh)	2009-05-27	漂白纸浆的制备方法
US3874992A (en)	1975-04-01	Press alkaline extraction of cellulosic pulp
NO178079B (no)	1995-10-09	Fremgangsmåte ved bleking av dissolving-masse
NO143298B (no)	1980-10-06	Friserapparat.
AU2003216028B2 (en)	2006-03-16	Process for bleaching lignocellulose-containing non-wood pulp
US6019870A (en)	2000-02-01	Process for the preparation of delignified and bleached chemical paper pulps
CA1221809A (fr)	1987-05-19	Defibrage de la pate chimique
CA2869351C (fr)	2020-01-07	Procede de blanchiment de pate a papier
CA2398312C (fr)	2005-05-03	Procede de blanchiment
NZ242356A (en)	1994-06-27	Process for preparing bleached paper pulp comprising: treating chips with a reducing agent, then alkaline hydrogen peroxide, followed by refining
CA1275759C (fr)	1990-11-06	Methode et dispositif de defibrage alcalin des matieres cellulosiques
FI75374C (fi)	1988-06-09	Hypokloritbehandling av kemiska pappersmassor.
CA1174013A (fr)	1984-09-11	Methode d'usage en fabrication de la pate mecanique
US20090242152A1 (en)	2009-10-01	Bleaching process of chemical pulp
US20120031575A1 (en)	2012-02-09	Pulp Bleaching and Alkaline Extraction Method
US20080087390A1 (en)	2008-04-17	Multi-step pulp bleaching
US3817825A (en)	1974-06-18	Bleaching and refining process for producing dissolving pulps
NO884398L (no)	1989-04-06	Fremgangsmaate for bleking av mekanisk masse.
WO1988001661A1 (fr)	1988-03-10	Procede de blanchiment de pulpes
EP0960235B1 (fr)	2002-04-24	Procede de delignification a l'oxygene de pate a papier
CA1268906A (fr)	1990-05-15	Defibrage de la pate au sulfate