CA2000351A1 - Methode et appareil de declenchement de reactions chimiques - Google Patents
Methode et appareil de declenchement de reactions chimiquesInfo
- Publication number
- CA2000351A1 CA2000351A1 CA2000351A CA2000351A CA2000351A1 CA 2000351 A1 CA2000351 A1 CA 2000351A1 CA 2000351 A CA2000351 A CA 2000351A CA 2000351 A CA2000351 A CA 2000351A CA 2000351 A1 CA2000351 A1 CA 2000351A1
- Authority
- CA
- Canada
- Prior art keywords
- feed
- chemical reactions
- reactants
- microwave heating
- section
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/80—Apparatus for specific applications
- H05B6/806—Apparatus for specific applications for laboratory use
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/126—Microwaves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/6447—Method of operation or details of the microwave heating apparatus related to the use of detectors or sensors
- H05B6/645—Method of operation or details of the microwave heating apparatus related to the use of detectors or sensors using temperature sensors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00065—Pressure measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00132—Controlling the temperature using electric heating or cooling elements
- B01J2219/00137—Peltier cooling elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
- B01J2219/1206—Microwaves
- B01J2219/1209—Features relating to the reactor or vessel
- B01J2219/1221—Features relating to the reactor or vessel the reactor per se
- B01J2219/1224—Form of the reactor
- B01J2219/1227—Reactors comprising tubes with open ends
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Clinical Laboratory Science (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPJ087288 | 1988-10-10 | ||
| AUPJ0872 | 1988-10-10 | ||
| AUPJ5057 | 1989-07-04 | ||
| AUPJ505789 | 1989-07-04 | ||
| US07/892,996 US5387397A (en) | 1988-10-10 | 1992-06-03 | Method and apparatus for continuous chemical reactions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2000351A1 true CA2000351A1 (fr) | 1990-04-10 |
| CA2000351C CA2000351C (fr) | 1999-11-30 |
Family
ID=27157459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002000351A Expired - Fee Related CA2000351C (fr) | 1988-10-10 | 1989-10-10 | Methode et appareil de declenchement de reactions chimiques |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5387397A (fr) |
| EP (1) | EP0437480B1 (fr) |
| AT (1) | ATE112978T1 (fr) |
| CA (1) | CA2000351C (fr) |
| DE (1) | DE68918950T2 (fr) |
| WO (1) | WO1990003840A1 (fr) |
Families Citing this family (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2665264A1 (fr) * | 1990-07-24 | 1992-01-31 | Prolabo Sa | Procede pour realiser une reaction chimique par voie humide sur une succession d'echantillons, appareil pour la mise en óoeuvre du procede et utilisation dudit appareil. |
| FR2697448B1 (fr) * | 1992-10-30 | 1995-06-16 | Moulinex Sa | Dispositif de conduite d'opérations chimiques. |
| US5420039A (en) * | 1992-12-31 | 1995-05-30 | Cem Corporation | Control of continuous microwave digestion process |
| NZ265292A (en) * | 1993-05-05 | 1997-07-27 | Ciba Geigy Ag | Oven and associated processing equipment for heating epoxy resin above its gelation temperature with decoupled electromagnetic heating units |
| AU6690194A (en) * | 1993-05-11 | 1994-12-12 | Srl Inc. | Microwave irradiation method and microwave irradiation device |
| ATE168039T1 (de) * | 1993-11-11 | 1998-07-15 | Werner Lautenschlaeger | Vorrichtung zum auslösen und/oder fördern chemischer oder physikalischer prozesse in einem material, insbesondere probenmaterial |
| US5470541A (en) * | 1993-12-28 | 1995-11-28 | E. I. Du Pont De Nemours And Company | Apparatus and process for the preparation of hydrogen cyanide |
| US5689008A (en) * | 1996-02-02 | 1997-11-18 | United Technologies Corporation | Catalytic reaction rate enhancement at low temperatures |
| DE19631201C2 (de) * | 1996-08-02 | 2001-07-05 | Rainer Buchholz | Verfahren und Reaktor zur Umwandlung von Biomasse in flüssige, feste oder gasförmige Brennstoffe und Chemierohstoffe |
| ES2313752T3 (es) | 1997-08-20 | 2009-03-01 | The University Of Miami | Un metodo de fijacion-deshidratacion-eliminacion de grasa-impregnacion de tejidos de produccion continua, de alta calidad. |
| US6793890B2 (en) | 1997-08-20 | 2004-09-21 | The University Of Miami | Rapid tissue processor |
| US6031100A (en) * | 1997-09-18 | 2000-02-29 | Bayer Corporation | Microwave syntheses of quinacridones, 6,13-Dihydroquinacridones, and 6,13-quinacridonequinones |
| US6084226A (en) * | 1998-04-21 | 2000-07-04 | Cem Corporation | Use of continuously variable power in microwave assisted chemistry |
| US6175037B1 (en) | 1998-10-09 | 2001-01-16 | Ucb, S.A. | Process for the preparation of (meth)acrylate esters and polyester (meth)acrylates using microwave energy as a heating source |
| FR2791670A1 (fr) * | 1999-03-31 | 2000-10-06 | Rhodia Chimie Sa | Procede d'activation de substrats aromatiques par micro-ondes |
| KR100411194B1 (ko) * | 2000-11-03 | 2003-12-18 | 한국화학연구원 | 연속식 마이크로파 합성법을 이용한 무기소재의 제조방법및 그 장치 |
| DK1282878T3 (da) | 2000-05-08 | 2004-05-17 | Personal Chemistry I Uppsala | Fremgangsmåde til udförelse af en flerhed af kemiske reaktioner og et kit og et system dertil |
| US20030091487A1 (en) * | 2001-10-19 | 2003-05-15 | Magnus Fagrell | Continuous flow heating system |
| WO2003041856A1 (fr) * | 2001-10-19 | 2003-05-22 | Personal Chemistry I Uppsala Ab | Systeme a ecoulement continu avec chauffage a micro-ondes |
| FR2839069B1 (fr) * | 2002-04-25 | 2006-04-07 | Satie Sa | Nouveaux procedes de transesterification, esterification, interesterification, par chauffage dielectrique |
| US6744024B1 (en) | 2002-06-26 | 2004-06-01 | Cem Corporation | Reaction and temperature control for high power microwave-assisted chemistry techniques |
| US6867400B2 (en) * | 2002-07-31 | 2005-03-15 | Cem Corporation | Method and apparatus for continuous flow microwave-assisted chemistry techniques |
| US7157401B2 (en) * | 2002-10-17 | 2007-01-02 | Carnegie Mellon University | Catalyst for the treatment of organic compounds |
| US20040074760A1 (en) * | 2002-10-17 | 2004-04-22 | Carnegie Mellon University | Production of biofuels |
| US7387712B2 (en) * | 2002-10-17 | 2008-06-17 | Carnegie Mellon University | Catalytic process for the treatment of organic compounds |
| WO2004054707A1 (fr) * | 2002-12-18 | 2004-07-01 | Biotage Ab | Procede et appareil permettant de controler des reactions chimiques |
| DE60220554T2 (de) * | 2002-12-19 | 2008-02-14 | Council Of Scientific & Industrial Research | Mikrowelleninduzierter prozess zur herstellung von substituierten 4-vinylphenolen |
| FR2849343B1 (fr) * | 2002-12-23 | 2009-01-23 | Aldivia | Synthese chimique comportant un traitement thermique par chauffage dielectrique intermittent, combine a un systeme de recirculation |
| US7393920B2 (en) * | 2003-06-23 | 2008-07-01 | Cem Corporation | Microwave-assisted peptide synthesis |
| FR2858616B1 (fr) * | 2003-08-07 | 2006-02-17 | Aldivia Sa | Procede d'estolidation par chauffage dielectrique |
| US7041947B2 (en) * | 2003-09-02 | 2006-05-09 | Cem Corporation | Controlled flow instrument for microwave assisted chemistry with high viscosity liquids and heterogeneous mixtures |
| US6989519B2 (en) | 2003-09-02 | 2006-01-24 | Cem Corporation | Controlled flow instrument for microwave assisted chemistry with high viscosity liquids and heterogeneous mixtures |
| US7470401B2 (en) * | 2003-10-24 | 2008-12-30 | The University Of Miami | Simplified tissue processing |
| EE200400060A (et) * | 2004-02-25 | 2005-10-17 | Nordic Alternative Energy OÜ | Meetod ja seade karboksüülhapete estrite pidevaprotsessiliseks transesterifikatsioonikssuperkriitilises monovalentses alkoholis |
| US20050274065A1 (en) * | 2004-06-15 | 2005-12-15 | Carnegie Mellon University | Methods for producing biodiesel |
| JPWO2006126439A1 (ja) * | 2005-05-24 | 2008-12-25 | 日立化成工業株式会社 | 共役ポリマーの製造方法 |
| KR100693126B1 (ko) * | 2005-07-14 | 2007-03-13 | 한국화학연구원 | 다공성 물질 및 혼합 금속산화물의 연속적 제조방법 및연속적 제조 장치 |
| GB0608512D0 (en) | 2006-04-28 | 2006-06-07 | Vincent Processes Ltd | Process for the production of esters of sugars and sugar derivatives |
| US7998418B1 (en) | 2006-06-01 | 2011-08-16 | Nanotek, Llc | Evaporator and concentrator in reactor and loading system |
| US7641860B2 (en) * | 2006-06-01 | 2010-01-05 | Nanotek, Llc | Modular and reconfigurable multi-stage microreactor cartridge apparatus |
| US7854902B2 (en) * | 2006-08-23 | 2010-12-21 | Nanotek, Llc | Modular and reconfigurable multi-stage high temperature microreactor cartridge apparatus and system for using same |
| DE102006047619B4 (de) * | 2006-10-09 | 2008-11-13 | Clariant International Limited | Verfahren zur Herstellung basischer Fettsäureamide |
| DE102006047617B4 (de) | 2006-10-09 | 2008-11-27 | Clariant International Limited | Verfahren zur Herstellung basischer (Meth)acrylamide |
| WO2008118808A1 (fr) | 2007-03-23 | 2008-10-02 | Advion Bioscience, Inc. | Système de spectrométrie de masse et de chromatographie liquide |
| DE102008017216B4 (de) | 2008-04-04 | 2013-08-14 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Fettsäureamiden |
| DE102008017217A1 (de) * | 2008-04-04 | 2009-10-08 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Amiden aromatischer Carbonsäuren |
| DE102008017213B4 (de) * | 2008-04-04 | 2012-08-09 | Clariant International Limited | Kontinuierliches Verfahren zur Herstellung von Amiden aliphatischer Hydroxycarbonsäuren |
| DE102008017215B4 (de) * | 2008-04-04 | 2012-08-09 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Amiden ethylenisch ungesättigter Carbonsäuren |
| DE102008017219A1 (de) * | 2008-04-04 | 2009-10-08 | Clariant International Ltd. | Verfahren zur Herstellung von Amiden in Gegenwart von überhitztem Wasser |
| DE102008017218B4 (de) * | 2008-04-04 | 2011-09-22 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Amiden niederer aliphatischer Carbonsäuren |
| DE102008017214B4 (de) * | 2008-04-04 | 2012-02-16 | Clariant International Limited | Kontinuierliches Verfahren zur Herstellung von Fettsäurealkanolamiden |
| US20090298172A1 (en) | 2008-05-28 | 2009-12-03 | Steven Paul Wheeler | Histological specimen treatment apparatus and method |
| HRP20150147T1 (hr) * | 2008-09-23 | 2015-05-08 | Aseptia, Inc. | Elektromagnetski sustav |
| US20120108818A1 (en) * | 2009-01-26 | 2012-05-03 | Cambrex Karlskoga Ab | Microwave apparatus |
| JP5107278B2 (ja) * | 2009-02-16 | 2012-12-26 | 株式会社日立製作所 | マイクロ波加熱装置および加熱方法 |
| DE102009031057A1 (de) * | 2009-06-30 | 2011-01-05 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Amiden aliphatischer Carbonsäuren |
| DE102009031056A1 (de) * | 2009-06-30 | 2011-01-27 | Clariant International Ltd. | Kontinuierliches Verfahren zur Acrylierung von Aminogruppen tragenden organischen Säuren |
| DE102009031054A1 (de) * | 2009-06-30 | 2011-01-13 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Estern aromatischer Carbonsäuren |
| DE102009031053A1 (de) * | 2009-06-30 | 2011-01-13 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Estern aliphatischer Carbonsäuren |
| DE102009031059A1 (de) | 2009-06-30 | 2011-01-05 | Clariant International Ltd. | Vorrichtung zur kontinuierlichen Durchführung chemischer Reaktionen bei hohen Temperaturen |
| DE102009031058A1 (de) | 2009-06-30 | 2011-01-27 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Amiden aromatischer Carbonsäuren |
| DE102009033216A1 (de) | 2009-07-15 | 2011-01-27 | Brümmer, Heinz | Vorrichtung und Verfahren zur Herstellung von Leichtölen aus Biomasse und kohlenwasserstoffhaltigen Stoffen mittels Verpressen der Reaktionsmasse zusammen mit einem zeolithischen Katalysator als Reaktionsbeschleuniger zu Pellets und anschließender Molekülverkürzung der Reaktionsmasse durch von Mikrowellenstrahlung initiiertem Plasma in einem Flachbettreaktor |
| DE102009042522A1 (de) | 2009-09-22 | 2011-04-07 | Clariant International Ltd. | Kontinuierliches Umesterungsverfahren |
| DE102009042523B4 (de) | 2009-09-22 | 2012-02-16 | Clariant International Ltd. | Vorrichtung und Verfahren zur kontinuierlichen Durchführung heterogen katalysierter chemischer Reaktionen bei hohen Temperaturen |
| DE102010056565A1 (de) | 2010-12-30 | 2012-07-05 | Clariant International Ltd. | Verfahren zur Modifizierung Hydroxylgruppen tragender Polymere |
| DE102010056566A1 (de) | 2010-12-30 | 2012-07-05 | Clariant International Ltd. | Kontinuierliches Verfahren zur Veresterung Säuregruppen tragender Polymere |
| DE102010056564A1 (de) | 2010-12-30 | 2012-07-05 | Clariant International Limited | Hydroxylgruppen und Estergruppen tragende Polymere und Verfahren zu ihrer Herstellung |
| CN102260170B (zh) * | 2011-06-02 | 2014-10-15 | 浙江大学 | 微波管道化生产乙酸正t酯的方法 |
| ES2573280T3 (es) * | 2012-02-28 | 2016-06-07 | Inventram Fikri Mulkiyet Haklari Yonetim Ticaret Ve Yatirim Anonim Sirketi | Conjunto de preparación de revestimiento de zeolita y procedimiento de funcionamiento |
| US10450259B2 (en) | 2013-06-26 | 2019-10-22 | University Of Virginia Patent Foundation | Compositions and methods for hydrocarbon functionalization |
| EP3006103A1 (fr) * | 2014-10-06 | 2016-04-13 | Paul Scherrer Institut | Procédé pour produire des structures organométalliques et structures organiques covalentes |
| US10365189B2 (en) | 2015-05-07 | 2019-07-30 | Steven Wheeler | Histological specimen treatment |
| EP4045182A1 (fr) * | 2019-11-04 | 2022-08-24 | Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. | Procédé assisté par micro-ondes de synthèse d'oligosaccharides et de polysaccharides sur phase solide |
| CN111117676B (zh) * | 2020-01-19 | 2025-06-24 | 中国林业科学研究院林产化学工业研究所 | 一种微波连续调频协同生物质定向解聚装置及其使用方法 |
| CN116520712B (zh) * | 2023-07-03 | 2023-08-22 | 贵阳职业技术学院 | 一种反应容器入料量自适应调控方法、系统、终端及介质 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3535482A (en) * | 1968-06-26 | 1970-10-20 | Hammtronics Systems Inc | Microwave apparatus for rapid heating of fluids |
| GB1371400A (en) * | 1972-06-14 | 1974-10-23 | Camph Eng Co Ab | Method of heating blood |
| NL7509305A (nl) * | 1974-08-07 | 1976-02-10 | British Petroleum Co | Werkwijze voor het tot stand brengen van chemische reacties. |
| AU521896B2 (en) * | 1976-11-17 | 1982-05-06 | Jean, O.A.L. | Apparatus for subjecting a material to electromagnetic waves |
| AU7556981A (en) * | 1976-12-23 | 1981-12-24 | Kenneth Frederick Currie | Irradiation unit |
| US4353890A (en) * | 1979-10-24 | 1982-10-12 | Colgate-Palmolive Company | Stabilization of carrageenan-containing toothpaste |
| GB2098040A (en) * | 1981-03-31 | 1982-11-10 | Sanyo Electric Co | System for and method of sterilization of food material |
-
1989
- 1989-10-09 EP EP89911229A patent/EP0437480B1/fr not_active Expired - Lifetime
- 1989-10-09 AT AT89911229T patent/ATE112978T1/de not_active IP Right Cessation
- 1989-10-09 DE DE68918950T patent/DE68918950T2/de not_active Expired - Fee Related
- 1989-10-09 WO PCT/AU1989/000437 patent/WO1990003840A1/fr not_active Ceased
- 1989-10-10 CA CA002000351A patent/CA2000351C/fr not_active Expired - Fee Related
-
1992
- 1992-06-03 US US07/892,996 patent/US5387397A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0437480B1 (fr) | 1994-10-19 |
| ATE112978T1 (de) | 1994-11-15 |
| EP0437480A4 (en) | 1991-10-30 |
| WO1990003840A1 (fr) | 1990-04-19 |
| DE68918950D1 (de) | 1994-11-24 |
| CA2000351C (fr) | 1999-11-30 |
| EP0437480A1 (fr) | 1991-07-24 |
| US5387397A (en) | 1995-02-07 |
| DE68918950T2 (de) | 1995-03-16 |
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