CA2000572A1 - Procede de pultrusion a injection de resine de condensation - Google Patents
Procede de pultrusion a injection de resine de condensationInfo
- Publication number
- CA2000572A1 CA2000572A1 CA002000572A CA2000572A CA2000572A1 CA 2000572 A1 CA2000572 A1 CA 2000572A1 CA 002000572 A CA002000572 A CA 002000572A CA 2000572 A CA2000572 A CA 2000572A CA 2000572 A1 CA2000572 A1 CA 2000572A1
- Authority
- CA
- Canada
- Prior art keywords
- die
- resin
- injection
- strands
- section
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 166
- 239000011347 resin Substances 0.000 title claims abstract description 166
- 238000002347 injection Methods 0.000 title claims abstract description 61
- 239000007924 injection Substances 0.000 title claims abstract description 61
- 238000009833 condensation Methods 0.000 title claims abstract description 21
- 230000005494 condensation Effects 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 30
- 239000000178 monomer Substances 0.000 claims abstract description 14
- 239000012779 reinforcing material Substances 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 9
- 230000006978 adaptation Effects 0.000 claims abstract description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 16
- 239000005011 phenolic resin Substances 0.000 claims description 15
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 10
- 230000007935 neutral effect Effects 0.000 claims description 10
- 238000005470 impregnation Methods 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims 1
- 230000007704 transition Effects 0.000 abstract description 13
- 230000008569 process Effects 0.000 abstract description 12
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 5
- 230000008859 change Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 46
- 235000013824 polyphenols Nutrition 0.000 description 29
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 24
- 238000006116 polymerization reaction Methods 0.000 description 15
- 230000003014 reinforcing effect Effects 0.000 description 15
- 239000011152 fibreglass Substances 0.000 description 12
- 230000035515 penetration Effects 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 239000003518 caustics Substances 0.000 description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 7
- 229910000077 silane Inorganic materials 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000032798 delamination Effects 0.000 description 6
- 229920001225 polyester resin Polymers 0.000 description 5
- 239000004645 polyester resin Substances 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- POYODSZSSBWJPD-UHFFFAOYSA-N 2-methylprop-2-enoyloxy 2-methylprop-2-eneperoxoate Chemical group CC(=C)C(=O)OOOC(=O)C(C)=C POYODSZSSBWJPD-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000026058 directional locomotion Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
- B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
- B29C70/523—Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement in the die
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2061/00—Use of condensation polymers of aldehydes or ketones or derivatives thereof, as moulding material
- B29K2061/04—Phenoplasts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Moulding By Coating Moulds (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25751488A | 1988-10-13 | 1988-10-13 | |
| US07/257,514 | 1988-10-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2000572A1 true CA2000572A1 (fr) | 1990-04-13 |
Family
ID=22976615
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002000572A Abandoned CA2000572A1 (fr) | 1988-10-13 | 1989-10-12 | Procede de pultrusion a injection de resine de condensation |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0403607A4 (fr) |
| JP (1) | JPH04502889A (fr) |
| AU (1) | AU4485989A (fr) |
| CA (1) | CA2000572A1 (fr) |
| WO (1) | WO1990003877A1 (fr) |
| ZA (1) | ZA897788B (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07501996A (ja) * | 1992-10-05 | 1995-03-02 | オウェンス コーニング ファイバーグラス コーポレイション | 線状部材の製造方法 |
| AT403448B (de) * | 1994-11-15 | 1998-02-25 | Danubia Petrochem Polymere | Extrusionsimprägniervorrichtung |
| CA2178365A1 (fr) * | 1995-06-07 | 1996-12-08 | Zbigniew Kusibab | Methode et systeme de production de pieces pultrudees |
| US6387179B1 (en) * | 1997-06-24 | 2002-05-14 | Hydril Company | Method and device for impregnating fiber bundles with resin |
| CN102198730B (zh) * | 2011-04-21 | 2013-06-12 | 北京玻钢院复合材料有限公司 | 酚醛树脂复合材料拉挤成型工艺及其成型装置 |
| RU2612291C1 (ru) * | 2015-10-16 | 2017-03-06 | Общество с ограниченной ответственностью "Рекстром-М" | Пултрузионная установка для изготовления стержней из полимерных композиционных материалов |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1539577A (fr) * | 1966-10-11 | 1968-09-13 | English Electric Co Ltd | Procédé et appareillage pour la production continue de matière plastique armée de fibres |
| US3960629A (en) * | 1975-01-31 | 1976-06-01 | William Brandt Goldsworthy | Method for inductive heat curing of conductive fiber stock |
| US4312917A (en) * | 1979-09-13 | 1982-01-26 | Hawley Ronald C | Fiber-reinforced compound composite structure and method of manufacturing same |
| NO812163L (no) * | 1981-06-24 | 1982-12-27 | Berg Ltd A S Laader | Fremgangsmaate ved fremstilling av fiberarmerte gjenstander, og innretning for utfoerelse av fremgangsmaaten |
| US4419400A (en) * | 1981-10-26 | 1983-12-06 | Occidental Chemical Corporation | Pultruded reinforced phenolic resin products |
| US4588538A (en) * | 1984-03-15 | 1986-05-13 | Celanese Corporation | Process for preparing tapes from thermoplastic polymers and carbon fibers |
| DE3413601A1 (de) * | 1984-04-11 | 1985-10-24 | Grillo-Werke AG, 4223 Voerde | Verfahren und vorrichtung zur herstellung von verbundprofilen |
| FR2592609A1 (fr) * | 1986-01-06 | 1987-07-10 | Charbonnages Ste Chimique | Procede de fabrication de materiaux profiles par pultrusion. |
| CA1323160C (fr) * | 1987-09-04 | 1993-10-19 | Frank C. Beall | Produits hybrides pultrudes et mode de fabrication connexe |
-
1989
- 1989-10-12 CA CA002000572A patent/CA2000572A1/fr not_active Abandoned
- 1989-10-13 JP JP1511291A patent/JPH04502889A/ja active Pending
- 1989-10-13 ZA ZA897788A patent/ZA897788B/xx unknown
- 1989-10-13 AU AU44859/89A patent/AU4485989A/en not_active Abandoned
- 1989-10-13 WO PCT/US1989/004622 patent/WO1990003877A1/fr not_active Ceased
- 1989-10-13 EP EP19890912070 patent/EP0403607A4/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP0403607A1 (fr) | 1990-12-27 |
| JPH04502889A (ja) | 1992-05-28 |
| WO1990003877A1 (fr) | 1990-04-19 |
| EP0403607A4 (en) | 1992-04-01 |
| ZA897788B (en) | 1990-10-31 |
| AU4485989A (en) | 1990-05-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued | ||
| FZDE | Discontinued |
Effective date: 19950412 |