CA2007311C - Methode pour extraire et concentrer certains ions a partir de leurs solutions - Google Patents

Methode pour extraire et concentrer certains ions a partir de leurs solutions Download PDF

Info

Publication number: CA2007311C
Authority: CA; Canada
Prior art keywords: silica gel; group; ion; matrix; ions
Prior art date: 1988-10-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002007311A

Other languages

English (en)

Other versions

CA2007311A1 (fr

Inventor

Jerald S. Bradshaw

Maria Bochenska

Krzysztof E. Krakowiak

Jan F. Biernat

Bryon J. Tarbet

Ronald L. Bruening

Reed M. Izatt

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Brigham Young University

Original Assignee

Brigham Young University

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-10-07

Filing date

1990-01-08

Publication date

2002-03-26

1988-10-07 Priority claimed from US07/255,353 external-priority patent/US4952321A/en

1990-01-08 Application filed by Brigham Young University filed Critical Brigham Young University

1990-01-08 Priority to CA002007311A priority Critical patent/CA2007311C/fr

1991-07-08 Publication of CA2007311A1 publication Critical patent/CA2007311A1/fr

2002-03-26 Application granted granted Critical

2002-03-26 Publication of CA2007311C publication Critical patent/CA2007311C/fr

2010-01-08 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

150000002500 ions Chemical class 0.000 title claims abstract description 91
238000000034 method Methods 0.000 title claims abstract description 53
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 81
239000000741 silica gel Substances 0.000 claims abstract description 76
229910002027 silica gel Inorganic materials 0.000 claims abstract description 76
150000001875 compounds Chemical class 0.000 claims abstract description 32
239000011159 matrix material Substances 0.000 claims abstract description 28
239000007788 liquid Substances 0.000 claims abstract description 21
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 19
125000000217 alkyl group Chemical group 0.000 claims abstract description 16
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 12
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 11
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims abstract description 11
125000003118 aryl group Chemical group 0.000 claims abstract description 8
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 6
239000003365 glass fiber Substances 0.000 claims abstract description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 6
229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 6
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 6
239000004576 sand Substances 0.000 claims abstract description 6
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 5
239000011521 glass Substances 0.000 claims abstract description 5
125000001424 substituent group Chemical group 0.000 claims abstract description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract 12
235000019256 formaldehyde Nutrition 0.000 claims abstract 12
229910021645 metal ion Inorganic materials 0.000 claims description 27
239000000203 mixture Substances 0.000 claims description 18
238000000926 separation method Methods 0.000 claims description 16
-1 Ca(II) Chemical class 0.000 claims description 13
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 13
238000004587 chromatography analysis Methods 0.000 claims description 7
239000002002 slurry Substances 0.000 claims description 6
229910052723 transition metal Inorganic materials 0.000 claims description 6
150000003624 transition metals Chemical class 0.000 claims description 6
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 5
WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims description 4
239000007787 solid Substances 0.000 claims description 4
150000001768 cations Chemical class 0.000 claims description 3
BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 claims description 3
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims description 3
230000000536 complexating effect Effects 0.000 claims description 3
MILUBEOXRNEUHS-UHFFFAOYSA-N iridium(3+) Chemical compound [Ir+3] MILUBEOXRNEUHS-UHFFFAOYSA-N 0.000 claims description 3
WXHIJDCHNDBCNY-UHFFFAOYSA-N palladium dihydride Chemical compound [PdH2] WXHIJDCHNDBCNY-UHFFFAOYSA-N 0.000 claims description 3
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 1
229910017604 nitric acid Inorganic materials 0.000 claims 1
238000005406 washing Methods 0.000 claims 1
229910001428 transition metal ion Inorganic materials 0.000 abstract description 8
239000012141 concentrate Substances 0.000 abstract description 5
125000001624 naphthyl group Chemical group 0.000 abstract description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract description 4
125000004076 pyridyl group Chemical group 0.000 abstract description 4
101100073357 Streptomyces halstedii sch2 gene Proteins 0.000 abstract 2
229960001866 silicon dioxide Drugs 0.000 description 47
239000000243 solution Substances 0.000 description 47
150000001412 amines Chemical class 0.000 description 39
238000011084 recovery Methods 0.000 description 20
239000000463 material Substances 0.000 description 18
229930195733 hydrocarbon Natural products 0.000 description 17
239000004215 Carbon black (E152) Substances 0.000 description 15
239000003446 ligand Substances 0.000 description 15
150000002430 hydrocarbons Chemical class 0.000 description 14
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
239000000377 silicon dioxide Substances 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
238000001479 atomic absorption spectroscopy Methods 0.000 description 5
239000000499 gel Substances 0.000 description 5
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
229910052802 copper Inorganic materials 0.000 description 4
239000010949 copper Substances 0.000 description 4
229910001385 heavy metal Inorganic materials 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
125000003277 amino group Chemical group 0.000 description 3
125000001183 hydrocarbyl group Chemical group 0.000 description 3
229910001629 magnesium chloride Inorganic materials 0.000 description 3
229910000077 silane Inorganic materials 0.000 description 3
150000004756 silanes Chemical class 0.000 description 3
229910052709 silver Inorganic materials 0.000 description 3
239000004332 silver Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
235000012206 bottled water Nutrition 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000003651 drinking water Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
235000002639 sodium chloride Nutrition 0.000 description 2
BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 2
239000002699 waste material Substances 0.000 description 2
MDAXKAUIABOHTD-UHFFFAOYSA-N 1,4,8,11-tetraazacyclotetradecane Chemical compound C1CNCCNCCCNCCNC1 MDAXKAUIABOHTD-UHFFFAOYSA-N 0.000 description 1
BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
LXWLHXNRALVRSL-UHFFFAOYSA-N 3-(oxiran-2-ylmethoxy)propylsilane Chemical compound [SiH3]CCCOCC1CO1 LXWLHXNRALVRSL-UHFFFAOYSA-N 0.000 description 1
BSFODEXXVBBYOC-UHFFFAOYSA-N 8-[4-(dimethylamino)butan-2-ylamino]quinolin-6-ol Chemical compound C1=CN=C2C(NC(CCN(C)C)C)=CC(O)=CC2=C1 BSFODEXXVBBYOC-UHFFFAOYSA-N 0.000 description 1
FBEHFRAORPEGFH-UHFFFAOYSA-N Allyxycarb Chemical compound CNC(=O)OC1=CC(C)=C(N(CC=C)CC=C)C(C)=C1 FBEHFRAORPEGFH-UHFFFAOYSA-N 0.000 description 1
KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
241001633942 Dais Species 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
101000800807 Homo sapiens Tumor necrosis factor alpha-induced protein 8 Proteins 0.000 description 1
UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
229920002873 Polyethylenimine Polymers 0.000 description 1
102100033649 Tumor necrosis factor alpha-induced protein 8 Human genes 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229910001431 copper ion Inorganic materials 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
229960002887 deanol Drugs 0.000 description 1
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
101150059195 metY gene Proteins 0.000 description 1
239000007769 metal material Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
150000001282 organosilanes Chemical class 0.000 description 1
150000002924 oxiranes Chemical class 0.000 description 1
238000004094 preconcentration Methods 0.000 description 1
238000003825 pressing Methods 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Treatment Of Liquids With Adsorbents In General (AREA)
Extraction Or Liquid Replacement (AREA)

CA002007311A 1988-10-07 1990-01-08 Methode pour extraire et concentrer certains ions a partir de leurs solutions Expired - Lifetime CA2007311C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA002007311A CA2007311C (fr)	1988-10-07	1990-01-08	Methode pour extraire et concentrer certains ions a partir de leurs solutions

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/255,353 US4952321A (en)	1988-10-07	1988-10-07	Process of removing and concentrating desired ions from solutions
CA002007311A CA2007311C (fr)	1988-10-07	1990-01-08	Methode pour extraire et concentrer certains ions a partir de leurs solutions

Publications (2)

Publication Number	Publication Date
CA2007311A1 CA2007311A1 (fr)	1991-07-08
CA2007311C true CA2007311C (fr)	2002-03-26

Family

ID=25673870

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002007311A Expired - Lifetime CA2007311C (fr)	1988-10-07	1990-01-08	Methode pour extraire et concentrer certains ions a partir de leurs solutions

Country Status (1)

Country	Link
CA (1)	CA2007311C (fr)

1990
- 1990-01-08 CA CA002007311A patent/CA2007311C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA2007311A1 (fr)	1991-07-08

Legal Events

Date	Code	Title	Description
1996-12-31	EEER	Examination request
2010-01-08	MKEX	Expiry

Publication	Publication Date	Title
US4952321A (en)	1990-08-28	Process of removing and concentrating desired ions from solutions
EP0355376B1 (fr)	1995-12-20	Composés d'hydrocarbure contenant du soufre et procédé de leur utilisation dans la récupération et la concentration d'ions désirés de leurs solutions
CA2120242C (fr)	2002-12-03	Ligands contenant de l'acide aminoalkylphosphonique lies a des supports solides pour l'elimination d'ions metalliques
US5039419A (en)	1991-08-13	Sulfur-containing hydrocarbon compounds and process of using same in recovering and concentrating desired ions from solutions thereof
US6117330A (en)	2000-09-12	Process of using sulfur and nitrogen-containing hydrocarbons in recovering and concentrating desired ions from solutions thereof
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US5084430A (en)	1992-01-28	Sulfur and nitrogen containing hydrocarbons and process of using same in separating desired ions from solutions thereof
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US6372903B1 (en)	2002-04-16	Method for preparing polyazacycloalkanes grafted on silica gel and use of grafted compounds
CA2007311C (fr)	2002-03-26	Methode pour extraire et concentrer certains ions a partir de leurs solutions
CN1041694C (zh)	1999-01-20	从多离子源溶液中浓缩和分离所希望得到的离子的方法及所使用的配位体－固体复合物
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