CA2007730A1 - Procede pour la recuperation de produits catalytiques - Google Patents

Procede pour la recuperation de produits catalytiques

Info

Publication number: CA2007730A1
Authority: CA; Canada
Prior art keywords: rhodium; recovery; catalyst values; iodide; methyl iodide
Prior art date: 1989-11-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

CA2007730A

Other languages

English (en)

Other versions

CA2007730C (fr

Inventor

Steve Conley Odom

Steven Leroy Cook

Brent Alan Tennant

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Chemical Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-11-20

Filing date

1990-01-15

Publication date

1991-05-20

1990-01-15 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1991-05-20 Publication of CA2007730A1 publication Critical patent/CA2007730A1/fr

1996-02-06 Application granted granted Critical

1996-02-06 Publication of CA2007730C publication Critical patent/CA2007730C/fr

2010-01-15 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000000034 method Methods 0.000 title abstract 3
239000003054 catalyst Substances 0.000 title abstract 2
238000011084 recovery Methods 0.000 title abstract 2
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 3
229910052703 rhodium Inorganic materials 0.000 abstract 3
239000010948 rhodium Substances 0.000 abstract 3
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 3
INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 2
239000011269 tar Substances 0.000 abstract 2
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 1
239000008346 aqueous phase Substances 0.000 abstract 1
230000006315 carbonylation Effects 0.000 abstract 1
238000005810 carbonylation reaction Methods 0.000 abstract 1
238000000605 extraction Methods 0.000 abstract 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
229910000043 hydrogen iodide Inorganic materials 0.000 abstract 1
229910052740 iodine Inorganic materials 0.000 abstract 1
239000011630 iodine Substances 0.000 abstract 1
239000000203 mixture Substances 0.000 abstract 1
238000002360 preparation method Methods 0.000 abstract 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/573—Separation; Purification; Stabilisation; Use of additives
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
- C22B11/048—Recovery of noble metals from waste materials from spent catalysts
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C22B7/007—Wet processes by acid leaching
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Mechanical Engineering (AREA)
Manufacturing & Machinery (AREA)
Metallurgy (AREA)
Oil, Petroleum & Natural Gas (AREA)
Life Sciences & Earth Sciences (AREA)
Environmental & Geological Engineering (AREA)
General Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

CA 2007730 1989-11-20 1990-01-15 Procede pour la recuperation de produits catalytiques Expired - Fee Related CA2007730C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
PCT/US1989/005193 WO1991007372A1 (fr)	1989-11-20	1989-11-20	Procede de recuperation de quantites catalytiques
USPCT89/05193		1989-11-20

Publications (2)

Publication Number	Publication Date
CA2007730A1 true CA2007730A1 (fr)	1991-05-20
CA2007730C CA2007730C (fr)	1996-02-06

Family

ID=22215370

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2007730 Expired - Fee Related CA2007730C (fr)	1989-11-20	1990-01-15	Procede pour la recuperation de produits catalytiques

Country Status (7)

Country	Link
EP (1)	EP0497759B1 (fr)
JP (1)	JPH05501516A (fr)
KR (1)	KR0120194B1 (fr)
AT (1)	ATE118474T1 (fr)
CA (1)	CA2007730C (fr)
DE (1)	DE68921224T2 (fr)
WO (1)	WO1991007372A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9806527D0 (en) *	1998-03-26	1998-05-27	Bp Chem Int Ltd	Process
EP0985449A1 (fr) *	1998-09-11	2000-03-15	Dsm N.V.	Procédé pour séparer le rhodium de mélanges organiques
EP1575705A2 (fr)	2002-12-23	2005-09-21	Eastman Chemical Company	Processus de recuperation de composants catalyseur contenant du phosphore et de l'iode
GB0602663D0 (en) *	2006-02-09	2006-03-22	Univ Cardiff	Removal of catalyst species
WO2013101015A1 (fr) *	2011-12-28	2013-07-04	Eastman Chemical Company	Récupération de catalyseur à l'aide d'iodure d'hydrogène aqueux et d'acide acétique aqueux

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4364907A (en) *	1981-06-18	1982-12-21	Eastman Kodak Company	Process for recovery of rhodium values
DE3515396A1 (de) *	1985-04-29	1986-10-30	Hoechst Ag, 6230 Frankfurt	Verfahren zur reinigung und rueckgewinnung der bei der carbonylierung von methylacetat und/oder dimethylether anfallenden verunreinigten katalysatorloesung

1989
- 1989-11-20 EP EP19900901193 patent/EP0497759B1/fr not_active Expired - Lifetime
- 1989-11-20 KR KR1019920701186A patent/KR0120194B1/ko not_active Expired - Fee Related
- 1989-11-20 AT AT90901193T patent/ATE118474T1/de not_active IP Right Cessation
- 1989-11-20 DE DE68921224T patent/DE68921224T2/de not_active Expired - Lifetime
- 1989-11-20 WO PCT/US1989/005193 patent/WO1991007372A1/fr not_active Ceased
- 1989-11-20 JP JP90501262A patent/JPH05501516A/ja active Pending
1990
- 1990-01-15 CA CA 2007730 patent/CA2007730C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
DE68921224D1 (de)	1995-03-23
EP0497759B1 (fr)	1995-02-15
CA2007730C (fr)	1996-02-06
DE68921224T2 (de)	1995-06-14
WO1991007372A1 (fr)	1991-05-30
KR927003500A (ko)	1992-12-18
ATE118474T1 (de)	1995-03-15
JPH05501516A (ja)	1993-03-25
EP0497759A1 (fr)	1992-08-12
KR0120194B1 (ko)	1997-10-22

Legal Events

Date	Code	Title	Description
1990-01-15	EEER	Examination request
2002-01-15	MKLA	Lapsed

Publication	Publication Date	Title
TW344739B (en)	1998-11-11	Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
AU576150B2 (en)	1988-08-11	Process for purifying and recovering contaminated catalyst solution obtained in the carbonylation of methyl acetate and/or dimethylether
NZ240009A (en)	1993-01-27	Process for preparation of carboxylic acid anhydrides by reaction of co with a carboxylic acid ester or alkyl ether
ATE118474T1 (de)	1995-03-15	Verfahren zur wiedergewinnung von katalysatorwerten.
EP0398464A3 (fr)	1992-03-04	Récupération d'arôme à partir de l'hydrolyse thermique de marc de café
DE3261715D1 (en)	1985-02-07	Process for the separation of acetone from the reaction mixtures of carbonylation reactions
CA2058620A1 (fr)	1991-06-05	Procede de recuperation de rhodium a l'aide d'oxydants
IE41936L (en)	1976-07-28	Rhodium-containing hydrogenation catalyst; tetracycline
EP0074506A3 (en)	1983-06-01	Process for the separation of acetone from carbonylation mixtures
ZA855952B (en)	1986-04-30	Process for making acetic anhydride and,if desired,acetic acid
CA2007101A1 (fr)	1990-07-28	Procede pour la recuperation et la purification de la solution contaminee de catalyseur, produite par carbonylation du methanol et (ou) de l'acetate de methyle et (ou) de l'oyde de dimethyle
ES2030870T3 (es)	1992-11-16	Recuperacion de metales nobles.
CA2008226A1 (fr)	1990-08-10	Procede pour eliminer les produits de corrosion metallique dans la solution catalytique contaminee, obtenue lors de la carbonylation du methanol et (ou) de l'acetate de methyle et(ou) de l'oxyde de dimethyle
NO873277D0 (no)	1987-08-05	Fremgangsmaate for gjenvinning av kaffein fra aktivkull.
Gulliver	1988	Process for Recovering Metals
Gulliver	1990	Process for the Recovery of Metals
Gulliver	1989	Recovery of Noble Metals
JPS5384932A (en)	1978-07-26	Preparation of terephthalic acid
JPS5239523A (en)	1977-03-26	Method of recovering noble metals in waste catalyst
ES2034672T3 (es)	1993-04-01	Procedimiento de preparacion de acetato de metilo a partir de formiato de metilo.
IE38785L (en)	1974-07-11	2, 2- ANHYDRO - 1ß -D -ARABINOFURANOSYL - 5 - FLUOROCYTOSINE
JPS5711929A (en)	1982-01-21	Production of 1,1-diester or aldehyde
Bruckner et al.	1983	Studies of Residual Stresses Due to Induction Hardening
Bildl et al.	1986	Process for the Purification of Silicon by the Action of an Acid
JPS5219607A (en)	1977-02-15	Process for recovery of polyhydric alcohols